Abstract
There are currently extensive studies that have evidenced the capability of nanoparticles in stabilizing foam via irreversible adsorption at the gas/liquid interface. Nanoparticle adsorption enhances both the dilatational viscoelasticity and interfacial properties of foam liquid films, retards film thinning and bubble coalescence, and decreases the Ostwald ripening. Many studies have investigated the potential of several types of nanoparticles including silica, metal oxides, graphene, and fly ash nanoparticles and the synergistic effect between surfactants and nanoparticles for foam stabilization. The selection of the appropriate surface wettability and the optimum nanoparticle concentration remains the most crucial criteria. Literature results suggested that hydrophilic nanoparticles (contact angle between 40° and 70°) can maximize the detachment energy of nanoparticles at the gas/liquid interface and contribute to maximum static and dynamic foam stability. Therefore, in this chapter, we review the fundamentals of foam stability, the mechanisms of foam stabilization by nanoparticles, and the major factors influencing nanoparticle-stabilized foam including nanoparticle surface wettability and surface hydrophilicity modification. Moreover, the remarkable foam studies discussed in this chapter provide evidence on the role of nanoparticles in enhancing the static and dynamic foam stability and recovering residual oil in porous media during gas enhanced oil recovery (EOR). Hence, nanoparticle-stabilized foam can be an alternative solution for the drawbacks of gas EOR.
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Acknowledgments
The authors gratefully acknowledge the Natural Sciences and Engineering Research Council of Canada (NSERC). The second author thanks the Islamic Development Bank (IDB) for its support during his internship at Dr. Nassar Research Group at the University of Calgary.
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Nomenclature
Nomenclature
- A :
-
Surface area, also used as the cross-sectional area of a core
- B :
-
Bridging coefficient
- C s :
-
Surfactant concentration in solution
- D i :
-
Diameter of a foam bubble
- D med :
-
Median of the volume-averaged bubble diameter in the foam
- D sm :
-
Sauter mean diameter
- E :
-
Entering coefficient
- ∆E:
-
Energy required to remove particle from the gas/liquid interface
- EG:
-
Gibbs surface elasticity
- EM:
-
Marangoni surface elasticity
- f g :
-
Foam quality
- k :
-
Core permeability
- L :
-
Lamella number, core length
- MRF :
-
Mobility reduction ratio
- \( {P}_c^{\mathrm{max}} \) :
-
Maximum capillary pressure
- \( {P}_c^{\ast } \) :
-
Limiting capillary pressure
- PG, PL:
-
Pressure on each side of an interface (gas, liquid)
- ∆P:
-
Pressure difference across an interface or pressure change
- p :
-
Nanoparticle packing parameter
- Q :
-
Injection rate
- R :
-
Radius of a curved surface or interface, also used as the gas constant, radius of nanoparticles
- S :
-
Spreading coefficient
- R1, R2:
-
Principal radii of curvature of a surface or interface
- T :
-
Absolute temperature
- Ug:
-
The superficial velocity of the gas
- U poly :
-
Polydispersity
- Uw:
-
The superficial velocity of water
- ut:
-
The total foam superficial velocity
- σ :
-
Surface or interfacial tension
- σ og :
-
The interfacial tension between oil and gas
- σ wo :
-
The interfacial tension between water and oil
- σ wg :
-
The interfacial tension between water and gas
- ε :
-
Viscoelastic modulus
- θ :
-
Contact angle
- Γs:
-
Surface excess concentration of surfactant
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Mheibesh, Y., Sagala, F., Nassar, N.N. (2021). Using Nanoparticles as Gas Foam Stabilizing Agents for Enhanced Oil Recovery Applications. In: Nassar, N.N., Cortés, F.B., Franco, C.A. (eds) Nanoparticles: An Emerging Technology for Oil Production and Processing Applications. Lecture Notes in Nanoscale Science and Technology, vol 32. Springer, Cham. https://doi.org/10.1007/978-3-319-12051-5_8
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