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Based on a three phase, mixed-methods series of investigations, we explore and develop the concept of reactance and related constructs relevant to the (non)adoption of six contrasting pro-environmental behaviors. Using innovative online elicitation methodology (nā€‰=ā€‰342), we develop items for the measurement of the main dimensions of resistance, testing the reliability and validity of these measures in the USA, UK, and Australia (total nā€‰=ā€‰8397). Using an expanded form of the Stages of Change model, we identify areas of resistance most relevant at each point of stage transition, exploring different resistance profiles. We identify practical implications for policy makers and practitioners in pro-environmental marketing, as well as further opportunities for researchers.