Abstract
Introduction of nanostructure into electrochemistry has been widely confirmed to succeed in the performance enhancement. The morphology control of electrochemical material has become a key to the combination of electrochemistry and nanoscience. Normally, it is not easy to realize the regular structures in nanoscale by self-organization for all materials. This must rely on the well-understood properties of the desired material. The crucial control parameter of morphology should be recognized first. In this case, the design of fabrication approach can fix a direction. For the electrochemical material, application normally requires the immobilization on electrode surface. Therefore, in situ formation methods are more appreciated. Here in this chapter, two different kinds of electrochemical materials – Prussian Blue, an inorganic complex compound, and Ni(en)3Ag2I4, a hybrid material – served as examples to describe the nano/microstructure control of crystal growth by the targeted design of novel preparation approaches. Focusing on the different issues of structure control, different synthesis techniques have been developed to reach the goal. According to characterizations, these self-organized nanostructures can obviously increase the electrochemical performance of original materials which exhibits the meaningful and useful functions for the nanostructure self-organization that relied on this targeted design of fabrication approach.
References
Meier J, Schiotz J, Liu P et al (2004) Nano-scale effects in electrochemistry. Chem Phys Lett 390(4-6):440–444
Bockris JO’M (2000) Modern electrochemistry 2B: electrodics in chemistry, engineering, biology and environmental science. Kluwer/Plenum, New York
O’Regan B, Gratzel M, Fitzmaurice D (1991) Optical electrochemistry I: steady-state spectroscopy of conduction-band electrons in a metal oxide semiconductor electrode. Chem Phys Lett 183(1–2):89–93
Trasatti S (1991) Physical electrochemistry of ceramic oxides. Electrochim Acta 36(2):225–241
Schindler W, Kirschner J (1997) Ultrathin magnetic films: electrochemistry versus molecular-beam epitaxy. Phys Rev B 55(4):1989–1996
Ohzuku T, Ueda A, Nagayama M (1993) Electrochemistry and structural chemistry of LiNiO2 (R3̅m) for 4 volt secondary lithium cells. J Electrochem Soc 140(7):1862–1870
Stupp SI (2005) Introduction: functional nanostructures. Chem Rev 105(4):1023–1024
Guo Y, Hu Y, Sigle W et al (2007) Superior electrode performance of nanostructured mesoporous TiO2 (anatase) through efficient hierarchical mixed conducting networks. Adv Mater 19(16):2087–2091
Yu A, Liang Z, Cho J et al (2003) Nanostructured electrochemical sensor based on dense gold nanoparticle films. Nano Lett 3(9):1203–1207
Bisquert J (2008) Physical electrochemistry of nanostructured devices. Phys Chem Chem Phys 10:49–72
Adams RN (1969) Electrochemistry at solid electrodes. Marcel Dekker, New York
Fulop GF, Taylor RM (1985) Electrodeposition of semiconductors. Ann Rev Mater Sci 15:197–210
Gurrappa I, Binder L (2008) Electrodeposition of nanostructured coatings and their characterization-a review. Sci Technol Adv Mat 9(4):43001–43011
Li Y, Shi G (2005) Electrochemical growth of two-dimensional gold nanostructures on a thin polypyrrole film modified ITO electrode. J Phys Chem B 109(50):23787–23793
Gou L, Murphy CJ (2005) Fine-tuning the shape of gold nanorods. Chem Mater 17(14):3668–3672
Chu Z, Liu Y, Jin W et al (2009) Facile fabrication of a Prussian blue film by direct aerosol deposition on a Pt electrode. Chem Commun 24:3566–3567
