Skip to main content

Gallium

  • Living reference work entry
  • First Online:
Encyclopedia of Geochemistry

Part of the book series: Encyclopedia of Earth Sciences Series ((EESS))

  • 356 Accesses

FormalPara Element Data

Atomic symbol: Ga

Atomic number: 31

Atomic weight: 69.723 ± 1 g/mol

Isotopes and abundances:69Ga 60.1 %;71Ga 39.9 %

1 Atm melting point: 29.8 °C

1 Atm boiling point: ~2,400 °C

Common valences: +3

Ionic radii values: 47 pm (fourfold); 62 pm (sixfold)

Pauling electronegativity: 1.81

First ionization energy: 174.6 kJ/mol

Chondritic (CI) abundance: 9.5 ± 0.3 μg/g

Silicate Earth abundance: 4.0 μg/g

Crustal abundance: 17.5 μg/g

Seawater abundance: ~1.2 pg/g

Core abundance: <1 μg/g

Properties

Gallium does not occur as a native metal and forms very few minerals like gallite (CuGaS2), but widely occurs in nature as a trace constituent substituted for Al. Gallium metal is prepared as a by-product of aluminum production from bauxite ore and from Zn ores (e.g., sphalerite). Synthetically prepared metallic Ga is a soft, silvery...

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Institutional subscriptions

References

  • Benezeth, P., Diakonov, I. I., Pokrovski, G. S., Dandurand, J.-L., Schott, J., and Khodakovsky, I. L., 1997. Gallium speciation in aqueous solution. Experimental study and modeling: part 2. Solubility of α-GaOOH in acidic solutions from 150 to 250°C and hydrolysis constants of gallium (III) to 300°C. Geochimica et Cosmochimica Acta, 61, 1345–1357.

    Article  Google Scholar 

  • Bennett, R., and Czechowski, F., 1980. Gallium porphyrins in bituminous coal. Nature, 283, 465–467.

    Article  Google Scholar 

  • Blanchard, I., Badro, J., Siebert, J., and Ryerson, F. J., 2015. Composition of the core from gallium metal-silicate partitioning experiments. Earth and Planetary Science Letters, 427, 191–201.

    Article  Google Scholar 

  • Bowen, H. J. M., 1982. Chapter 12, Boron, aluminum, gallium, indium thallium. In Environmental Chemistry. London: Royal Society of Chemistry, Vol. 2, pp. 159–161.

    Chapter  Google Scholar 

  • Campbell, A. J., and Humayun, M., 2005. Compositions of group IVB iron meteorites and their parent melt. Geochimica et Cosmochimica Acta, 69, 4733–4744.

    Article  Google Scholar 

  • Chabot, N. L., Wollack, E. A., Humayun, M., and Shank, E. M., 2015. The effect of oxygen as a light element in metallic liquids on partitioning behavior. Meteoritics & Planetary Science, 50, 530–546.

    Article  Google Scholar 

  • Chitamber, C. R., 2010. Medical applications and toxicities of gallium compounds. International Journal of Environmental Research and Public Health, 7, 2337–2361.

    Article  Google Scholar 

  • Clayton, D. D., 2003. Handbook of Isotopes in the Cosmos: Hydrogen to Gallium. Cambridge, UK: Cambridge University Press, 326 pp.

    Book  Google Scholar 

  • Davis, F. A., Humayun, M., Hirschmann, M. M., and Cooper, R. S., 2013. Experimentally determined mineral/melt partitioning of first-row transition elements (FRTE) during partial melting of peridotite at 3 GPa. Geochimica et Cosmochimica Acta, 104, 232–260.

    Article  Google Scholar 

  • Diakonov, I. I., Pokrovski, G. S., Benezeth, P., Schott, J., Dandurand, J.-L., and Escalier, J., 1997. Gallium speciation in aqueous solution. Experimental study and modeling: part 1. Thermodynamic properties of Ga(OH)4 − to 300°C. Geochimica et Cosmochimica Acta, 61, 1333–1343.

    Article  Google Scholar 

  • Dupre, B., Viers, J., Dandurand, J.-L., Polve, M., Benezeth, P., Vervier, P., and Braun, J.-J., 1999. Major and trace elements associated with colloids in organic-rich river waters: ultrafiltration of natural and spiked solutions. Chemical Geology, 160, 63–80.

    Article  Google Scholar 

  • Goldstein, J. I., Scott, E. R. D., and Chabot, N. L., 2009. Iron meteorites: crystallization, thermal history, parent bodies, and origin. Chemie der Erde, 69, 293–325.

