Skip to main content
SpringerLink
Log in

Thermodynamic Models for the Adsorption of Alkyl Trimethyl Ammonium Bromides at the Water/Hexane Interface

  • Chapter
  • First Online:
Colloid Process Engineering

  • 1635 Accesses

Abstract

Based on surface/interfacial tension isotherms measured for the homologous series of alkyl trimethyl ammonium bromides (CnTAB) using the drop profile analysis tensiometry the adsorption behavior at three different liquid-fluid interfaces is discussed: solution/air, solution/hexane vapor and solution/hexane bulk liquid. The adsorption behavior can be described by different models. In the presence of hexane molecules (as a bulk liquid or as vapor in the air phase) the adsorption of the CnTAB molecules can be best described by a competitive adsorption with hexane molecules. This competitive thermodynamic model can be applied successfully to all three interfaces.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 79.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Fainerman VB, Möbius D, Miller R (eds.) (2001) Surfactants—chemistry, interfacial properties and application. In: Studies in interface science, vol 13. Elsevier, Amsterdam

    Google Scholar 

  2. Maldonado-Valderrama J, Martin-Rodriguez A, Galvez-Ruiz MJ, Miller R, Langevin D, Cabrerizo-Vilchez MA (2008) Colloids Surf A 323:116–122

    Article  Google Scholar 

  3. Ravera F, Ferrari M, Liggieri L (2000) Adv Colloid Interface Sci 88:129–177

    Article  Google Scholar 

  4. Kalinin VV, Radke CJ (1996) Colloids Surf A 114:337–350

    Article  Google Scholar 

  5. Monroy F, Ortega F, Rubio RG, Ritacco H, Langevin D (2005) Phys Rev Lett. 95, Article Nr. 056103

    Google Scholar 

  6. Fainerman VB, Mucic N, Pradines V, Aksenenko EV, Miller R (2013) Langmuir 29:13783–13789

    Article  Google Scholar 

  7. Bergeron V (1997) Langmuir 13:3474–3482

    Article  Google Scholar 

  8. Pradines V, Fainerman VB, Aksenenko EV, Krägel J, Mucic N, Miller R (2010) Colloids Surf A 371:22–28

    Article  Google Scholar 

  9. Mucic N, Kovalchuk NM, Aksenenko EV, Fainerman VB, Miller R (2013) J Colloid Interface Sci 410:181–187

    Article  Google Scholar 

  10. Medrzycka K, Zwierzykowski W (2000) J Colloid Interface Sci 2000(230):67–72

    Article  Google Scholar 

  11. Haydon DA, Taylor EH (1962) Trans Faraday Soc 58:1233–1250

    Article  Google Scholar 

  12. Mucic N, Kovalchuk NM, Pradines V, Javadi A, Aksenenko EV, Miller R (2014) Colloids Surf A 441:825–830

    Article  Google Scholar 

  13. Simister EA, Thomas RK, Penfold J, Aveyard R, Binks BP, Cooper P, Fletcher PDI, Lu JR, Sokolowski A (1992) J Phys Chem 96:1383–1388

