Atomic symbol: Ga
Atomic number: 31
Atomic weight: 69.723 ± 1 g/mol
Isotopes and abundances:69Ga 60.1 %;71Ga 39.9 %
1 Atm melting point: 29.8 °C
1 Atm boiling point: ~2,400 °C
Common valences: +3
Ionic radii values: 47 pm (fourfold); 62 pm (sixfold)
Pauling electronegativity: 1.81
First ionization energy: 174.6 kJ/mol
Chondritic (CI) abundance: 9.5 ± 0.3 μg/g
Silicate Earth abundance: 4.0 μg/g
Crustal abundance: 17.5 μg/g
Seawater abundance: ~1.2 pg/g
Core abundance: <1 μg/g
Properties
Gallium does not occur as a native metal and forms very few minerals like gallite (CuGaS2), but widely occurs in nature as a trace constituent substituted for Al. Gallium metal is prepared as a by-product of aluminum production from bauxite ore and from Zn ores (e.g., sphalerite). Synthetically prepared metallic Ga is a soft, silvery...
References
Benezeth, P., Diakonov, I. I., Pokrovski, G. S., Dandurand, J.-L., Schott, J., and Khodakovsky, I. L., 1997. Gallium speciation in aqueous solution. Experimental study and modeling: part 2. Solubility of α-GaOOH in acidic solutions from 150 to 250°C and hydrolysis constants of gallium (III) to 300°C. Geochimica et Cosmochimica Acta, 61, 1345–1357.
Bennett, R., and Czechowski, F., 1980. Gallium porphyrins in bituminous coal. Nature, 283, 465–467.
Blanchard, I., Badro, J., Siebert, J., and Ryerson, F. J., 2015. Composition of the core from gallium metal-silicate partitioning experiments. Earth and Planetary Science Letters, 427, 191–201.
Bowen, H. J. M., 1982. Chapter 12, Boron, aluminum, gallium, indium thallium. In Environmental Chemistry. London: Royal Society of Chemistry, Vol. 2, pp. 159–161.
Campbell, A. J., and Humayun, M., 2005. Compositions of group IVB iron meteorites and their parent melt. Geochimica et Cosmochimica Acta, 69, 4733–4744.
Chabot, N. L., Wollack, E. A., Humayun, M., and Shank, E. M., 2015. The effect of oxygen as a light element in metallic liquids on partitioning behavior. Meteoritics & Planetary Science, 50, 530–546.
Chitamber, C. R., 2010. Medical applications and toxicities of gallium compounds. International Journal of Environmental Research and Public Health, 7, 2337–2361.
Clayton, D. D., 2003. Handbook of Isotopes in the Cosmos: Hydrogen to Gallium. Cambridge, UK: Cambridge University Press, 326 pp.
Davis, F. A., Humayun, M., Hirschmann, M. M., and Cooper, R. S., 2013. Experimentally determined mineral/melt partitioning of first-row transition elements (FRTE) during partial melting of peridotite at 3 GPa. Geochimica et Cosmochimica Acta, 104, 232–260.
Diakonov, I. I., Pokrovski, G. S., Benezeth, P., Schott, J., Dandurand, J.-L., and Escalier, J., 1997. Gallium speciation in aqueous solution. Experimental study and modeling: part 1. Thermodynamic properties of Ga(OH)4 − to 300°C. Geochimica et Cosmochimica Acta, 61, 1333–1343.
Dupre, B., Viers, J., Dandurand, J.-L., Polve, M., Benezeth, P., Vervier, P., and Braun, J.-J., 1999. Major and trace elements associated with colloids in organic-rich river waters: ultrafiltration of natural and spiked solutions. Chemical Geology, 160, 63–80.
Goldstein, J. I., Scott, E. R. D., and Chabot, N. L., 2009. Iron meteorites: crystallization, thermal history, parent bodies, and origin. Chemie der Erde, 69, 293–325.
Gross, J. L., and Thoennessen, M., 2012. Discovery of gallium, germanium, lutetium, and hafnium isotopes. Atomic Data and Nuclear Data Tables, 98, 983–1002.