    Article  Google Scholar 

  • Gross, J. L., and Thoennessen, M., 2012. Discovery of gallium, germanium, lutetium, and hafnium isotopes. Atomic Data and Nuclear Data Tables, 98, 983–1002.

    Article  Google Scholar 

  • Humayun, M., 2012. Chondrule cooling rates inferred from diffusive profiles in metal lumps from the Acfer 097 CR2 chondrite. Meteoritics & Planetary Science, 47, 1191–1208.

    Article  Google Scholar 

  • Jenner, F. E., and O’Neill, H. St. C., 2012. Analysis of 60 elements in 616 ocean floor basaltic glasses. Geochemistry, Geophysics, Geosystems, 13, Q02005. doi:10.1029/2011GC004009.

    Google Scholar 

  • Johnson, K., 2016. Periodic table of elements in the ocean. Monterey Bay Aquarium Research Institute. Available at http://www.mbari.org/science/upper-ocean-systems/chemical-sensor-group/periodic-table-of-elements-in-the-ocean. Accessed 18 Jan 2016.

  • Kato, C., Foriel, J., and Moynier, F., 2014. Isotopic study of gallium in terrestrial and meteoritic samples. In 77th Annual Meeting of the Meteoritical Society, Abstract #5209.

    Google Scholar 

  • Lodders, K., 2003. Solar system abundances and condensation temperatures of the elements. The Astrophysical Journal, 591, 1220–1247.

    Article  Google Scholar 

  • McDonough, W. F., and Sun, S.-S., 1995. The composition of the Earth. Chemical Geology, 120, 223–253.

    Article  Google Scholar 

  • Mittlefehldt, D. W., McCoy, T. J., Goodrich, C. A., and Kracher, A., 1998. Non-chondritic meteorites from asteroidal bodies. In Papike, J. J. (ed.) Planetary Materials, Reviews in Mineralogy, 36, 195 pp.

    Google Scholar 

  • Orians, K. J., and Bruland, K. W., 1988. The marine geochemistry of dissolved gallium: a comparison with dissolved aluminum. Geochimica et Cosmochimica Acta, 52, 2955–2962.

    Article  Google Scholar 

  • Righter, K., Campbell, A. J., and Humayun, M., 2005. Diffusion of trace elements in FeNi metal: applications to zoned metal grains in chondrites. Geochimica et Cosmochimica Acta, 69, 3145–3158.

    Article  Google Scholar 

  • Schulte, R. F., and Foley, N. K., 2013. Compilation of gallium resource data for bauxite deposits. US Geological Survey Open File Report 2013-1272. https://pubs.usgs.gov/of/2013/1272/pdf/ofr2013-1272.pdf

  • Shiller, A. M., and Frilot, D. M., 1996. The geochemistry of gallium relative to aluminum in California streams. Geochimica et Cosmochimica Acta, 60, 1323–1328.

    Article  Google Scholar 

  • Wasson, J. T., and Kallemeyn, G. W., 1988. Compositions of chondrites. Philosophical Transactions of the Royal Society of London. Series A, 325, 535–544.

    Article  Google Scholar 

  • Wasson, J. T., Huber, H., and Malvin, D. J., 2007. Formation of IIAB iron meteorites. Geochimica et Cosmochimica Acta, 71, 760–781.

    Article  Google Scholar 

  • Wänke, H., Palme, H., Kruse, H., Baddenhausen, H., Cendales, M., Dreibus, G., Hofmeister, H., Jagoutz, E., Palme, C., Spettel, B., and Thacker, R., 1976. Chemistry of lunar highland rocks: A refined evaluation of the composition of primary matter. Proceedings of Lunar Science Conference, 7, 3479–3499.

    Google Scholar 

  • Yang, S., Humayun, M., Righter, K., Jefferson, G., Fields, D., and Irving, A. J., 2015. Siderophile and chalcophile element abundances in shergottites: Implications for Martian core formation. Meteoritics & Planetary Science, 50, 691–714.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Munir Humayun .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2016 Springer International Publishing Switzerland

About this entry

Cite this entry

Humayun, M. (2016). Gallium. In: White, W. (eds) Encyclopedia of Geochemistry. Encyclopedia of Earth Sciences Series. Springer, Cham. https://doi.org/10.1007/978-3-319-39193-9_246-1

Download citation

  • DOI: https://doi.org/10.1007/978-3-319-39193-9_246-1

  • Received:

  • Accepted:

  • Published:

  • Publisher Name: Springer, Cham

  • Online ISBN: 978-3-319-39193-9

  • eBook Packages: Springer Reference Earth and Environm. ScienceReference Module Physical and Materials ScienceReference Module Earth and Environmental Sciences

Publish with us

Policies and ethics