Abstract
Dielectric capacitors are ubiquitous in electronics and electric power systems as basic electrical component for power energy storage, in which the energy stored is limited by the dielectric constant and electric breakdown strength of the dielectric material employed. Realization of high-energy-density in capacitors hence relies on the development of advanced dielectric materials. Inorganic dielectric materials, while enjoying high dielectric constant, suffer from low breakdown strength. On the other hand, polymer dielectrics possess excellent processability, high breakdown strength, and graceful failure mechanism but have dielectric constant that are orders of magnitude smaller than those of their inorganic counterparts. Recent advancements in the research area of dielectric materials are represented by integration of the complementary advantages of inorganic and organic dielectric materials which creates the polymer nanocomposite dielectrics. In this chapter we summarize the recent progress in polymer nanocomposites for dielectric power energy storage.
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References
Pikul JH, Zhang HG, Cho J, Braun PV, King WP (2013) High-power lithium ion microbatteries from interdigitated three-dimensional bicontinuous nanoporous electrodes. Nat Commun 4:1732
El-Kady MF, Strong V, Dubin S, Kaner RB (2012) Laser scribing of high-performance and flexible graphene-based electrochemical capacitors. Science 335:1326–1330
Wu ZS, Parves K, Feng XL, Müllen K (2013) Graphene-based in-plane micro-supercapacitors with high power and energy densities. Nat Commun 4:2487
Burke A (2007) R&D considerations for the performance and application of electrochemical capacitors. Electrochim Acta 53:1083–1091
Dang ZM, Wu JB, Fan LZ, Nan CW (2003) Dielectric behavior of Li and Ti co-doped NiO/PVDF composites. Chem Phys Lett 376:389–394
Subodh G, Deepu V, Mohanan P, Sebastian MT (2009) Dielectric response of high permittivity polymer ceramic composite with low loss tangent. Appl Phys Lett 95:062903
Zhou X, Zhao XH, Suo ZG, Zou C, Runt J, Liu S, Zhang SH, Zhang QM (2009) Electrical breakdown and ultrahigh electrical energy density in poly(vinylidene fluoride-hexafluoropropylene) copolymer. Appl Phys Lett 94:162901
Parvatikar N, Ambika Prasad MVN (2006) Frequency-dependent conductivity and dielectric permittivity of polyaniline/CeO2 composites. J Appl Polym Sci 100:1403–1405
Afzal AB, Akhtar MJ, Nadeem M, Hassan MM (2009) Investigation of structural and electrical properties of polyaniline/gold nanocomposites. J Phys Chem C 113:17560–17565
Schroeder R, Majewski LA, Grell M (2005) High-performance organic transistors using solution-processed nanoparticle-filled high-k polymer gate insulators. Adv Mater 17:1535–1539
Ginzburg VV, Myers K, Malowinski S, Cieslinski R, Elwell M, Bernius M (2006) High-dielectric-constant self-assembled nodular structures in polymer/gold nanoparticle films. Macromolecules 39:3901–3906
Guo N, DiBenedetto SA, Tewari P, Lanagan MT, Ratner MA, Marks TJ (2010) Nanoparticle, size, shape, and interfacial effects on leakage current density, permittivity, and breakdown strength of metal oxide−polyolefin nanocomposites: experiment and theory. Chem Mater 22:1567–1578
Love GR (1990) Energy storage in ceramic dielectric. J Am Ceram Soc 73:323–328
Cao Y, Irwin PC, Younsi K (2004) The future of nanodielectrics in the electric power industry. IEEE Trans Dielectr Electr Insul 11:797–807
