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Calcium Oxalates: Thermodynamic and Kinetic Conditions of Their Formation in the Presence of Organic Components

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Biogenic—Abiogenic Interactions in Natural and Anthropogenic Systems

Part of the book series: Lecture Notes in Earth System Sciences ((LNESS))

Abstract

The paper researches a range of problems related to the peculiarities of calcium oxalate crystallization in the presence of amino acids on the bases of thermodynamic calculations and experimental data. The regularities of phase formation in the system Ca2+–C2O4 2−–H2O–amino acid in a widely variable interval of component concentrations and pH are theoretically researched. The influence of pH on the thermodynamic stability of crystalline compounds is considered. The kinetic parameters of crystallization are determined: the induction period, the rate constant, the order of crystals’ growth, and the influence of amino acids on the kinetics of crystallization of calcium oxalate is established.

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Authors and Affiliations

  1. Omsk F.M. Dostoevsky State University, Omsk, Russia

    Vyacheslav V. Korolkov & Olga A. Golovanova

  2. National Research Tomsk Polytechnic University, Tomsk, Russia

    Marina V. Kuimova

Authors
  1. Vyacheslav V. Korolkov
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  2. Olga A. Golovanova
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  3. Marina V. Kuimova
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Corresponding author

Correspondence to Olga A. Golovanova .

Editor information

Editors and Affiliations

  1. Institute of Earth Sciences, Saint Petersburg State University, Saint Petersburg, Russia

    Olga V. Frank-Kamenetskaya

  2. Department of Geochemistry, Saint Petersburg State University, Saint Petersburg, Russia

    Elena G. Panova

  3. Department of Botany, Saint Petersburg State University, Saint Petersburg, Russia

    Dmitry Yu. Vlasov

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Korolkov, V.V., Golovanova, O.A., Kuimova, M.V. (2016). Calcium Oxalates: Thermodynamic and Kinetic Conditions of Their Formation in the Presence of Organic Components. In: Frank-Kamenetskaya, O., Panova, E., Vlasov, D. (eds) Biogenic—Abiogenic Interactions in Natural and Anthropogenic Systems. Lecture Notes in Earth System Sciences. Springer, Cham. https://doi.org/10.1007/978-3-319-24987-2_37

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