Abstract
In order to address the depletion of fossil fuels and the serious environmental problems accompanying their combustion and the concomitant CO2 emission, large-scale chemical conversion of CO2 into energy-rich materials would be an ultimate solution, and several reactions have been proposed. There have been a lot of challenges that have to be addressed in this field of research, but several breakthroughs have been achieved in recent 10 years. In this chapter, photocatalytic CO2 reduction systems, which are of particular importance, are reviewed, with a focus on both homogeneous and heterogeneous aspects.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Morris AJ, Meyer GJ, Fujita E (2009) Molecular approaches to the photocatalytic reduction of carbon dioxide for solar fuels. Acc Chem Res 42:1983–1994
Takeda H, Ishitani O (2010) Development of efficient photocatalytic systems for CO2 reduction using mononuclear and multinuclear metal complexes based on mechanistic studies. Coord Chem Rev 254:346–354
Hawecker J, Lehn J-M, Ziessel R (1983) Efficient photochemical reduction of CO2 to CO by visible light irradiation of systems containing Re(bipy)(CO)3X or Ru(bipy) 2+3 –Co2+ combinations as homogeneous catalysts. J Chem Soc Chem Commun 536–538
Yui T, Kan A, Saitoh C, Koike K, Ibusuki T, Ishitani O (2011) Photochemical reduction of CO2 using TiO2: effects of organic adsorbates on TiO2 and deposition of Pd onto TiO2. ACS Appl Mater Interfaces 3:2594–2600
Hori H, Koike K, Ishizuka M, Takeuchi K, Ibusuki T, Ishitani O (1997) Preparation and characterization of [Re(bpy)(CO)3L][SbF6] (L = phosphine, phosphite). J Organomet Chem 530:169–176
Koike K, Hori H, Ishizuka M, Westwell JR, Takeuchi K, Ibusuki T, Enjouji K, Konno H, Sakamoto K, Ishitani O (1997) Key process of the photocatalytic reduction of CO2 using [Re(4,4-X2-bipyridine)(CO)3PR3]+ (X = CH3, H, CF3; PR3 = Phosphorus Ligands): dark reaction of the one-electron-reduced complexes with CO2. Organometallics 16:5724–5729
Hori H, Johnson FPA, Koike K, Ishitani O, Ibusuki T (1996) Efficient photocatalytic CO2 reduction using [Re(bpy)(CO)3{P(OEt)3}]+. J Photochem Photobiol A Chem 96:171–174
Takeda H, Koike K, Inoue H, Ishitani O (2008) Development of an efficient photocatalytic system for CO2 reduction using rhenium(I) complexes based on mechanistic studies. J Am Chem Soc 130:2023–2031
Kutal C, Weber MA, Ferraudi G, Geiger D (1985) A mechanistic investigation of the photoinduced reduction of carbon dioxide mediated by tricarbonylbromo(2,2’-bipyridine)rhenium(I). Organometallics 4:2161–2166
Kalyanasundaram K (1986) Luminescence and redox reactions of the metal-to-ligand charge-transfer excited state of tricarbonylchloro-(polypyridyl)rhenium(I) complexes. J Chem Soc Faraday Trans 2(82):2401–2415
Kutal C, Corbin AJ, Ferraudi G (1987) Further studies of the photoinduced reduction of carbon dioxide mediated by tricarbonylbromo(2,2′-bipyridine)rhenium(I). Organometallics 6:553–557
Smieja JM, Benson EE, Kumar B, Grice KA, Seu CS, Miller AJM, Mayer JM, Kubiak CP (2012) Kinetic and structural studies, origins of selectivity, and interfacial charge transfer in the artificial photosynthesis of CO. Proc Natl Acad Sci 109:15646–15650