Rabuffi M, Picci G (2002) Status quo and future prospects for metallized polypropylene energy storage capacitors. IEEE Trans Plasma Sci 30:1939–1942
Chu BJ, Zhou X, Ren KL, Neese B, Lin MR, Wang Q, Bauer F, Zhang QM (2006) A dielectric polymer with high electric energy density and fast discharge speed. Science 313:334–336
Ho J, Jow TR (2012) High field conduction in biaxially oriented polypropylene at elevated temperature. IEEE Trans Dielectr Electr Insul 19:990–995
Levy O, Stroud D (1997) Maxwell Garnett theory for mixtures of anisotropic inclusions: application to conducting polymers. Phys Rev B 56:8035
Nan CW, Shen Y, Ma J (2010) Physical properties of composites near percolation. Annu Rev Mater Res 40:131
Wang Q, Zhu L (2011) Polymer nanocomposites for electrical energy storage. J Polym Sci B Polym Phys 49:1421–1429
Dang ZM, Yuan JK, Yao SH, Liao RJ (2013) Flexible nanodielectric materials with high permittivity for power energy storage. Adv Mater 25:6334–6365
Li J, Seok SI, Chu B, Dogan F, Zhang Q, Wang Q (2009) Nanocomposites of ferroelectric polymers with TiO2 nanoparticles exhibiting significantly enhanced electrical energy density. Adv Mater 21:217
Li J, Claude J, Norena-Franco LE, Il Seok S, Wang Q (2008) Electrical energy storage in ferroelectric polymer nanocomposites containing surface-functionalized BaTiO3 nanoparticles. Chem Mater 20:6304
Kim P, Doss NM, Tillotson JP, Hotchkiss PJ, Pan MJ, Marder SR, Li J, Calame JP, Perry JW (2009) High energy density nanocomposites based on surface-modified BaTiO3 and a ferroelectric polymer. ACS Nano 3:2581
Kim P, Jones SC, Hotchkiss PJ, Haddock JN, Kippelen B, Marder SR, Perry JW (2007) Phosphonic acid-modified barium titanate polymer nanocomposites with high permittivity and dielectric strength. Adv Mater 19:1001–1005
Li Z, Fredin LA, Tewari P, DiBenedetto SA, Lanagan MT, Ratner MA, Marks TJ (2010) In situ catalytic encapsulation of core-shell nanoparticles having variable shell thickness: dielectric and energy storage properties of high-permittivity metal oxide nanocomposites. Chem Mater 22:5154
Li J, Khanchaitit P, Han K, Wang Q (2010) New route toward high-energy-density nanocomposites based on chain-end functionalized ferroelectric polymers. Chem Mater 22:5350
Deng Y, Zhang Y, Xiang Y, Wang G, Xu H (2009) Bi2S3–BaTiO3/PVDF three-phase composites with high dielectric permittivity. J Mater Chem 19:2058
Huang X, Xie L, Jiang P, Wang G, Liu F (2009) Electrical, thermophysical and micromechanical properties of ethylene-vinyl acetate elastomer composites with surface modified BaTiO3 nanoparticles. J Phys D Appl Phys 42:245407
Jung HM, Kang JH, Yang SY, Won JC, Kim YS (2010) Barium titanate nanoparticles with diblock copolymer shielding layers for high-energy density nanocomposites. Chem Mater 22:450
Dang ZM, Wang HY, Xu HP (2006) Influence of silane coupling agent on morphology and dielectric property in BaTiO3/polyvinylidene fluoride composites. Appl Phys Lett 89:112902
Song Y, Shen Y, Liu H, Lin Y, Li M, Nan CW (2012) Enhanced dielectric and ferroelectric properties induced by dopamine-modified BaTiO3 nanofibers in flexible poly(vinylidene fluoride-trifluoroethylene) nanocomposites. J Mater Chem 22:8063
Song Y, Shen Y, Liu H, Lin Y, Li M, Nan CW (2012) Improving the dielectric constants and breakdown strength of polymer composites: effects of the shape of the BaTiO3 nanoinclusions, surface modification and polymer matrix. J Mater Chem 22:16491
