Skip to main content

Surface Behavior of Iron Sulfide Ore during Grinding with Alumina Media

  • Chapter
Characterization of Minerals, Metals, and Materials 2016

Abstract

This research was conducted to study the oxidation and surface modification of pyrite in an inert mill and alumina grinding media at different pH values. The extent and progress of the oxidation function of milling time, by measuring some physicochemical variables, zeta potential (ZP), infrared analysis and monitoring. The results indicate pyrite oxidation during grinding, releasing iron and sulfur ions to the solution increasing its concentration with the initial pH and the milling time, the ORP and DO decrease the grinding time, on the other hand presents negative values ZP pH of 9, 11 and 12, whereas at pH 5, 7 and 13, the ZP is positive, FTIR generally detect the presence of free sulfate ion molecule 1084 cm-1, goethite with the absorption band at about 794 cm-1, also occurs in a band assigned to 470 cm-1 lepidocrocite oxy iron hydroxide γ- FeOOH, nucleated species or formed during milling.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 239.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Similar content being viewed by others

References

  1. Murphy, R. and D.R. Strongin, Surface reactivity of pyrite and related sulfides. Surface Science Reports, (2009). 64(1): p. 1–45.

    Article  Google Scholar 

  2. Schaufuß, A.G., et al., Reactivity of surface chemical states on fractured pyrite. Surface Science, (1998). 411(3): p. 321–328.

    Article  Google Scholar 

  3. Adam, K., K.A. Natarajan, and I. Iwasaki, Grinding media wear and its effect on the flotation of sulfide minerals. International Journal of Mineral Processing, (1984). 12(1–3): p. 39–54.

    Article  Google Scholar 

  4. Woods, Y.R.D.F.K.a.R., The interaction of iron species with pyrite surfaces. Journal of Applied electrochemistry, (1991). 21: p. 531–536.

    Article  Google Scholar 

  5. Huang, G. and S. Grano, Galvanic interaction of grinding media with pyrite and its effect on floatation. Minerals Engineering, (2005). 18(12): p. 1152–1163.

    Article  Google Scholar 

  6. Peng, Y. and S. Grano, Inferring the distribution of iron oxidation species on mineral surfaces during grinding of base metal sulphides. Electrochimica Acta, (2010). 55(19): p. 5470–5477.

    Article  Google Scholar 

  7. Michael Descostes, C., Beaucaire, Florence Mercie, Sebastien Savaoy, Joachim Sow and Pierpaolo Zuddas, Effect of carbonate ions on pyrite (FeS2) dissolution. Bull. Soc. géol. France, (2002). 173(3): p. 265–270.

    Article  Google Scholar 

  8. Peng, Y. and S. Grano, Effect of grinding media on the activation of pyrite flotation. Minerals Engineering, (2010). 23(8): p. 600–605.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2016 TMS (The Minerals, Metals & Materials Society)

About this chapter

Cite this chapter

Martín, R.P. et al. (2016). Surface Behavior of Iron Sulfide Ore during Grinding with Alumina Media. In: Ikhmayies, S.J., et al. Characterization of Minerals, Metals, and Materials 2016. Springer, Cham. https://doi.org/10.1007/978-3-319-48210-1_96

Download citation

Publish with us

Policies and ethics