Abstract
The probable importance of NO and NO2 in controlling the ozone concentrations and production rates in the stratosphere is pointed out. Observations on and determinations of nitric acid concentrations in the stratosphere by Murcray et al. (1968) and Rhine et al. (1969) support the high NO and NO2 concentrations indicated by Bates/Hays (1967). Some processes which may lead to production of nitric acid are discussed. The importance of O (1S), possibly produced in the ozone photolysis below 2340 Å, on the ozone photochemistry is mentioned.
This manuscript was first published as: “The influence of nitrogen oxides on the atmospheric ozone content” in: Quaterly Journal of the Royal Meteorological Society, Vol. 96, No. 408, April 1970: 320–325. Wiley Online Library grants its authors the free republication of their texts.
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References
Bates, D.R.; Hays, P.B., 1967: “Atmospheric Nitrous Oxide”, in: Planetary and Space Science, 150: 189–197.
Baulch, D.L.; Drysdale, D.D.; Lloyd, A.C., 1969: “High Temperature Reaction Rate Data”, Report No. 3, (Leeds: Department of Physical Chemistry, The University).
Benson, S.W.; Axworthy, A.E., 1965: “Reconsiderations of the Rate Constants from the Thermal Decomposition of Ozone”, in: Journal of Chemical Physics, 42,2: 614–2,615.
Brewer, A.W.; Wilson, A.W., 1965: “Measurements of Solar Ultraviolet Radiation in the Stratosphere”, in: Quarterly Journal of the Royal Meteorological Society, 91: 452–461.
Crutzen, P.J., 1969: “Determination of Parameters Appearing in the ‘Dry’ and ‘Wet’ Photochemical Theories for Ozone in the Stratosphere”, in: Tellus, 21: 368–388.
Dalmon, M.R., 1943: Recherches sur l’acide nitrique et ses solutions par les spectres d’absorption dans 1’ultraviolet’ Thèses présentées à la faculté des sciences de l’université de Paris.
Detwiler, C.R.; Garret, D.L.; Purcell, J.D.; Tousey, R., 1961: “The Intensity Distribution in the Ultraviolet Solar Spectrum”, in: Annals of Geophysics, 17: 263–272.
Dütsch, H.U., 1964: “Uniform Evaluation of Umkehr Observations from the World Network”, Part III, N.C.A.R., Boulder: Colorado.
Hampson, J., 1965: “Chemiluminescent Emission Observed in the Stratosphere and Mesosphere”, Les problèmes météorologiques de la stratosphère et de la mésosphère, Presses Universitaires de France: 393–440.
Hunt, B.G., 1966: “Photochemistry of Ozone in a Moist Atmosphere”, in: Journal of Geophysical Research, 71: 1385–1398.
Johnson, F.S., 1954: “The Solar Constant”, in: Journal of Meteorological, 11: 431–439.
Kaufman, F., 1969: “Neutral Reactions Involving Hydrogen and Other Minor Constituents”, in: Canadian Journal of Chemistry, 47: 1917–1927.
Leighton, P.A., 1961: Photochemistry of Air Pollution (New York: Academic Press).
Murcray, D.G.; Kyle, T.G.; Murcray, F.H.; Williams, W.J., 1968: “Nitric Acid and Nitric Oxide in the Lower Stratosphere”, in: Nature, 218: 78–79.
Nicolet, M., 1965: “Nitrogen Oxides in the Chemosphere”, in: Journal of Geophysical Research, 70: 679–689.
Rhine, P.E.; Tubbs, L.D.; Dudley, Williams, 1969: “Nitric Acid Vapour Above 19 km in the Earth’s Atmosphere”, in: Application for Optics, 8: 1500–1501.
Schiff, H.I., 1969: “Neutral Reactions Involving Oxygen and Nitrogen”, in: Canadian Journal of Chemistry, 47: 1903–1916.
Schofield, K., 1967: “An Evaluation of Kinetic Rate Data for Reactions of Neutrals of Atmospheric Interest”, in: Planetary and Space Science, 15: 643–670.
Vigroux, E., 1953: “Contribution à l’étude expérimental de l’absorption de l’ozone”, in: Annales de Physique, 8: 709–763.
Zipf, E.C., 1969: “The Collisional Deactivation of Metastable Atoms and Molecules in the Upper Atmosphere”, in: Canadian Journal of Chemistry, 47: 1863–1870.
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Crutzen, P.J. (2016). The Influence of Nitrogen Oxides on Atmospheric Ozone Content. In: Crutzen, P., Brauch, H. (eds) Paul J. Crutzen: A Pioneer on Atmospheric Chemistry and Climate Change in the Anthropocene. SpringerBriefs on Pioneers in Science and Practice(), vol 50. Springer, Cham. https://doi.org/10.1007/978-3-319-27460-7_3
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