Tuncer E, Sauers I, James DR, Ellis AR, Duckworth RC (2008) Electrical properties of percolative polystyrene/carbon nanofiber composites. IEEE Trans Dielectr Electr Insul 15:236
Dou XL, Liu XL, Zhang Y, Feng H, Chen JF, Du S (2009) Improved dielectric strength of barium titanate-polyvinylidene fluoride nanocomposite. Appl Phys Lett 95:132904
Dang ZM, Zhou T, Yao SH, Yuan JK, Zha JW, Song HT, Li JY, Chen Q, Yang WT, Bai J (2009) Advanced calcium copper titanate/polyimide functional hybrid films with high dielectric permittivity. Adv Mater 21:2077
Yang W, Yu S, Sun R, Du R (2011) Nano- and microsize effect of CCTO fillers on the dielectric behavior of CCTO/PVDF composites. Acta Mater 59:5593
Prakash BS, Varma KBR (2007) Dielectric behavior of CCTO/epoxy and Al-CCTO/epoxy composites. Compos Sci Technol 67:2363
Amaral F, Rubinger CPL, Henry F, Costa LC, Valente MA, Barros-Timmons A (2008) Dielectric properties of polystyrene–CCTO composite. J Non Cryst Solids 354:5321
Tang HX, Lin YR, Andrews C, Sodano HA (2011) Nanocomposites with increased energy density through high aspect ratio PZT nanowires. Nanotechnology 22:015702
Yao J, Xiong C, Dong L, Chen C, Lei Y, Chen L, Li R, Zhu Q, Liu X (2009) Enhancement of dielectric constant and piezoelectric coefficient of ceramic–polymer composites by interface chelation. J Mater Chem 19:2817
Banerjee S, Cook-Chennault KA (2011) Influence of Al particle size and lead zirconate titanate (PZT) volume fraction on the dielectric properties of PZT-epoxy-aluminum composites. J Eng Mater Technol 133:041016
Tang H, Lin Y, Sodano HA (2012) Enhanced energy storage in nanocomposite capacitors through aligned PZT nanowires by uniaxial strain assembly. Adv Energy Mater 2:469
Yu K, Wang H, Zhou Y, Bai Y, Niu Y (2013) Enhanced dielectric properties of BaTiO3/poly(vinylidene fluoride) nanocomposites for energy storage applications. J Appl Phys 113:034105
Tomer V, Polizos G, Manias E, Randall CA (2010) Epoxy-based nanocomposites for electrical energy storage. I: effects of montmorillonite and barium titanate nanofillers. J Appl Phys 108:074116
Xia WM, Xu Z, Wen F, Zhang ZC (2012) Electrical energy density and dielectric properties of poly (vinylidene fluoride-chlorotrifluoroethylene)/BaSrTiO3 nanocomposites. Ceram Int 38:1071–1075
Ducharme S (2009) An inside-out approach to storing electrostatic energy. ACS Nano 3:2447
Guo N, DiBenedetto SA, Kwon DK, Wang L, Russell MT, Lanagan MT, Facchetti A, Marks TJ (2007) Supported metallocene catalysis for in situ synthesis of high energy density metal oxide nanocomposites. J Am Chem Soc 129:766
Xie L, Huang X, Wu C, Jiang P (2011) Core-shell structured poly(methyl methacrylate)/BaTiO3 nanocomposites prepared by in situ atom transfer radical polymerization: a route to high dielectric constant materials with the inherent low loss of the base polymer. J Mater Chem 21:5897
Paniagua SA, Kim YS, Henry K, Kumar R, Perry JW, Marder SR (2014) Surface-initiated polymerization from barium titanate nanoparticles for hybrid dielectric capacitors. ACS Appl Mater Interfaces 6:3477
Yang K, Huang XY, Xie LY, Wu C, Jiang PK, Tanaka T (2012) Core-shell structured polystyrene/BaTiO3 hybrid nanodielectrics prepared by in situ RAFT polymerization: a route to high dielectric constant and low loss materials with weak frequency dependence. Macromol Rapid Comm 33:1921
