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The Wetting Behavior of CrMnNi Steel on Mg-PSZ as a Function of Phosphorous, Sulphur and Titanium Content

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Advances in Molten Slags, Fluxes, and Salts: Proceedings of the 10th International Conference on Molten Slags, Fluxes and Salts 2016

Abstract

The effect of temperature and elemental concentrations of phosphorous, sulphur and titanium in high alloyed Cr-Mn-Ni TRIP/TWIP steels (16 %Cr, 7 %Mn, 6 % Ni) on the wettability of MgO partially stabilized zirconia (Mg-PSZ) substrates was studied. The investigation of the wetting behavior is of a major importance of the infiltration of steel into open foam ceramics and in interfacial contact of steel & ceramic powder in the spark plasma sintering. The interfacial reaction was characterized using X-ray and secondary neutral mass spectrometry analysis. The contact angle was investigated between 1500 ℃ and 1600 ℃ in argon (99.999 vol% Ar) atmosphere and was found to decrease with increasing temperature. At 1600 ℃ sulphur decreased the contact angle from 103 ° (100 ppm S) to 92 ° (1000 ppm S) in Fe-Cr-Mn-Ni. Increasing phosphorous content was found to increase the interfacial oxygen content in samples and the contact angle decreased to ca. 97 °. For titanium alloyed Cr-Mn-Ni sample, a TixOy interfacial layer was found after experiments and the contact angle was ca. 87 ° at maximum Ti content of 0.232 %.

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Authors and Affiliations

  1. Institute of Iron and Steel Technology, TU Bergakademie Freiberg, Leipziger Straße 34, 09599, Freiberg, Germany

    Tobias Dubberstein & Hans-Peter Heller

  2. Institute of Ceramic, Glass and Construction Materials, TU Bergakademie Freiberg, Agricolastraße 17, 09596, Freiberg, Germany

    Claudia Wenzel & Christos G. Aneziris

Authors
  1. Tobias Dubberstein
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  2. Hans-Peter Heller
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  3. Claudia Wenzel
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  4. Christos G. Aneziris
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Editor information

Editors and Affiliations

  1. The University of Alabama, USA

    Ramana G. Reddy (Conference Chair) (Conference Chair)

  2. Global R&D, ArcelorMittal USA, USA

    Pinakin Chaubal (Co-chair) (Co-chair)

  3. Carnegie Mellon University, USA

    P. Chris Pistorius (Co-chair) (Co-chair)

  4. Boston University, USA

    Uday Pal (Co-chair) (Co-chair)

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© 2016 TMS (The Minerals, Metals & Materials Society)

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Dubberstein, T., Heller, HP., Wenzel, C., Aneziris, C.G. (2016). The Wetting Behavior of CrMnNi Steel on Mg-PSZ as a Function of Phosphorous, Sulphur and Titanium Content. In: Reddy, R.G., Chaubal, P., Pistorius, P.C., Pal, U. (eds) Advances in Molten Slags, Fluxes, and Salts: Proceedings of the 10th International Conference on Molten Slags, Fluxes and Salts 2016. Springer, Cham. https://doi.org/10.1007/978-3-319-48769-4_149

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