Skip to main content

Electronic Structure of Exfoliated MoS2

  • Chapter
  • First Online:
MoS2

Part of the book series: Lecture Notes in Nanoscale Science and Technology ((LNNST,volume 21))

Abstract

Molybdenum disulfide (MoS2) is a transition metal dichalcogenide which has been a subject of intense research mainly due to its catalytic properties. MoS2 is formed by two-dimensional (2D) graphene-like S–Mo–S layers held together by weak noncovalent interactions. Recently, MoS2 has been exfoliated into individual S–M–S monolayers and the electronic and optical properties of a single MoS2 layer have been investigated. It was demonstrated that a single layer MoS2 undergoes indirect to direct band gap transition, which enables a wide range of optoelectronic applications. I will review the electronic structure of exfoliated MoS2 and discuss several ways in which it can be manipulated. I will also review potential applications of exfoliated MoS2 in the exciting new field of valleytronics.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 139.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 179.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Similar content being viewed by others

References

  1. Neto, A.H.C., Guinea, F., Peres, N.M.R., Novoselov, K.S., Geim, A.K.: Rev. Mod. Phys. 81, 109 (2009)

    Article  Google Scholar 

  2. Ohta, T., Bostwick, A., Seyller, T., Horn, K., Rotenberg, E.: Science 313, 951 (2006)

    Google Scholar 

  3. Castro, E.V., Novoselov, K.S., Morozov, S.V., Peres, N.M.R., Lopes dos Santos, J.M.B., Nilsson, J., Guinea, F., Geim, A.K., Castro Neto, A.H.: Phys. Rev. Lett. 99, 216802 (2007)

    Article  Google Scholar 

  4. Oostinga, J. B., Heersche, H. B., Liu, X., Morpurgo, A. F., Vandersypen, L. M. K.: Nature Mater. 7, 151 (2007)

    Google Scholar 

  5. Nakada, K., Fujita, M., Dresselhaus, G., Dresselhaus, M.S.: Phys. Rev. B 54, 17954 (1996)

    Article  CAS  Google Scholar 

  6. Wakabayashi, K., Fujita, M., Ajiki, H., Sigrist, M.: Phys. Rev. B 59, 8271 (1999)

    Article  CAS  Google Scholar 

  7. Wunsch, B., Stauber, T., Sols, F., Guinea, F.: Phys. Rev. Lett. 101, 036803 (2008)

    Article  CAS  Google Scholar 

  8. Yang, L., Cohen, M.L., Louie, S.G.: Phys. Rev. Lett. 101, 186401 (2008)

    Article  Google Scholar 

  9. Wunsch, B., Stauber, T., Guinea, F.: Phys. Rev. B 77, 035316 (2008)

    Article  Google Scholar 

  10. Wurm, J., Rycerz, A., Adagideli, I., Wimmer, M., Richter, K., Baranger, H. U.: Phys. Rev. Lett. 102, 056806 (2009)

    Google Scholar 

  11. Libisch, F., Stampfer, C., Burgdorfer, J.: Phys. Rev. B 79, 115423 (2009)

    Article  Google Scholar 

  12. Sheng, W.-D., Korkusinski, M., Güçlü, A.D., Zielinski, M., Potasz, P., Kadantsev, E.S., Voznyy, O., Hawrylak, P.: Front. Phys. 7, 328 (2012)

    Article  Google Scholar 

  13. Zhang, Y., Tang, T.-T., Girit, C., Hao, Z., Martin, M. C., Zettl, A., Crommie, M. F., Shen, Y. R., Wang, F.: Nature 459, 820 (2009)

    Google Scholar 

  14. Xu, M., Liang, T., Shi, M., Chen, H.: Chem. Rev. 113, 3766 (2013)

    Article  CAS  Google Scholar 

  15. Butler, S. Z., Hollen, S. M., Cao, L., Cui, Y., Gupta, J. A., Gutierrez, H. R., Heinz, T. F., Hong, S. S., Huang, J., Ismach, A. F., Johnston-Halperin, E., Kuno, M., Plashnitsa, V. V., Robinson, R. D., Ruoff, R. S., Salahuddin, S., Shan J., et al.: ACS Nano. 7, 2898 (2013)

