Skip to main content

Effect of Operational Parameters on the Behavior of Phosphorus and Sulfur in Aluminum Reduction

  • Chapter
Light Metals 2015

Abstract

Impurities in the electrolyte of an aluminum reduction cell are known to affect current efficiency and other aspects of potroom operation. Traces of phosphorus and sulfur are generally present in the cells and their behavior is of interest due to their known adverse effect on the process of aluminum production In this study, data analysis was performed on the phosphorus concentration and different process parameters registered during the three years of daily measurements at the Alcoa Fjarðaál smelter. Experimental samples taken during power outages were also collected and analyzed for the sulfur and phosphorus concentrations in the bath.

High bath height was found to be correlated with higher phosphorus concentration in the metal. Moreover, there is a very strong negative correlation between superheat and phosphorus in the metal. Elemental analysis shows an increase of the phosphorus and sulfur concentration during power outages.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 289.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. J. Thonstad, P. Fellner, G.M. Haarberg, J. Híveš, H. Kvande, and Å. Sterten Aluminum electrolysis — Fundamentals of the Hall-Héroult process, 3rd edition (Aluminum-Verlag GmbH, Düsseldorf, Germany, 2001), 227

    Google Scholar 

  2. K. Grjotheim and H. Kvande, Introduction to Aluminum Electrolysis, (Aluminum-Verlag GmbH, Düsseldorf, Germany, 1993), 147

    Google Scholar 

  3. V. Danek, M. Chrenkova, A. Silny, G.M. Haarberg and M. Stas, Distribution of Phosphorus in Industrial Aluminum Cells, Canadian Metallurgical Quaterly, 38, 1999, 149–156

    Google Scholar 

  4. R. Meirbekova, J. Thonstad and G.M. Haarberg, G. Saevarsdottir, Effect of Current Density and Phosphorus Species on Current Efficiency in Aluminum Electrolysis at High Current Densities, Light Metals 2014

    Book  Google Scholar 

  5. E. Haugland, G. M. Haarberg, E. Thisted, J. Thonstad, The behavior of the phosphorus impurities in aluminum electrolysis cells, Light Metals, 2001, 549–553

    Google Scholar 

  6. T.E. Jentoftsen, Behaviour of iron and titanium species in cryolite-alumina melts, Dr.ing. thesis, NTNU Trondheim, Norway, 2000.

    Google Scholar 

  7. E.W. Thisted, Electrochemical properties of Phosphorus Compounds in Fluoride Melts cells, (Ph.D. thesis, Norwegian University of Science and Technology, 2003), 200–202

    Google Scholar 

  8. S Rolseth, Tilbakereaksjonen i aluminiumelektrolysen, Dr. Ing. Thesis, The University of Trondheim, NTH, 1980

    Google Scholar 

  9. J Thonstad, TA Utigard, H Vogt, On the Anode Effect in Aluminum Electrolysis, Light Metals, 2000, 131–137

    Google Scholar 

  10. L Schuh and G Wedde, Removal of impurities from dry scrubbed fluoride enriched alumina, Light Metals 1996

    Google Scholar 

  11. P. Lossius and H.A. Øye, Removing Impurities from Secondary Alumina Fines

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2015 TMS (The Minerals, Metals & Materials Society)

About this chapter

Cite this chapter

Meirbekova, R., Haarberg, G.M., Thonstad, J., Ziegler, D.P., Brynjarsson, J., Saevarsdottir, G. (2015). Effect of Operational Parameters on the Behavior of Phosphorus and Sulfur in Aluminum Reduction. In: Hyland, M. (eds) Light Metals 2015. Springer, Cham. https://doi.org/10.1007/978-3-319-48248-4_93

Download citation

Publish with us

Policies and ethics