Abstract
Aiming at intermediate temperature operation (100–150 °C), composite polymer electrolyte membranes consisting of perfluorosulfonic acid (PFSA) ionomer and inorganic fillers, particularly short-side chain perfluorosulfonic membranes, e.g., Aquivion® membranes with an equivalent weight of 790–850 g eq−1 and their composites with inorganic fillers represent a practical approach to advanced membrane materials. This chapter is devoted to an updated review of the methodologies and materials including their practical applications in direct alcohol fuel cells, water electrolysers, and automotive hydrogen fuel cells. An analysis of the basic operation mechanism of such materials is provided and the characteristic performances achieved under intermediate temperature operation are reviewed. The influence of the surface chemistry and acid–base characteristics of the inorganic fillers is also discussed.
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References
Aricò AS, Siracusano S, Briguglio N et al (2013) Polymer electrolyte membrane water electrolysis: status of technologies and potential applications in combination with renewable power sources. J Appl Electrochem 43:107–118
Aricò AS, Di Blasi A, Brunaccini G et al (2010) Investigation of proton exchange membrane fuel cell stacks for high temperature operation. Fuel Cells 10:1013–1023
Arico AS, Srinivasan S, Antonucci V (2001) DMFCs: from fundamental aspects to technology development. Fuel Cells 1:133–161
Aricò AS, Creti P, Antonucci PL et al (1998) Comparison of ethanol and methanol oxidation in a liquid-feed solid polymer electrolyte fuel cell at high temperature. Electrochem Solid-State Lett 1:66–68
Costamagna P, Srinivasan S (2001) Quantum jumps in the PEMFC science and technology from the 1960s to the year 2000: Part I. Fundamental scientific aspects. J Power Sources 102:242–252
Aricò AS, Baglio V, Antonucci V (2008) Composite membranes for high temperature direct methanol fuel cells. In: Peinemann KV, Nunes SP (eds) Membrane for energy conversion. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, pp 123–168
Aricò AS, Baglio V, Di Blasi A et al (2003) Influence of the acid-base characteristics of inorganic fillers on the high temperature performance of composite membranes in direct methanol fuel cells. Solid State Ionics 161:251–265
Li Q, Jensen JO (2008) Membranes for HT-PEMFC based on acid doped polybenzimidazoles. In: Peinemann KV, Nunes SP (eds) Membrane for energy conversion. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, pp 61–96
Savadogo O (1998) Emerging membranes for electrochemical systems. J New Mater Electrochem Syst 1:47–66
Alberti G, Casciola M (2003) Composite membranes for medium-temperature PEM fuel cells. Annu Rev Mater Res 33:129–154
Ruffmann B, Silva H, Schulte B (2003) Organic/inorganic composite membranes for application in DMFC. Solid State Ionics 162–163:269–275
Jung DH, Cho SY, Peck DH et al (2003) Preparation and performance of a Nafion/montmorillonite nanocomposite membrane for direct methanol fuel cell. J Power Sources 118:205–211
Yang C, Srinivasan S, Aricò AS et al (2001) Composite Nafion/zirconium phosphate membranes for direct methanol fuel cell operation at high temperature. Electrochem Solid-State Lett 4:A31–A34
Aricò AS, Baglio V, Di Blasi A et al (2003) FTIR spectroscopic investigation of inorganic fillers for composite DMFC membranes. Electrochem Commun 5:862–866
Aricò AS, Baglio V, Di Blasi A et al (2004) Surface properties of inorganic fillers for application in composite membranes-direct methanol fuel cells. J Power Sources 128:113–118
Lufrano F, Baglio V, Staiti P et al (2008) Polymer electrolytes based on sulfonated polysulfone for direct methanol fuel cells. J Power Sources 179:34–41
Aricò AS, Baglio V, Di Blasi A et al (2006) Proton exchange membranes based on the short-side-chain perfluorinated ionomer for high temperature direct methanol fuel cells. Desalination 199:271–273
Barbir F (2005) PEM electrolysis for production of hydrogen from renewable energy sources. Sol Energy 78:661–669
Millet P, Mbemba N, Grigoriev SA et al (2011) Electrochemical performances of PEM water electrolysis cells and perspectives. Int J Hydrogen Energy 36:4134–4142
Antonucci V, Di Blasi A, Baglio V et al (2008) High temperature operation of a composite membrane-based solid polymer electrolyte water electrolyser. Electrochim Acta 53:7350–7356
Arcella V, Ghielmi A, Tommasi G (2003) High performance perfluoropolymer films for membranes. Ann N Y Acad Sci 984:226–244
Ghielmi A, Vaccarono P, Troglia C et al (2005) Proton exchange membranes based on short-side chain perfluorinated ionomer. J Power Sources 145:108–115
Arcella V, Troglia C, Ghielmi A (2005) Hyflon ion membranes for fuel cells. Ind Eng Chem Res 44:7646–7651
Merlo L, Ghielmi A, Cirillo L et al (2007) Membrane electrode assemblies based on Hyflon ion for an evolving fuel cell technology. Sep Sci Technol 42:2891–2908
Peron J, Nedellec Y, Jones DJ et al (2008) The effect of dissolution, migration precipitation of platinum in Nafion®-based membrane electrode assemblies during fuel cell operation at high potential. J Power Sources 185:1209–1217
Stassi A, Gatto I, Passalacqua E et al (2011) Performance comparison of long and short-side chain perfluorosulfonic membranes for high temperature polymer electrolyte membrane fuel cell operation. J Power Sources 196:8925–8930
Siracusano S, Baglio V, Stassi A et al (2014) Performance analysis of short-side-chain Aquivion® perfluorosulfonic acid polymer for proton exchange membrane water electrolysis. J Membr Sci 466:1–7
Skulimowska A, Dupont M, Zaton M et al (2014) Proton exchange membrane water electrolysis with short-side-chain Aquivion® membrane and IrO2 anode catalyst. Int J Hydrogen Energy 39:6307–6316
Chandan A, Hattenberger M et al (2013) High temperature (HT) polymer electrolyte membrane fuel cells (PEMFC)—a review. J Power Sources 231:264–278
Gasteiger HA, Kocha SS, Sompalli B et al (2005) Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs. Appl Catal B Environ 56:9–35
Li Q, Jensen JO, Pan C et al (2008) Partially fluorinated arylene polyethers and their ternary blends with PBI and H3PO4: Part II. Characterisation and fuel cell tests of the ternary membranes. Fuel Cells 8:188–199
Aricò AS, Stassi A, Gatto I et al (2010) Surface properties of Pt-based electro-catalysts and their influence on performance and degradation of high temperature polymer electrolyte fuel cells. J Phys Chem C 114:15823–15836
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Aricò, A.S. et al. (2016). Modifications of Sulfonic Acid-Based Membranes. In: Li, Q., Aili, D., Hjuler, H., Jensen, J. (eds) High Temperature Polymer Electrolyte Membrane Fuel Cells. Springer, Cham. https://doi.org/10.1007/978-3-319-17082-4_2
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DOI: https://doi.org/10.1007/978-3-319-17082-4_2
Publisher Name: Springer, Cham
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