Smieja JM, Kubiak CP (2010) Re(bipy-tBu)(CO)3Cl−improved catalytic activity for reduction of carbon dioxide: IR-spectroelectrochemical and mechanistic studies. Inorg Chem 49:9283–9289
Hayashi Y, Kita S, Brunschwig BS, Fujita E (2003) Involvement of a binuclear species with the Re−C(O)O−Re moiety in CO2 reduction catalyzed by tricarbonyl rhenium(I) complexes with diimine ligands: strikingly slow formation of the Re−Re and Re−C(O)O−Re species from Re(dmb)(CO)3S (dmb = 4,4′-Dimethyl-2,2′-bipyridine, S = Solvent). J Am Chem Soc 125:11976–11987
Agarwal J, Fujita E, Schaefer HF III, Muckerman JT (2012) Mechanisms for CO Production from CO2 using reduced rhenium tricarbonyl catalysts. J Am Chem Soc 134:5180–5186
Lehn J-M, Ziessel R (1982) Photochemical generation of carbon monoxide and hydrogen by reduction of carbon dioxide and water under visible light irradiation. Proc Natl Acad Sci 79:701–704
Morimoto T, Nakajima T, Sawa S, Nakanishi R, Imori D, Ishitani O (2013) CO2 capture by a rhenium(I) complex with the aid of triethanolamine. J Am Chem Soc 135:16825–16828
Gholamkhass B, Mametsuka H, Koike K, Tanabe T, Furue M, Ishitani O (2005) Architecture of supramolecular metal complexes for photocatalytic CO2 reduction: Rutheniu−rhenium Bi-and tetranuclear complexes. Inorg Chem 44:2326–2336
Tamaki Y, Morimoto T, Koike K, Ishitani O (2012) Photocatalytic CO2 reduction with high turnover frequency and selectivity of formic acid formation using Ru(II) multinuclear complexes. Proc Natl Acad Sci 109:15673–15678
Bourrez M, Molton F, Chardon-Noblat S, Deronzier A (2012) [Mn(bipyridyl)(CO)3Br]: an abundant metal carbonyl complex as efficient electrocatalyst for CO2 reduction. Angew Chem Int Ed 50:9903–9906
Takeda H, Koizumi H, Okamoto K, Ishitani O (2014) Photocatalytic CO2 reduction using a Mn complex as a catalyst. Chem Commun 50:1491–1493
Pullerits T, Sundström V (1996) Photosynthetic light-harvesting pigment-protein complexes: toward understanding how and why. Acc Chem Res 29:381–389
Alstrum-Acevedo JH, Brennaman MK, Meyer TJ (2005) Chemical approaches to artificial photosynthesis. 2. Inorg Chem 44:6802–6827
Takeda H, Ohashi M, Tani T, Ishitani O, Inagaki S (2010) Enhanced photocatalysis of rhenium(I) complex by light-harvesting periodic mesoporous organosilica. Inorg Chem 49:4554–4559
Maeda K (2011) Photocatalytic water splitting using semiconductor particles: History and recent developments. J Photochem Photobiol C: Reviews 12:237–268
Kohno Y, Tanaka T, Funabiki T, Yoshida S (1997) Photoreduction of carbon dioxide with methane over ZrO2. Chem Lett 993–994
Kohno Y, Ishikawa H, Tanaka T, Funabiki T, Yoshida S (2001) Photoreduction of carbon dioxide by hydrogen over magnesium oxide. Phys Chem Chem Phys 3:1108–1113
Teramura K, Tanaka T, Ishikawa H, Kohno Y, Funabiki T (2004) Photocatalytic reduction of CO2 to CO in the presence of H2 or CH4 as a reductant over MgO. J Phys Chem B 108:346–354
Tsuneoka H, Teramura K, Shishido T, Tanaka T (2010) Adsorbed species of CO2 and H2 on Ga2O3 for the photocatalytic reduction of CO2. J Phys Chem C 114:8892–8898
Iizuka K, Wato T, Miseki Y, Saito K, Kudo A (2011) Photocatalytic reduction of carbon dioxide over Ag cocatalyst-loaded ALa4Ti4O15 (A = Ca, Sr, and Ba) using water as a reducing reagent. J Am Chem Soc 133:20863–20868