Jiang YS, Yao HG, Ji SH et al (2008) New framework iodoargentates: M(en)3Ag2I4 (M = Zn, Ni) with tridymite topology. Inorg Chem 47(10):3922–3924
Razmi H, Mohammad-Rezaei R, Heidari H (2009) Self-assembled Prussian blue nanoparticles based electrochemical sensor for high sensitive determination of H2O2 in acidic media. Electroanalysis 21(21):2355–2362
Ricci F, Palleschi G, Yigzaw Y et al (2003) Investigation of the effect of different glassy carbon materials on the performance of Prussian blue based sensors for hydrogen peroxide. Electroanalysis 15(3):175–182
Haghighi B, Nikzad R (2009) Prussian blue modified carbon ionic liquid electrode: electrochemical characterization and its application for hydrogen peroxide and glucose measurements. Electroanalysis 21(16):1862–1868
Ludi A (1981) Prussian blue, an inorganic evergreen. J Chem Educ 58(12):1013
Robin MB (1962) The color and electronic configurations of Prussian blue. Inorg Chem 1(2):337–342
Itaya K, Akahoshi H, Toshima S (1982) Electrochemistry of Prussian blue modified electrodes: an electrochemical preparation method. J Electrochem Soc 129(7):1498–1500
Muller G, Metois J, Rudolph P (eds) (2004) Crystal growth-from fundamentals to technology. Elsevier, Amsterdam
Ulrich J, Strege C (2002) Some aspects of the importance of metastable zone width and nucleation in industrial crystallizers. J Cryst Growth 237–239(3):2130–2135
Debe MK (2012) Electrocatalyst approaches and challenges for automotive fuel cells. Nature 486:43–51
Laidler KJ (1979) Theories of chemical reaction rates. R. E. Krieger, Michigan
Itaya K, Uchida I, Neff VD (1986) Electrochemistry of polynuclear transition metal cyanides: Prussian blue and its analogues. Acc Chem Res 19(6):162–168
Ricci F, Palleschi G (2005) Sensor and biosensor preparation, optimisation and applications of Prussian blue modified electrodes. Biosens Bioelectron 21(3):389–407
Gultepe I (ed) (2007) Fog and boundary layer clouds: fog visibility and forecasting. Springer, Berlin
Hinds WC (1999) Aerosol technology: properties, behavior, and measurement of airborne particles. Wiley, Hoboken
Liu Y, Chu Z, Jin W (2009) A sensitivity-controlled hydrogen peroxide sensor based on self-assembled Prussian blue modified electrode. Electrochem Commun 11(2):484–487
Zhang J, Huang M, Ma H et al (2007) High catalytic activity of nanostructured Pd thin films electrochemically deposited on polycrystalline Pt and Au substrates towards electro-oxidation of methanol. Electrochem Commun 9(6):1298–1304
Lao C, Liu J, Gao P et al (2006) ZnO nanobelt/nanowire schottky diodes formed by dielectrophoresis alignment across Au electrodes. Nano Lett 6(2):263–266
Chu Z, Zhang Y, Dong X et al (2010) Template-free growth of regular nano-structured Prussian blue on a platinum surface and its application in biosensors with high sensitivity. J Mater Chem 20:7815–7820
Karyakin A, Puganova E, Bolshakov I et al (2007) Electrochemical sensor with record performance characteristics. Angew Chem Int Edit 119(40):7822–7824
Karyakin A (2001) Prussian blue and its analogues: electrochemistry and analytical applications. Electroanalysis 13(10):813–819
Chu Z, Shi L, Liu Y et al (2013) In-situ growth of micro-cubic Prussian blue-TiO2 composite film as a highly sensitive H2O2 sensor by aerosol co-deposition approach. Biosens Bioelectron 47(15):329–334
Zeis R, Lei T, Sieradzki K et al (2008) Catalytic reduction of oxygen and hydrogen peroxide by nanoporous gold. J Catal 253(1):132–138
Millward RC, Madden CE, Sutherland I et al (2001) Directed assembly of multilayers-the case of Prussian blue. Chem Commun 19:1994–1996