    Article  Google Scholar 

  14. Lyttle DJ, Lu JR, Su TJ, Thomas RK (1995) Langmuir 11:1001–1008

    Article  Google Scholar 

  15. Purcell IP, Lu JR, Thomas RK, Howe AM, Penfold J (1998) Langmuir 14:1637–1645

    Article  Google Scholar 

  16. Binks BP, Crichton D, Fletcher PDI, MacNab JR, Li ZX, Thomas RK, Penfold J (1999) Colloids Surf A 146:299–313

    Article  Google Scholar 

  17. Javadi A, Moradi N, Karbaschi M, Fainerman VB, Möhwald H, Miller R (2011) Colloids Surf A 391:19–24

    Article  Google Scholar 

  18. Mucic N, Moradi N, Javadi A, Aksenenko EV, Fainerman VB, Miller R (2014) Colloids Surf A 442:50–55

    Article  Google Scholar 

  19. Fainerman VB, Lucassen-Reynders EH (2002) Adv Colloid Interface Sci 96:295

    Article  Google Scholar 

  20. Butler JAV (1932) Proc Roy Soc Ser A 135:348–375

    Article  MATH  Google Scholar 

  21. Fainerman VB, Aksenenko EV, Mucic N, Javadi A, Miller R (2014) Soft Matter 10:6873–6887

    Google Scholar 

  22. Fainerman VB, Miller R, Kovalchuk VI (2003) J Phys Chem B 107:6119–6121

    Article  Google Scholar 

  23. Fainerman VB, Vollhardt D (2003) J Phys Chem B 107:3098–3100

    Article  Google Scholar 

  24. Stubenrauch C, Fainerman VB, Aksenenko EV, Miller R (2005) J Phys Chem 109:1505–1509

    Article  Google Scholar 

  25. Fainerman VB, Aksenenko EV, Kovalchuk VI, Javadi A, Miller R (2011) Soft Matter 7:7860–7865

    Article  Google Scholar 

  26. Danov KD, Kralchevsky PA (2012) Colloid J 74:172–185

    Article  Google Scholar 

  27. Asnacios A, Langevin D, Argillier J-F (1996) Macromolecules 29:7412–7417

    Article  Google Scholar 

  28. Fang H, Shah DO (1998) J Colloid Interface Sci 205:531–534

    Article  Google Scholar 

  29. Azizian S, Kashimoto K, Matsuda T, Matsubara H, Takiue T, Aratono M (2007) J Colloid Interface Sci 316:25–30

    Article  Google Scholar 

  30. Schlossmann ML, Tikhonov AM (2008) Annu Rev Phys Chem 59:153–177

    Article  Google Scholar 

  31. Takiue T, Tottori T, Tatsuta K, Matsubara H, Tanida H, Nitta K, Uruga T, Aratono M (2012) J Phys Chem B 116:13739–13748

    Article  Google Scholar 

  32. Traube J (1891) J Liebigs Ann Chem 265:27–55

    Article  Google Scholar 

  33. Lucassen-Reynders EH (1966) J Phys Chem 70:1777–1785

    Article  Google Scholar 

Download references

Acknowledgements

The work was supported by projects of the DFG (Mi418/18-2), the DLR (50WM1129), and the COST actions CM1101 and MP1106.

Author information

Authors and Affiliations

  1. Max-Planck Institute of Colloids and Interfaces, Potsdam/Golm, Germany

    N. Mucic, A. Javadi, J. Krägel, M. Karbaschi & R. Miller

  2. Chemical Engineering Department, University of Tehran, Tehran, Iran

    A. Javadi

  3. Institute of Colloid Chemistry and Chemistry of Water, UNAS, Kiev, 03680, Ukraine

    E. V. Aksenenko

  4. Donetsk Medical University, 16 Ilych Avenue, Donetsk, 83003, Ukraine

    V. B. Fainerman

Authors
  1. N. Mucic
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Javadi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. Krägel
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. Karbaschi
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. V. Aksenenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. B. Fainerman
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. R. Miller
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to R. Miller .

Editor information

Editors and Affiliations

  1. Institute of Thermal Process Engineering, Karlsruhe Institute of Technology (KIT), Karlsruhe, Germany

    Matthias Kind

  2. Institute of Particle Technology, Friedrich-Alexander-Universität Erlangen, Erlangen, Germany

    Wolfgang Peukert

  3. Physical Chemistry II, TU Dortmund, Dortmund, Germany

    Heinz Rehage

  4. Institute of Process Engineering in Life Section I: Food Process Engineering, Karlsruhe Institute of Technology (KIT), Karlsruhe, Germany

    Heike P. Schuchmann

Rights and permissions

Reprints and permissions

Copyright information

© 2015 Springer International Publishing Switzerland

About this chapter

Cite this chapter

Mucic, N. et al. (2015). Thermodynamic Models for the Adsorption of Alkyl Trimethyl Ammonium Bromides at the Water/Hexane Interface. In: Kind, M., Peukert, W., Rehage, H., Schuchmann, H. (eds) Colloid Process Engineering. Springer, Cham. https://doi.org/10.1007/978-3-319-15129-8_13

Download citation

  • DOI: https://doi.org/10.1007/978-3-319-15129-8_13

  • Published:

  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-319-15128-1

  • Online ISBN: 978-3-319-15129-8

  • eBook Packages: EngineeringEngineering (R0)

Publish with us

Policies and ethics

Search

Navigation