Xie LY, Huang XY, Yang K, Li ST, Jiang PK (2014) “Grafting to” route to PVDF-HFP-GMA/BaTiO3 nanocomposites with high dielectric constant and high thermal conductivity for energy storage and thermal management applications. J Mater Chem A 2:5244–5251
Tchoul MN, Fillery SP, Koerner H, Drummy LF, Oyerokun FT, Mirau PA, Durstock MF, Vaia RA (2010) Assemblies of titanium dioxide-polystyrene hybrid nanoparticles for dielectric applications. Chem Mater 22:1749
Maliakal A, Katz H, Cotts P, Subramoney S, Mirau P (2005) Inorganic oxide core, polymer shell nanocomposite as a high K gate dielectric for flexible electronics applications. J Am Chem Soc 127:14655
Tang HX, Lin YR, Sodano HA (2013) Synthesis of high aspect ratio BaTiO3 nanowires for high energy density nanocomposite capacitors. Adv Energy Mater 3:451–456
Tang HX, Sodano HA (2013) Ultra high energy density nanocomposite capacitors with fast discharge using Ba0.2Sr0.8TiO3nanowires. Nano Lett 13:1373–1379
Tang HX, Sodano HA (2013) High energy density nanocomposite capacitors using non-ferroelectric nanowires. Appl Phys Lett 102:063901
Zhou Z, Tang HX, Lin YR, Sodano HA (2013) Hydrothermal growth of textured BaxSr1-xTiO3 films composed of nanowires. Nanoscale 5:10901–10907
Zou C, Kushner D, Zhang S (2011) Wide temperature polyimide/ZrO2 polyimide/ZrO2 nanodielectric capacitor film with excellent electrical performance. Appl Phys Lett 98:082905
Balasubramanian B, Kraemer KL, Reding NA, Skomski R, Ducharme S, Sellmyer DJ (2010) Synthesis of monodisperse TiO2-paraffin core-shell nanoparticles for improved dielectric properties. ACS Nano 4:1893
Lin S, Kuang X, Wang F, Zhu H (2012) Effect of TiO2 crystalline composition on the dielectric properties of TiO2/P(VDF-TrFE) composites. Phys Status Solidi RRL 6:352
Ouyang G, Wang K, Chen XY (2012) TiO2 nanoparticles modified polydimethylsiloxane with fast response time and increased dielectric constant. J Micromech Microeng 22:074002
Dang ZM, Xia YJ, Zha JW, Yuan JK, Bai J (2011) Preparation and dielectric properties of surface modified TiO2/silicone rubber nanocomposites. Mater Lett 65:3430
Zha JW, Dang ZM, Zhou T, Song HT, Chen G (2010) Electrical properties of TiO2-filled polyimide nanocomposite films prepared via an in situ polymerization process. Synth Met 160:2670
Zha JW, Fan BH, Dang ZM, Li ST, Chen G (2010) Microstructure and electrical properties in three-component (Al2O3–TiO2)/polyimide nanocomposite films. J Mater Res 25:2384
McCarthy DN, Stoyanov H, Rychkov D, Ragusch H, Melzer M, Kofod G (2012) Increased permittivity nanocomposite dielectrics by controlled interfacial interactions. Compos Sci Technol 72:731
Nan CW (1993) Physics of inhomogeneous inorganic materials. Prog Mater Sci 37:1
Huang XY, Jiang PK, Kim CU (2007) Electrical properties of polyethylene/aluminum nanocomposites. J Appl Phys 102:124103
Panda M, Srinivas V, Thakur AK (2011) Role of polymer matrix in large enhancement of dielectric constant in polymer-metal composites. Appl Phys Lett 99:042905
Dang ZM, Lin YH, Nan CW (2003) Novel ferroelectric polymer composites with high dielectric constants. Adv Mater 15:1625
Panda M, Srinivas V, Thakur AK (2008) On the question of percolation threshold in polyvinylidene fluoride/nanocrystalline nickel composites. Appl Phys Lett 92:132905
Huang XY, Jiang PK, Xie LY (2009) Ferroelectric polymer/silver nanocomposites with high dielectric constant and high thermal conductivity. Appl Phys Lett 95:242901
