Skip to main content

Preparation of TiC from Titanium Bearing Blast Furnace Slag by Carbothermal Reduction in Vacuum

  • Chapter
7th International Symposium on High-Temperature Metallurgical Processing
  • 1817 Accesses

Abstract

Titanium bearing blast furnace slag, which contains 20%-30% TiO2, is a valuable secondary titanium resource. Based on the thermodynamics calculation effect of the temperature on the reduction of the slag in vacuum were studied at certain vacuum degrees. The results show that magnesium vapor and silicon monoxide vapor can be obtained at the condition of high temperature and low pressure. The purity of TiC increases with temperature increasing. When the temperature arrives at 1623K TiC can be obtained besides the reductant carbon. XRD result of the powder collected from the furnace cover show that magnesium and silicon in the titanium bearing BF slag leave the slag system during carbothermal reduction in vacuum. From the above it can be concluded that TiC can be obtained from the titanium bearing BF slag and silicon and titanium in the slag can be separated by carbothermal reduction in vacuum and acid leaching.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 239.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Kwauk, Mooson, Legacy and growth-chemical engineering in China(Chemical engineering science 44.11,1989),2421–2434.

    Article  Google Scholar 

  2. Ooka, Chihiro et al., Highly hydrophobic TiO 2 pillared clay for photo catalytic degradation of organic compounds in water(Microporous and Mesoporous Materials 67.2,2004), 143–150.

    Article  Google Scholar 

  3. Robin, James E., and Paul Nordin, Spectral absorptance at 3.8- wavelength for aluminum and pyroceram at elevated temperatures(Applied Physics Letters 27.9,1975),493–495.

    Article  Google Scholar 

  4. Portinari, L., C. Chiosi, and A. Bressan, Galactic chemical enrichment with new metallicity dependent stellar yields(Astronomy and Astrophysics 334,1998), 505–539.

    Google Scholar 

  5. Ahuja, R., et al, Structural, elastic, and high-pressure properties of cubic TiC, TiN, and TiO (Physical review B 53.6,1996), 3072.

    Article  Google Scholar 

  6. Vallauri, Dario, IC Atias Adrian, and A. Chrysanthou, TiC-TiB 2 composites: a review of phase relationships, processing and properties(Journal of the European Ceramic Society 28.8,2008),1697–1713.

    Article  Google Scholar 

  7. Lefebvre, Louis-Philippe, and Eric Baril, Effect of oxygen concentration and distribution on the compression properties on titanium foams(Advanced Engineering Materials 10.9,2008), 868–876.

    Article  Google Scholar 

  8. Ono, L. K., D. Sudfeld, and B. Roldan Cuenya, In situ gas-phase catalytic properties of TiC-supported size-selected gold nanoparticles synthesized by diblock copolymer encapsulation(Surface science 600.23,2006), 5041–5050.

    Article  Google Scholar 

  9. Bellucci, A., D. Gozzi, and A. Latini, Overview of the TiC/TiO 2 (rutile) interface(Solid state ionics 172.1,2004), 369–375.

    Article  Google Scholar 

  10. Lefort, Pierre, Alexandre Maitre, and Pascal Tristant, Influence of the grain size on the reactivity of TiO 2/C mixtures(Journal of alloys and compounds 302.1,2000),287–298.

    Article  Google Scholar 

  11. Lee, Gil-Geun, and Gook-Hyun Ha, Carbothermic reduction of oxide powder prepared from titanium dioxide and cobalt nitrate(Materials transactions 47.12,2006), 3007–3011.

    Article  Google Scholar 

  12. Zhang, Haijun, et al, Preparation of titanium carbide powders by sol-gel and microwave carbothermal reduction methods at low temperature(Journal of Sol-Gel Science and Technology 46.2,2008), 217–222.

    Article  Google Scholar 

  13. Bai, C., G. Qiu, and H. Pei, Research on the foaming property of blast furnace slag bearing TiO2(Teoksessa: VII International Conference on Molten Slags, Fluxes and Salts, the South African Institute of Mining and Metallurgy,2004).

    Google Scholar 

  14. Dickerson, Theodore, and Juan Soria, Catalytic fast pyrolysis(a review Energies 6.1,2013), 514–538.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Meilong Hu .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2016 TMS (The Minerals, Metals & Materials Society)

About this chapter

Cite this chapter

Yin, F., Qu, Z., Hu, M., Deng, Q., Hu, M. (2016). Preparation of TiC from Titanium Bearing Blast Furnace Slag by Carbothermal Reduction in Vacuum. In: Hwang, JY., et al. 7th International Symposium on High-Temperature Metallurgical Processing. Springer, Cham. https://doi.org/10.1007/978-3-319-48093-0_70

Download citation

Publish with us

Policies and ethics