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Electroless Ni-P/Nano-SiO2 Composite Plating on Dual Phase Magnesium-Lithium Alloy

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Magnesium Technology 2015
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Abstract

The application of Mg-Li alloys is restricted in practice due to mainly poor corrosion resistance and wear resistance. Electroless nickel plating is one of the common and effective ways to protect alloys from corrosion. In this study, nano-SiO2 particles with Ni-P matrix have been successfully co-deposited onto dual phase Mg-8Li base alloy through electroless plating, generating homogeneously Ni-P/nano-SiO2 composite coating. The morphology, elemental composition and structures of coatings were investigated. Coating performances were evaluated using hardness tests and electrochemical analysis. The results indicate that the Ni-P/nano-SiO2 composite coating can significantly improve the wear and corrosion resistance.

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References

  1. A. Sharma, R. Uma Rani, and S. Mayanna, “Thermal studies on electrodeposited black oxide coating on magnesium alloys,” Thermochimica acta, 376 (2001), 67–75.

    Article  Google Scholar 

  2. J. M. Song, T. X. Wen, and J. Y. Wang, “Vibration fracture properties of a lightweight Mg-Li-Zn alloy,” Scripta materialia, 56 (2007), 529–532.

    Article  Google Scholar 

  3. A. Sanschagrin et al, “Mechanical properties and micro structure of new magnesium-lithium base alloys,” Materials Science and Engineering: A, 220 (1996), 69–77.

    Article  Google Scholar 

  4. Z. Trojanová et al., “Deformation behaviour of Mg-Li alloys at elevated temperatures,” Materials Science and Engineering: A, 410 (2005), 148–151.

    Article  Google Scholar 

  5. S. Wang, et al., “Microstructures and mechanical properties of 5 wt.% Al2 Y p/Mg-Li composite,” Materials Letters, 60 (2006), 1863–1865.

    Article  Google Scholar 

  6. M. C. Zhao et al., “An exploratory study of the corrosion of Mg alloys during interrupted salt spray testing,” Corrosion Science, 51 (2009), 1277–1292.

    Article  Google Scholar 

  7. L. Liu, M. Schlesinger, “Corrosion of magnesium and its alloys,” Corrosion Science, 51 (2009), 1733–1737.

    Article  Google Scholar 

  8. J. Gray, B. Luan, “Protective coatings on magnesium and its alloys-a critical review,” Journal of alloys and compounds, 336 (2002), 88–113.

    Article  Google Scholar 

  9. R. Ambat, W. Zhou, “Electroless nickel-plating on AZ91D magnesium alloy: effect of substrate micro structure and plating parameters,” Surface and Coatings Technology, 179 (2004), 124–134.

    Article  Google Scholar 

  10. A. Grosjean, M. Rezrazi, and J. Takadoum, “Hardness, friction and wear characteristics of nickel-SiC electroless composite deposits,” Surf Coat Technol, 137 (2001), 92–96.

    Article  Google Scholar 

  11. J. N. Balaraju, T. S. N. Sankara-Narayanan, and S. K. Seshadri, “Electroless Ni-P composite coatings,” Appl Electrochem, 33 (2003), 807–816.

    Article  Google Scholar 

  12. R. Wang et al., “Preparation and characterization of nanodiamond cores coated with a thin Ni-Zn-P alloy film,” Mater Character 59 (2008), 108–111.

    Article  Google Scholar 

  13. T. Rabizadeh, and S. R. Allahkaram, “Corrosion resistance enhancement of Ni-P electroless coatings by incorporation of nano-SiO2 particles,” Materials and Design, 32 (2011), 133–138.

    Article  Google Scholar 

  14. D. Dong et al., “Preparation and properties of electroless Ni-P-SiO2 composite coatings” Applied Surface Science, 255 (2009), 7051–7055.

    Article  Google Scholar 

  15. S. Alirezaei et al., “Wear behavior of Ni-P and Ni-P-Al2O3 electroless coatings,” Wear, 262 (2007), 978–985.

    Article  Google Scholar 

  16. K. Keong, W. Sha, “Crystallisation and phase transformation behaviour of electroless nickel-phosphorus deposits and their engineering properties,” Surface Engineering, 18 (2002), 329–343.

    Article  Google Scholar 

  17. Y. Song et al., “Corrosion characterization of Mg-8Li alloy in NaCl solution,” Corrosion Science, 51 (2009), 1087–1094.

    Article  Google Scholar 

  18. H.P. Liu et al, “Effect of organic additives on the corrosion resistance properties of electroless nickel deposits,” Thin solid films, 516(2008), 1883–1889.

    Article  Google Scholar 

  19. H. Yang et al., “A homogenisation pre-treatment for adherent and corrosion-resistant Ni electroplated coatings on Mg-alloy AZ91D,” Corrosion Science, 79 (2014), 41–49.

    Article  Google Scholar 

  20. J. Lian et al., “Electroless Ni-P deposition plus zinc phosphate coating on AZ91D magnesium alloy,” Surface and Coatings Technology, 200 (2006), 5956–5962.

    Article  Google Scholar 

  21. H. Ashassi-Sorkhabi, B. Shaabani, and D. Seifzadeh, “Corrosion inhibition of mild steel by some Schiff base compounds in hydrochloric acid,” Applied Surface Science, 239 (2005), 154–164.

    Article  Google Scholar 

  22. J. Balaraju, T. S. Narayanan, and S. Seshadri, “Evaluation of the corrosion resistance of electroless Ni-P and Ni-P composite coatings by electrochemical impedance spectroscopy,” Journal of solid state electrochemistry, 5 (2001), 334–338.

    Article  Google Scholar 

  23. R. Abdel Hameed, and A. Fekry, “Electrochemical impedance studies of modified Ni-P and Ni-Cu-P deposits in alkaline medium,” Electrochimica Acta, 55 (2010), 5922–5929.

    Article  Google Scholar 

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© 2015 TMS (The Minerals, Metals & Materials Society)

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Zou, Y., Zhang, Z.W., Zhang, M.L. (2015). Electroless Ni-P/Nano-SiO2 Composite Plating on Dual Phase Magnesium-Lithium Alloy. In: Manuel, M.V., Singh, A., Alderman, M., Neelameggham, N.R. (eds) Magnesium Technology 2015. Springer, Cham. https://doi.org/10.1007/978-3-319-48185-2_64

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