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Observation of the Dark State in Ruthenium Complexes Using Femtosecond Infrared Vibrational Spectroscopy

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Ultrafast Phenomena XIX

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 162))

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Abstract

Comprehensive analyses of the excited states of prototypical ruthenium complexes using time-resolved infrared vibrational spectroscopy reveal a peak that can be assigned to the dark 3MC (metal centered) state, which plays an important role for their photofunctions.

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References

  1. D.W. Thompson, et al. “[Ru(bpy)3]2+ and Other Remarkable Metal-to-Ligand Charge Transfer (MLCT) Excited States” Pure Appl. Chem. 85, 1257 (2013).

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  2. S. Campagna, et al. “Photochemistry and Photophysics of Coordination Compounds: Ruthenium” Top. Curr. Chem. 280, 117 (2007).

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  3. T. Mukuta, et al. “Infrared Vibrational Spectroscopy of [Ru(bpy)2(bpm)]2+ and [Ru(bpy)3]2+ in the Excited Triplet State” Inorg. Chem. 53, 2481 (2014).

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  4. B.D. Durham, et al. “Photochemistry of Ru(bpy) 2+3 ” J. Am. Chem. Soc. 104, 4803 (1982).

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Author information

Authors and Affiliations

  1. Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, 226-8503, Japan

    Ken Onda, Tatsuhiko Mukuta & Sei’ichi Tanaka

  2. PRESTO, Japan Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi, Saitama, 332-0012, Japan

    Ken Onda & Akiko Inagaki

  3. Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, 226-8503, Japan

    Kei Murata

  4. Graduate School of Science and Engineering, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji, Tokyo, 192-0397, Japan

    Akiko Inagaki

Authors
  1. Ken Onda
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  2. Tatsuhiko Mukuta
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  3. Sei’ichi Tanaka
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  4. Kei Murata
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  5. Akiko Inagaki
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Corresponding author

Correspondence to Ken Onda .

Editor information

Editors and Affiliations

  1. Department of Chemistry, The University of Tokyo, Tokyo, Japan

    Kaoru Yamanouchi

  2. JILA, University of Colorado, Boulder, Colorado, USA

    Steven Cundiff

  3. Department of Chemistry, Ludwig-Maximilians-University, München, Germany

    Regina de Vivie-Riedle

  4. Department of Physics, The University of Tokyo, Tokyo, Japan

    Makoto Kuwata-Gonokami

  5. Department of Physics, The Ohio State University, Columbus, Ohio, USA

    Louis DiMauro

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© 2015 Springer International Publishing Switzerland

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Onda, K., Mukuta, T., Tanaka, S., Murata, K., Inagaki, A. (2015). Observation of the Dark State in Ruthenium Complexes Using Femtosecond Infrared Vibrational Spectroscopy. In: Yamanouchi, K., Cundiff, S., de Vivie-Riedle, R., Kuwata-Gonokami, M., DiMauro, L. (eds) Ultrafast Phenomena XIX. Springer Proceedings in Physics, vol 162. Springer, Cham. https://doi.org/10.1007/978-3-319-13242-6_116

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