Humayun, M., 2012. Chondrule cooling rates inferred from diffusive profiles in metal lumps from the Acfer 097 CR2 chondrite. Meteoritics & Planetary Science, 47, 1191–1208.
Jenner, F. E., and O’Neill, H. St. C., 2012. Analysis of 60 elements in 616 ocean floor basaltic glasses. Geochemistry, Geophysics, Geosystems, 13, Q02005. doi:10.1029/2011GC004009.
Johnson, K., 2016. Periodic table of elements in the ocean. Monterey Bay Aquarium Research Institute. Available at http://www.mbari.org/science/upper-ocean-systems/chemical-sensor-group/periodic-table-of-elements-in-the-ocean. Accessed 18 Jan 2016.
Kato, C., Foriel, J., and Moynier, F., 2014. Isotopic study of gallium in terrestrial and meteoritic samples. In 77th Annual Meeting of the Meteoritical Society, Abstract #5209.
Lodders, K., 2003. Solar system abundances and condensation temperatures of the elements. The Astrophysical Journal, 591, 1220–1247.
McDonough, W. F., and Sun, S.-S., 1995. The composition of the Earth. Chemical Geology, 120, 223–253.
Mittlefehldt, D. W., McCoy, T. J., Goodrich, C. A., and Kracher, A., 1998. Non-chondritic meteorites from asteroidal bodies. In Papike, J. J. (ed.) Planetary Materials, Reviews in Mineralogy, 36, 195 pp.
Orians, K. J., and Bruland, K. W., 1988. The marine geochemistry of dissolved gallium: a comparison with dissolved aluminum. Geochimica et Cosmochimica Acta, 52, 2955–2962.
Righter, K., Campbell, A. J., and Humayun, M., 2005. Diffusion of trace elements in FeNi metal: applications to zoned metal grains in chondrites. Geochimica et Cosmochimica Acta, 69, 3145–3158.
Schulte, R. F., and Foley, N. K., 2013. Compilation of gallium resource data for bauxite deposits. US Geological Survey Open File Report 2013-1272. https://pubs.usgs.gov/of/2013/1272/pdf/ofr2013-1272.pdf
Shiller, A. M., and Frilot, D. M., 1996. The geochemistry of gallium relative to aluminum in California streams. Geochimica et Cosmochimica Acta, 60, 1323–1328.
Wasson, J. T., and Kallemeyn, G. W., 1988. Compositions of chondrites. Philosophical Transactions of the Royal Society of London. Series A, 325, 535–544.
Wasson, J. T., Huber, H., and Malvin, D. J., 2007. Formation of IIAB iron meteorites. Geochimica et Cosmochimica Acta, 71, 760–781.
Wänke, H., Palme, H., Kruse, H., Baddenhausen, H., Cendales, M., Dreibus, G., Hofmeister, H., Jagoutz, E., Palme, C., Spettel, B., and Thacker, R., 1976. Chemistry of lunar highland rocks: A refined evaluation of the composition of primary matter. Proceedings of Lunar Science Conference, 7, 3479–3499.
Yang, S., Humayun, M., Righter, K., Jefferson, G., Fields, D., and Irving, A. J., 2015. Siderophile and chalcophile element abundances in shergottites: Implications for Martian core formation. Meteoritics & Planetary Science, 50, 691–714.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2016 Springer International Publishing Switzerland
About this entry
Cite this entry
Humayun, M. (2016). Gallium. In: White, W. (eds) Encyclopedia of Geochemistry. Encyclopedia of Earth Sciences Series. Springer, Cham. https://doi.org/10.1007/978-3-319-39193-9_246-1
Download citation
DOI: https://doi.org/10.1007/978-3-319-39193-9_246-1
Received:
Accepted:
Published:
Publisher Name: Springer, Cham
Online ISBN: 978-3-319-39193-9
eBook Packages: Springer Reference Earth and Environm. ScienceReference Module Physical and Materials ScienceReference Module Earth and Environmental Sciences