Abstract
In this chapter we discuss coherent X-ray scattering, photon statistics of speckle patterns, and X-ray photon correlation spectroscopy (XPCS). XPCS is a coherent X-ray scattering technique used to characterize dynamic properties of condensed matter by recording a fluctuating speckle pattern. In the experiments, the time correlation function of the scattered intensity is calculated at different momentum transfers Q and thereby detailed information about the dynamics is obtained. Recently, XPCS applications have broadened to include the study of nonequilibrium and heterogeneous dynamics, e.g., in systems close to jamming or at the glass transition. This is enabled through multi-speckle techniques where a 2D area detector (CCDs or pixel detectors) is employed, and the correlation function is evaluated by averaging over subsets of equivalent pixels (same Q ). In this manner time averaging can be avoided, and the time-dependent dynamics is quantified by the so-called two-times correlation functions. Higher-order correlation functions may also be calculated to investigate questions related to non-Gaussian dynamics and dynamical heterogeneity. We discuss recent forefront applications of XPCS in the study of soft and hard condensed matter dynamics, including phase-separation dynamics of colloid-polymer mixtures, motion of Au nanoparticles at the air-water interface, dynamics of atoms in metallic crystals and glasses, and domain coarsening in phase-ordering binary alloys.
This is a preview of subscription content, log in via an institution to check access.
References
D.L. Abernathy et al., J. Sync. Rad. 5, 37 (1998)
E. Allaria et al., Nat. Photonics 6, 699 (2012)
J. Amann et al., Nat. Photonics 6, 693 (2012)
C.A. Angell, K.L. Ngai, G.B. McKenna, P.F. McMillan, S.W. Martin, J. Appl. Phys. 88 3113 (2000)
B.J. Berne, R. Pecora, Dynamic Light Scattering (Dover, Mineola, 2000)
L. Berthier, G. Biroli, Rev. Mod. Phys. 83, 587 (2011)
L. Berthier, G. Biroli, J.-P. Boucahaud, L. Cipelletti, W. Van Saarlos, Dynamical Heterogeneities in Glasses, Colloids and Granular Media (Oxford University Press, Oxford, 2011)
BESAC Report, The New Era of Science: Directing Matter and Energy: Five Challenges for Science and the Imagination, US Department of Energy (2007)
J.P. Bouchaud, E. Pitard, Eur. Phys. J. E 6, 231 (2001)
G. Brown, P.A. Rikvold, M. Sutton, M. Grant, Phys. Rev. E 56 6601 (1997)
Z.H. Cai et al., Phys. Rev. Lett. 73, 82 (1994)
Y. Chushkin, C. Caronna, A. Madsen, J. Appl. Cryst. 45, 807 (2012)
L. Cipelletti, D.A. Weitz, Rev. Sci. Instr. 70, 3214 (1999)
L. Cipelletti et al., Faraday Discuss. Chem. Soc. 123, 237 (2003)
P.G. de Gennes, Physica 25, 825 (1959)
P. Falus, M.A. Borthwick, S.G.J. Mochrie, Rev. Sci. Instr. 75, 4383 (2004)
A. Fluerasu, M. Sutton, E. Dufresne, Phys. Rev. Lett. 94, 055501 (2005)
A. Fluerasu, A. Moussaid, A. Madsen, A. Schofield, Phys. Rev. E 76, 0100401(R) (2007)
G. Geloni et al., New J. Phys. 12, 035021 (2010)
G. Geloni, V. Kocharyan, E. Saldin, J. Mod. Opt. 58, 1391 (2011)
J.W. Goodman, in Laser Speckle and Related Phenomena, ed. by J.C. Dainty (Springer, Berlin, 1984), pp. 9–74; J.W. Goodman, Speckle Phenomena in Optics: Theory and Applications (Roberts and Company, Greenwood Village, 2007)
G. Grübel, D.L. Abernathy, SPIE 3154, 103 (1997)
G. Grübel, G.B. Stephenson, C. Gutt, H. Sinn, T. Tschentscher, Nucl. Instrum. Methods Phys. Res. B 262, 357 (2007)
G. Grübel, A. Madsen, A. Robert, in Soft-Matter Characterization, ed. by R. Borsali, R Pecora (Springer, New York, 2008), pp. 935–995
J. Horbach, W. Kob, K. Binder, Phys. Rev. Lett. 88, 125502 (2002)
S.O. Hruszkewycz et al., Phys. Rev. Lett. 109, 185502 (2012)
D. Langevin (ed.), Light Scattering by Liquid Surfaces and Complementary Techniques (Marcel Dekker, New York, 1992)
S. Lee et al., Opt. Express 20, 9790 (2012)
P. Lehmann, Appl. Opt. 38, 1144 (1999)
