Abstract
Mesoporous silicon is a complex nanostructure whose optoelectronic properties and morphology have received intense study over the last 25 years. Its properties often depend on both its skeleton size distribution and the chemical nature of its high internal surface area. This review collates some of the lessons learned with regard characterization, highlighting potential issues that need to be considered and artifacts that can arise. These have in the past both complicated data interpretation and even caused problems in reproducing published data.
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References
Axelrod E, Givant A, Shappir J, Feldman Y, Saar A (2002) Dielectric relaxation and transport in porous silicon. Phys Rev B 65:165–429
Beckmann KH (1965) Investigation of the chemical properties of stain films on silicon by means of infrared spectroscopy. Surf Sci 3(4):314–332
Ben-Chorin M, Moller F, Koch F, Schirmacher W, Eberhard M (1995) Hopping transport on a fractal: ac conductivity of porous silicon. Phys Rev B 51(4):2199–2213
Bisi O, Ossicini S, Pavesi L (2000) Porous silicon: a quantum sponge structure for silicon based optoelectronics. Surf Sci Reports 38(1–3):1–126
Boarino L, Borini S, Amato G (2009) Electrical properties of mesoporous silicon: from a surface effect to coulomb blockade and more. J Electrochem Soc 156(12):K223–K226
Canham LT (1990) Silicon quantum wire array fabrication by electrochemical and chemical dissolution of waters. Appl Phys. Lett 57(10):1046–1048
Canham LT (1997) Properties of porous silicon, EMIS datareview series no 18. IEE Press, London
Canham LT, Houlton MR, Leong WY, Keen JM (1991) Atmospheric impregnation of porous silicon. J Appl Phys 70(1):422–431
Canham LT, Cullis AG, Pickering C, Dosser OD, Cox TI, Lynch TP (1994) Luminescent anodized silicon aerocrystal networks prepared by supercritical drying. Nature 368:133–135
Cao L, Price TP, Weiss M, Gao D (2008) Super water- and oil-repellent surfaces on intrinsically hydrophilic and oleophillic porous silicon films. Langmuir 24(5):1640–1643
Chao Y (2011) Optical properties of nanostructured silicon. Compr NanoSci Technol 1:543–570
Chuang SF, Collins SD, Smith RL (1989) Porous silicon microstructure as studied by transmission electron microscopy. Appl Phys Lett 55:1540–1543
Costa J, Roura P, Morante JR, Bertran E (1998) Blackbody emission under laser excitation of silicon nanopowder produced by plasma-enhanced chemical-vapour deposition. J Appl Phys 83(12):7879–7885
Cullis AG, Canham LT, Calcott PDJ (1997) The structural and luminescence properties of porous silicon. J Appl Phys 82(3):909–965
Derlet PM, Choy TC, Stoneham AM (1995) An investigation of the porous silicon optical absorption power law near the band edge. J Phys Condens Matter 7:2507–2523
Fauchet PM, Tsybeskov L, Peng C, Duttagupta SP, von Behren J, Kostoulas Y, Vandyshev JMV, Hirschman KD (1995) Light-emitting porous silicon: materials science, properties and device applications. IEEE J Sel Topics Quant Electron 1(4):1126–1139
Gentile F, Battista E et al (2011) Fractal structure can explain the increased hydrophobicity of nanoporous silicon films. Microelectron Eng 88:2537–2540
Giaddui T, Earwaker LG, Forcey KS, Loni A, Canham LT (1998) Improved capping layers for suppression of ambient ageing in porous silicon. J Phys D Appl Phys 31:1131–1136
Golovan LA, Timoshenko VY (2013) Nonlinear optical properties of porous silicon nanostructures. J Nanoelectron Optoelectron 8:223–239
Hamilton B (1995) Porous silicon. Semicond Sci Technol 10:1187–1207
Happo N, Fujiwara M, Iwamatsu M, Horii K (1998) Atomic force microscopy study of self-affine fractal roughness of porous silicon surfaces. Jpn J Appl Phys 37:3951–3953
Harsanyi J, Habermeier HU (1987) Fractal micropatterns generated by anodic etching. Microelectron Eng 6(1–4):575–580
Kim JH, Kim KP, Lyu HK, Woo SH, Seo HS, Lee JH (2009) Three dimensional macropore arrays in p-type silicon fabricated by electrochemical etching. J Korean Phys Soc 55(1):5–9
Loni A, Canham LT (2013) Exothermic phenomena and hazardous gas release during thermal oxidation of mesoporous silicon powders. J Appl Phys 113:173505
Lysenko V, Vitiello J, Remaki B, Barbier D (2004) Gas permeability of porous silicon nanostructures. Phys Rev E 70:017301
Moretti L, De Stefano L, Rendina I (2007) Quantitative analysis of capillary condensation in fractal-like porous silicon nanostructures. J Appl Phys 101:024309
Nychyporuk T, Lysenko V, Barbier D (2005) Fractal nature of porous silicon nanocrystallites. APS J Phys Rev B 71:115–402
Ouyang H, Christopherson M, Fauchet PM (2005) Enhanced control of porous silicon morphology from macropore to mesopore formation. Phys Stat Solidi (a) 202(8):1396–1401
Pacholski C (2013) Photonic crystal sensors based on porous silicon. Sensors 13:4694–4713
Roura P, Costa J (2002) Radiative thermal emission from silicon nanoparticles: a reversed story from quantum to classical theory. Eur J Phys 23:191–203
Scherer WG, Smith DM, Stein D (1995) Deformation of silica aerogels during characterisation. J Non Cryst Solids 186:309–315
Smith RL, Collins SD (1992) Porous silicon formation mechanisms. J Appl Phys 71, R1
Tondare VN, Gierhart BC, Howitt DG, Smith RL, Chen SJ, Collins SD (2008) An electron microscopy investigation of the structure of porous silicon by oxide replication. Nanotechnology 19:225–301
Torres-Costa V, Martin-Palma RJ (2010) Application of nanostructured porous silicon in the field of optics. A review. J Mater Sci 45:2823–2838
Valalaki K, Nassiopoulou AG (2014) Thermal conductivity of highly porous silicon in the temperature range 4.2 to 20K. Nano Res Lett 9, 318
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Canham, L. (2014). Characterization Challenges with Porous Silicon. In: Canham, L. (eds) Handbook of Porous Silicon. Springer, Cham. https://doi.org/10.1007/978-3-319-04508-5_40-1
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DOI: https://doi.org/10.1007/978-3-319-04508-5_40-1
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Characterization Techniques and Challenges with Porous Silicon- Published:
- 07 December 2017
DOI: https://doi.org/10.1007/978-3-319-04508-5_40-3
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Characterization Challenges with Porous Silicon
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- 11 July 2017
DOI: https://doi.org/10.1007/978-3-319-04508-5_40-2
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Original
Characterization Challenges with Porous Silicon- Published:
- 21 August 2014
DOI: https://doi.org/10.1007/978-3-319-04508-5_40-1