Chu Z, Shi L, Zhang Y et al (2011) Hierarchical self-assembly of double structured Prussian blue film for highly sensitive biosensors. J Mater Chem 21:11968–11972
Johansson A, Widenkvist E, Lu J et al (2005) Fabrication of high-aspect-ratio Prussian blue nanotubes using a porous alumina template. Nano Lett 5(8):1603–1606
Puganova E, Karyakin A (2005) New materials based on nanostructured Prussian blue for development of hydrogen peroxide sensors. Sens Actuators B 109(1):167–170
Pham T, Kim H, Yoon K (2011) Growth of uniformly oriented silica MFI and BEA zeolite films on substrates. Science 334:1533–1538
Shibata T, Fukuda K, Ebina Y, Kogure T, Sasaki T (2008) One-nanometer-thick seed layer of unilamellar nanosheets promotes oriented growth of oxide crystal films. Adv Mater 20(2):231–235
Hermes S, Schroder F, Chelmowski R, WÖll C, Fischer RA (2005) Selective nucleation and growth of metal-organic open framework thin films on patterned COOH/CF3-terminated self-assembled monolayers on Au(111). J Am Chem Soc 127(40):13744–13745
Liu B, Shekhah O, Arslan HK, Liu JX, WÖll C, Fischer RA (2012) Enantiopure metal–organic framework thin films: oriented SURMOF growth and enantioselective adsorption. Angew Chem Int Ed 51(3):807–810
Yusenko K, Meilikhov M, Zacher D, Wieland F, Sternemann C, Stammer X, Ladnorg T, WÖll C, Fischer RA (2010) Step-by-step growth of highly oriented and continuous seeding layers of [Cu2(ndc)2(dabco)] on bare oxide and nitride substrates. Cryst Eng Comm 12:2086–2090
Biemmi E, Scherb C, Bein T (2007) Oriented growth of the metal organic framework Cu3(BTC)2(H2O)3∙xH2O tunable with functionalized self-assembled monolayers. J Am Chem Soc 129(26):8054–8055
Schoedel A, Scherb C, Bein T (2010) Oriented nanoscale films of metal–organic frameworks by room–temperature gel-layer synthesis. Angew Chem Int Ed 49(40):7225–7228
Scherb C, Schoedel A, Bein T (2008) Directing the structure of metal–organic frameworks by oriented surface growth on an organic monolayer. Angew Chem Int Ed 47(31):5777–5779
Love JC, Estroff LA, Kriebel JK, Nuzzo RG, Whitesides GM (2005) Self-assembled monolayers of thiolates on metals as a form of nanotechnology. Chem Rev 105(4):1103–1169
Flink S, van Veggel FCJM, Reinhoudt DN (2000) Sensor functionalities in self-assembled monolayers. Adv Mater 12(18):1315–1328
Reed MA, Zhou C, Muller CJ, Burgin TP, Tour JM (1997) Conductance of a molecular junction. Science 278:252–254
Zhang J, Song SP, Wang LH, Pan D, Fan CH (2007) A gold nanoparticle-based chronocoulometric DNA sensor for amplified detection of DNA. Nat Protoc 2:888–2895
Peng HI, Strohsahl CM, Leach KE, Krauss TD, Miller BL (2009) Label-free DNA detection on nanostructured Ag surfaces. ACS Nano 3(8):2265–2273
Shi L, Chu Z, Dong X et al (2013) A highly oriented hybrid microarray modified electrode fabricated by a template-free method for ultrasensitive electrochemical DNA recognition. Nanoscale 5:10219–10225
Acknowledgment
This work was supported by the Innovative Research Team Program by the Ministry of Education of China (No. IRT13070) and the Doctoral Fund of Ministry of Education of China (No. 20113221110001) and is a project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).
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Chu, Z., Shi, L., Jin, W. (2015). Self-Organized Nano- and Micro-structure of Electrochemical Materials by Design of Fabrication Approaches. In: Aliofkhazraei, M., Makhlouf, A. (eds) Handbook of Nanoelectrochemistry. Springer, Cham. https://doi.org/10.1007/978-3-319-15207-3_41-1
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DOI: https://doi.org/10.1007/978-3-319-15207-3_41-1
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