M. Leitner, Studying Atomic Dynamics with Coherent X-rays (Springer, Heidelberg, 2012)
M. Leitner, B. Sepiol, L.-M. Stadler, B. Pfau, G. Vogl, Nat. Mater. 8, 717 (2009)
M. Leitner, B. Sepiol, L.-M. Stadler, B. Pfau, Phys. Rev. B 86, 064202 (2012)
B. Lengeler, Naturwissenschaften 88, 249 (2001)
F. Livet, M. Sutton, C. R. Phys. 13, 227 (2012)
F. Livet et al., Nucl. Instrum. Methods Phys. Res. Sect. A, 451, 596 (2000)
F. Livet et al., Phys. Rev. E 63 36108 (2001)
R. Loudon, The Quantum Theory of Light, 2nd edn. (Oxford Science, Oxford, 1991)
V. Lubchenko, P.G. Wolynes, J. Chem. Phys. 121, 2852 (2004)
K.F. Ludwig, Phys. Rev. Lett. 61, 1526 (1988)
K. Ludwig et al., Phys. Rev. B 72, 144201 (2005)
D. Lumma, L.B. Lurio, S. Mochrie, M. Sutton, Rev. Sci. Instr. 71, 3274 (2000)
A. Madsen, Conceptual Design Report: Scientific Instrument MID, XFEL.EU TR-2011-008 (2011). http://dx.doi.org/10.3204/XFEL.EU/TR-2011-008
A. Madsen, T. Seydel, M. Tolan, G. Grübel, J. Sync. Rad. 12, 786 (2005)
A. Madsen, R.L. Leheny, H. Guo, M. Sprung, O. Czakkel, New J. Phys 12, 055001 (2010)
J. Miao, R.L. Sandberg, C. Song, Sel. Top. Quant. Elect., IEEE 18, 399 (2012)
D. Orsi, L. Cristofolini, G. Baldi, A. Madsen, Phys. Rev. Lett. 108, 105701 (2012)
A. Papagiannopoulos, T.A. Waigh, A. Fluerasu, C. Fernyhough, A. Madsen, J. Phys.: Condens. Matter 17, L279 (2005)
K.N. Pham et al., Science 296, 104 (2002)
C. Ponchut et al., JINST 6, C01069 (2011)
P.N. Pusey, in Liquids, Freezing and Glass Transition, ed. by J.P. Hansen, D. Levesque, J. Zinn-Justin, Les Houches Session LI (Elsevier, Amsterdam, 1991), p. 763–942
V. Radicci et al., JINST 7, 02019 (2012)
J.D. Rigden, E.I. Gordon, Proc. IRE 50, 2367 (1962)
I. Robinson, R. Harder, Nat. Mater. 8, 291 (2009)
I. Robinson et al., Phys. Rev. B 52, 9917 (1995)
B. Ruta et al., Phys. Rev. Lett. 109, 165701 (2012)
B. Ruta et al., AIP Conf. Proc. 1518, 181 (2013a)
B. Ruta, G. Baldi, G. Monaco, Y. Chushkin, J. Chem. Phys. 138, 054508 (2013b)
B. Ruta, V.M. Giordano, L. Erra, C. Liu, E. Pineda, J. Alloy. Compd. 615, S45 (2014a)
B. Ruta et al., Nat. Commun. 5, 3939 (2014b)
P.N. Segre, P.N. Pusey, Physica A 235, 9 (1997)
T. Seydel et al., Rev. Sci. Instr. 74, 4033 (2003)
R.F. Shannon Jr., S.E. Nagler, C.R. Harkless, R.M. Nicklow, Phys. Rev. B 46, 40 (1992)
A.J.F. Siegert, Massachusetts Institute of Technology Radiation Labatory Report No. 465 (1943)
S.K. Sinha, D.K. Ross, Physica B 149, 51 (1988)
I. Sikharulidze et al., Phys. Rev. Lett 88, 115503 (2002)
M. Stana, M. Leitner, M. Ross, B. Sepiol, J. Phys.: Condens. Matter 25, 065401 (2013)
M. Sutton, C.R. Phys. 9, 657 (2008)
M. Sutton et al., Nature 352, 608 (1991)
G. Vogl, B. Sepiol, in Diffusion in Condensed Matter, ed. by P. Heitjans, J. Kärger (Springer, New York, 2005), pp. 65–91
A.R. Yavari et al., Acta Mater. 53, 1611 (2005)
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2015 Springer International Publishing Switzerland
About this entry
Cite this entry
Madsen, A., Fluerasu, A., Ruta, B. (2015). Structural Dynamics of Materials Probed by X-Ray Photon Correlation Spectroscopy. In: Jaeschke, E., Khan, S., Schneider, J., Hastings, J. (eds) Synchrotron Light Sources and Free-Electron Lasers. Springer, Cham. https://doi.org/10.1007/978-3-319-04507-8_29-1
Download citation
DOI: https://doi.org/10.1007/978-3-319-04507-8_29-1
Received:
Accepted:
Published:
Publisher Name: Springer, Cham
Online ISBN: 978-3-319-04507-8
eBook Packages: Springer Reference Physics and AstronomyReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics
Publish with us
Chapter history
-
Latest
Structural Dynamics of Materials Probed by X-Ray Photon Correlation Spectroscopy- Published:
- 19 September 2018
DOI: https://doi.org/10.1007/978-3-319-04507-8_29-2
-
Original
Structural Dynamics of Materials Probed by X-Ray Photon Correlation Spectroscopy- Published:
- 22 January 2015
DOI: https://doi.org/10.1007/978-3-319-04507-8_29-1