Panda M, Srinivas V, Thakur AK (2008) Surface and interfacial effect of filler particle on electrical properties of polyvinyledene fluoride/nickel composites. Appl Phys Lett 93:242908
Kofod G, Risse S, Stoyanov H, McCarthy DN, Sokolov S, Kraehnert R (2011) Broad-spectrum enhancement of polymer composite dielectric constant at ultralow volume fractions of silica-supported copper nanoparticles. ACS Nano 5:1623
Shen Y, Lin YH, Li M, Nan CW (2007) High dielectric performance of polymer composite films induced by a percolating interparticle barrier layer. Adv Mater 19:1418–1422
Fredin LA, Li Z, Lanagan MT, Ratner MA, Marks TJ (2013) Substantial recoverable energy storage in percolative metallic aluminum-polypropylene nanocomposites. Adv Funct Mater 23:3560–3569
Yao SH, Dang ZM, Jiang MJ, Xu HP, Bai JB (2007) Influence of aspect ratio of carbon nanotube on percolation threshold in ferroelectric polymer nanocomposite. Appl Phys Lett 91:212901
Dang ZM, Wang L, Yin Y, Zhang Q, Lei QQ (2007) Giant dielectric permittivities in functionalized carbon-nanotube/electroactive-polymer nanocomposites. Adv Mater 19:852
Wang L, Dang ZM (2005) Carbon nanotube composites with high dielectric constant at low percolation threshold. Appl Phys Lett 87:042903
Li Q, Xue QZ, Hao LZ, Gao XL, Zheng QB (2008) Large dielectric constant of the chemically functionalized carbon nanotube/polymer composites. Compos Sci Technol 68:2290
Yao SH, Dang ZM, Xu HP, Jiang MJ, Bai J (2008) Exploration of dielectric constant dependence on evolution of microstructure in nanotube/ferroelectric polymer nanocomposites. Appl Phys Lett 92:082902
Chang J, Liang G, Gu A, Cai S, Yuan L (2012) The production of carbon nanotube/epoxy composites with a very high dielectric constant and low dielectric loss by microwave curing. Carbon 50:689
Simoes R, Silva J, Vaia R, Sencadas V, Costa P, Gomes J, Lanceros-Mendez S (2009) Low percolation transitions in carbon nanotube networks dispersed in a polymer matrix: dielectric properties, simulations and experiments. Nanotechnology 20:035703
Yuan JK, Yao SH, Sylvestre A, Bai J (2012) Biphasic polymer blends containing carbon nanotubes: heterogeneous nanotube distribution and its influence on the dielectric properties. J Phys Chem C 116:2051
Yuan JK, Yao SH, Dang ZM, Sylvestre A, Genestoux M, Bai J (2011) Giant dielectric permittivity nanocomposites: realizing true potential of pristine carbon nanotubes in polyvinylidene fluoride matrix through an enhanced interfacial interaction. J Phys Chem C 115:5515
Yuan JK, Li WL, Yao SH, Lin YQ, Sylvestre A, Bai J (2011) High dielectric permittivity and low percolation threshold in polymer composites based on SiC-carbon nanotubes micro/nano hybrid. Appl Phys Lett 98:032901
Zhang S, Wang H, Wang G, Jiang Z (2012) Material with high dielectric constant, low dielectric loss, and good mechanical and thermal properties produced using multi-wall carbon nanotubes wrapped with poly(ether sulphone) in a poly(ether ether ketone) matrix. Appl Phys Lett 101:012904
Wu C, Huang X, Wu X, Yu J, Xie L, Jiang P (2012) TiO2-nanorod decorated carbon nanotubes for high-permittivity and low-dielectric-loss polystyrene composites. Compos Sci Technol 72:521
Sun LL, Li B, Zhao Y, Mitchell G, Zhong WH (2010) Structure-induced high dielectric constant and low loss of CNF/PVDF composites with heterogeneous CNF distribution. Nanotechnology 21:305702