    Google Scholar 

  16. Wang, Q. H., Kalantar-Zadeh, K., Kis, A., Coleman, J. N., Strano, M. S.: Nature Nanotech. 7, 699 (2012)

    Google Scholar 

  17. Osada, M., Sasaki, T.: Adv. Mater. 24, 210 (2012)

    Article  CAS  Google Scholar 

  18. Zhang, H., Liu, C.-X., Qi, X.-L., Dai, X., Fang, Z., Zhang, S.-C.: Nature Phys. 5, 438 (2009)

    Google Scholar 

  19. Aufray, B., Kara, A., Vizzini, S., Oughaddou, H., Léandri, C., Ealet, B., Le Lay, G.: Appl. Phys. Lett. 96, 183102 (2010)

    Article  Google Scholar 

  20. Lalmi, B., Oughaddou, H., Enriquez, H., Kara, A., Vizzini, S., Ealet, B., Aufray, B.: Appl. Phys. Lett. 97, 223109 (2010)

    Article  Google Scholar 

  21. Takeda, K., Shiraishi, K.: Phys. Rev. B 50, 14916 (1994)

    Article  CAS  Google Scholar 

  22. Watanabe, K., Taniguchi, T., Kanda, H.: Nature Mater. 3, 404 (2004)

    Google Scholar 

  23. Yoffe, A.D.: Chem. Soc. Rev. 5, 51 (1976)

    Article  CAS  Google Scholar 

  24. Bromley, R.A.: Phys. Lett. A 33, 1970 (242)

    Google Scholar 

  25. Harper P. G., Edmondson, D. R.: Phys. Stat. Sol. (b) 44, 59 (1971)

    Google Scholar 

  26. Mattheiss, L.F.: Phys. Rev. B 8, 3719 (1973)

    Article  CAS  Google Scholar 

  27. Chantis, A.N., Christensen, N.E., Svane, A., Cardona, M.: Phys. Rev. B 81, 205205 (2010)

    Article  Google Scholar 

  28. Xiao, D., Liu, G.-B., Feng, W., Xu, X., Yao, W.: Phys. Rev. Lett. 108, 196802 (2012)

    Article  Google Scholar 

  29. Raybaud, P., Hafner, J., Kresse, G., Kasztelan, S., Toulhoat, H.: J. Catal. 189, 129 (2000)

    Article  CAS  Google Scholar 

  30. Schweiger, H., Raybaud, P., Kresse, G., Toulhoat, H.: J. Catal. 207, 76 (2002)

    Article  CAS  Google Scholar 

  31. Byskov, L.S., Nørskov, J.K., Clausen, B.S., Topsøe, H.: J. Catal. 187, 109 (1999)

    Article  CAS  Google Scholar 

  32. Sun, M., Adjaye, J., Nelson, A.E.: Appl. Catal. A 263, 131 (2004)

    CAS  Google Scholar 

  33. Galea, N.M., Kadantsev, E.S., Ziegler, T., Phys, J.: Chem. C 113, 193 (2009)

    CAS  Google Scholar 

  34. Rydberg, H., Dion, M., Jacobson, N., Schröder, E., Hyldgaard, P., Simak, S.I., Langreth, D.C., Lundqvist, B.I.: Phys. Rev. Lett. 91, 126402 (2003)