Miseki Y, Kato H, Kudo A (2009) Water splitting into H2 and O2 over niobate and titanate photocatalysts with (111) plane-type layered perovskite structure. Energy Environ Sci 2:306–314
Hori Y, Wakabe H, Tsukamoto T, Koga O (1994) Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media. Electrochim Acta 39:1833–1839
Teramura K, Iguchi S, Mizuno Y, Shishido T, Tanaka T (2012) Photocatalytic conversion of CO2 in water over layered double hydroxides. Angew Chem Int Ed 51:8008–8011
Sato S, Morikawa T, Saeki S, Kajino T, Motohiro T (2010) Visible-light-induced selective CO2 reduction utilizing a ruthenium complex electrocatalyst linked to a p-type nitrogen-doped Ta2O5 semiconductor. Angew Chem Int Ed 49:5101–5105
Ishida H, Tanaka K, Tanaka T (1987) Electrochemical CO2 reduction catalyzed by ruthenium complexes [Ru(bpy)2(CO)2]2+ and [Ru(bpy)2(CO)Cl]+. Effect of pH on the formation of CO and HCOO–. Organometallics 6:181–186
Maeda K, Sekizawa K, Ishitani O (2013) A polymeric-semiconductor–metal-complex hybrid photocatalyst for visible-light CO2 reduction. Chem Commun 49:10127–10129
Maeda K, Kuriki R, Zhang M, Wang X, Ishitani O (2014) The effect of the pore-wall structure of carbon nitride on photocatalytic CO2 reduction under visible light. J Mater Chem A 2:15146–15151
Wang X, Maeda K, Thomas A, Takanabe K, Xin G, Carlsson JM, Domen K, Antonietti M (2009) A metal-free polymeric photocatalyst for hydrogen production from water under visible light. Nat Mater 8:76–80
Maeda K, Wang X, Nishihara Y, Lu D, Antonietti M, Domen K (2009) Photocatalytic activities of graphitic carbon nitride powder for water reduction and oxidation under visible light. J Phys Chem C 113:4940–4947
Zhang J, Chen X, Takanabe K, Maeda K, Domen K, Fu X, Antonietti M, Wang X (2010) Synthesis of a carbon nitride structure for visible-light catalysis by copolymerization. Angew Chem Int Ed 49:441–444
Goettmann F, Fischer A, Antonietti M, Thomas A (2006) Chemical synthesis of mesoporous carbon nitrides using hard templates and their use as a metal-free catalyst for friedel-crafts reaction of benzene. Angew Chem Int Ed 45:4467–4471
Sekizawa K, Maeda K, Koike K, Domen K, Ishitani O (2013) Artificial Z-scheme constructed with a supramolecular metal complex and semiconductor for the photocatalytic reduction of CO2. J Am Chem Soc 135:4596–4599
Maeda K, Higashi M, Lu D, Abe R, Domen K (2010) Efficient nonsacrificial water splitting through two-step photoexcitation by visible light using a modified oxynitride as a hydrogen evolution photocatalyst. J Am Chem Soc 132:5858–5868
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2016 Springer International Publishing Switzerland
About this chapter
Cite this chapter
Maeda, K. (2016). Photocatalytic Approach for CO2 Fixation. In: Sugiyama, M., Fujii, K., Nakamura, S. (eds) Solar to Chemical Energy Conversion. Lecture Notes in Energy, vol 32. Springer, Cham. https://doi.org/10.1007/978-3-319-25400-5_10
Download citation
DOI: https://doi.org/10.1007/978-3-319-25400-5_10
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-25398-5
Online ISBN: 978-3-319-25400-5
eBook Packages: EnergyEnergy (R0)