Sun LL, Zhao Y, Zhong WH (2011) Dependence of dielectric properties and percolative behavior on phase separation structure induced by heterogeneous carbon nanofiber distribution in polymer blend nanocomposites. Macromol Mater Eng 296:992
Barick AK, Tripathy DK (2012) Preparation and characterization of carbon nanofiber reinforced thermoplastic polyurethane nanocomposites. J Appl Polym Sci 124:765
Sun LL, Zhang ZG, Zhong WH (2011) Fluorination deposition on carbon nanofibers by PTFE decomposition as a facile method to enhance dispersion and interaction in PVDF composites. J Mater Chem 21:944
He F, Lau S, Chan HL, Fan JT (2009) High dielectric permittivity and low percolation threshold in nanocomposites based on poly(vinylidene fluoride) and exfoliated graphite nanoplates. Adv Mater 21:710
Yu J, Huang X, Wu C, Jiang P (2011) Permittivity, thermal conductivity and thermal stability of poly(vinylidene fluoride)/graphene nanocomposites. IEEE Trans Dielectr Electr Insul 18:478
Han K, Li Q, Chen ZY, Gadinski MR, Dong LJ, Xiong CX, Wang Q (2013) Suppression of energy dissipation and enhancement of breakdown strength in ferroelectric polymer–graphene percolative composites. J Mater Chem C 1:7034–7042
Fan P, Wang L, Yang J, Chen F, Zhong M (2012) Graphene/poly(vinylidene fluoride) composites with high dielectric constant and low percolation threshold. Nanotechnology 23:365702
Wu C, Huang X, Wang G, Wu X, Yang K, Li S, Jiang P (2012) Hyperbranched-polymer functionalization of graphene sheets for enhanced mechanical and dielectric properties of polyurethane composites. J Mater Chem 22:7010
Wang DR, Bao YR, Zha JW, Zhao J, Dang ZM, Hu GH (2012) Improved dielectric properties of nanocomposites based on poly(vinylidene fluoride) and poly(vinyl alcohol)-functionalized graphene. ACS Appl Mater Interfaces 4:6273–6279
Roy M, Nelson JK, McCrone RK, Schadler LS, Reed CW, Keefe R, Zeneger W (2005) Polymer nanocomposite dielectrics—the role of the interface. IEEE Trans Dielectr Electr Insul 12:629–643
Takala M, Ranta H, Nevalainen P, Pakonen P, Pelto J, Karttunen M, Virtanen S, Koivu V, Pettersson M, Sonerud B, Kannus K (2010) Dielectric properties and partial discharge endurance of polypropylene-silica nanocomposite. IEEE Trans Dielectr Electr Insul 17:1259–1267
Tomer V, Manias E, Randall CA (2011) High field properties and energy storage in nanocomposite dielectrics of poly(vinylidene fluoride-hexafluoropropylene). J Appl Phys 110:044107
Tomer V, Polizos G, Randall CA, Manias E (2011) Polyethylene nanocomposite dielectrics: implications of nanofiller orientation on high field properties and energy storage. J Appl Phys 109:074113
Fillery SP, Koerner H, Drummy L, Dunkerley E, Durstock MF, Schmidt DF, Vaia RA (2012) Nanolaminates: increasing dielectric breakdown strength of composites. ACS Appl Mater Interfaces 4:1388–1396
Hu PH, Shen Y, Guan YH, Zhang XH, Lin YH, Zhang QM, Nan CW (2014) Topological-structure modulated polymer nanocomposites exhibiting highly enhanced dielectric strength and energy density. Adv Funct Mater 24:3172–3178
Zhang X, Shen Y, Zhang QH, Gu L, Hu YH, Du JW, Lin YH, Nan CW (2015) Ultrahigh energy density of polymer nanocomposites containing BaTiO3@TiO2 nanofibers by atomic-scale interface engineering. Adv Mater 27:819–824
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Li, Q., Wang, Q. (2016). Polymer Nanocomposites for Power Energy Storage. In: Huang, X., Zhi, C. (eds) Polymer Nanocomposites. Springer, Cham. https://doi.org/10.1007/978-3-319-28238-1_6
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