    Article  CAS  Google Scholar 

  35. Hohenberg, P., Kohn, W.: Phys. Rev. 136, B864 (1964)

    Article  Google Scholar 

  36. Kohn, W., Sham, L.J.: Phys. Rev. 140, A1133 (1965)

    Article  Google Scholar 

  37. Grimme, S.: J. Comput. Chem. 27, 1787 (2006)

    Article  CAS  Google Scholar 

  38. Perdew, J.P., Burke, K., Ernzerhof, M.: Phys. Rev. Lett. 77, 3865 (1996)

    Article  CAS  Google Scholar 

  39. Bjorkman, T., Gulans, A., Krasheninnikov, A.V., Nieminen, R.M.: J. Phys.: Condens. Matter 24, 2012 (424218)

    Google Scholar 

  40. Dion, M., Rydberg, H., Schroder, E., Langreth, D.C., Lundqvist, B.I.: Phys. Rev. Lett. 92, 246401 (2004)

    Article  CAS  Google Scholar 

  41. Lee, K., Murray, E.D., Kong, L., Lundqvist, B.I., Langreth, D.C.: Phys. Rev. B 82, 081101 (2010)

    Article  Google Scholar 

  42. Vydrov, O.A., Van Voorhis, T.: J. Chem. Phys. 133, 244103 (2010)

    Article  Google Scholar 

  43. Johnson, E. R., Keinan, S., Mori-Sánchez, P., Contreras-García, J., Cohen, A. J., Yang, W.: JACS 132, 6498 (2010)

    Google Scholar 

  44. Novoselov, K. S. et al.: Proc. Natl. Acad. Sci. USA 102, 10451 (2005)

    Google Scholar 

  45. Frindt, R.F.: J. Appl. Phys. 37, 1928 (1966)

    Article  CAS  Google Scholar 

  46. Splendiani, A., Sun, L., Zhang, Y., Li, T., Kim, J., Chim, C.-Y., Galli, G., Wang, F.: Nano Lett. 10, 2010 (1271)

    Google Scholar 

  47. Mak, K.F., Lee, C., Hone, J., Shan, J., Heinz, T.F.: Phys. Rev. Lett. 105, 136805 (2010)

    Article  Google Scholar 

  48. Radisavljevic, B., Radenovic, A., Brivio, J., Giacometti, V., Kis, A.: Nature Nanotech. 6, 147 (2011)

    Google Scholar 

  49. Fontana, M., Deppe, T., Boyd, A. K., Rinzan, M., Liu, A. Y., Paranjape, M., Barbara, P.: Scientific Reports 3, 1634 (2013)

    Google Scholar 

  50. van der Zande, A. M., Huang, P. Y., Chenet, D. A., Berkelbach, T. C., You, Y., Lee, G.-H., Heinz, T. F., Reichman, D. R., Muller, D. A., Hone, J. C.: Nature Mater. 12, 554 (2013)

    Google Scholar 

  51. Li, T., Galli, G.: J. Phys. Chem. C 111, 16192 (2007)

    Article  CAS  Google Scholar 

  52. Kadantsev, E.S., Hawrylak, P.: Solid State Commun. 152, 2012 (909)

    Google Scholar 

  53. Lebègue, S., Eriksson, O.: Phys. Rev. B 79, 115409 (2009)

    Article  Google Scholar 

  54. Cheiwchanchamnangij, T., Lambrecht, W.R.L.: Phys. Rev. B 85, 205302 (2012)

    Article  Google Scholar 

  55. Yun, W.S., Han, S.W., Hong, S.C., Kim, I.G., Lee, J.D.: Phys. Rev. B 85, 033305 (2012)

    Article  Google Scholar 

  56. Dresselhaus, G.: Phys. Rev. 100, 580 (1955)

    Article  CAS  Google Scholar 

  57. Cardona, M., Christensen, N.E., Fasol, G.: Phys. Rev. B 38, 1806 (1988)

    Article  CAS  Google Scholar 

  58. Luo, J.-W., Bester, G., Zunger, A.: Phys. Rev. Lett. 102, 056405 (2009)

    Article  Google Scholar 

  59. Johari, P., Shenoy, V.B.: ACS Nano 6, 2012 (5449)

    Google Scholar 

  60. Scalise, E., Houssa, M., Pourtois, G., Afanas’ev, V., Stesmans, A.: Nano Res. 5, 43 (2012)

    Google Scholar 

  61. Ramasubramaniam, A., Naveh, D., Towe, E.: Phys. Rev. B 84, 205325 (2011)

    Article  Google Scholar 

  62. Liu, Q., Li, L., Li, Y., Gao, Z., Chen, Z., Lu, J., Phys, J.: Chem. C 116, 21556 (2012)

    CAS  Google Scholar 

  63. Mak, K. F., He, K., Shan, J., Heinz, T. F.: Nature Nanotech. 7, 494 (2012)

    Google Scholar 

  64. Zeng, H., Dai, J., Yao, W., Xiao, D., Cui, X.: Nature Nanotech. 7, 490 (2012)

    Google Scholar 

  65. Cao, T., Wang, G., Han, W., Ye, H., Zhu, C., Shi, J., Niu, Q., Tan, P., Wang, E., Liu, B., Feng, J.: Nature Commun. 3, 887 (2012)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Eugene Kadantsev .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2014 Springer International Publishing Switzerland

About this chapter

Cite this chapter

Kadantsev, E. (2014). Electronic Structure of Exfoliated MoS2 . In: Wang, Z. (eds) MoS2. Lecture Notes in Nanoscale Science and Technology, vol 21. Springer, Cham. https://doi.org/10.1007/978-3-319-02850-7_2

Download citation

Publish with us

Policies and ethics