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Ferroelectric and Dielectric Properties of Solid Solution Ceramics Based on Bismuth Ferrite and Lead Ferroniobate Multiferroics with Germanium Dioxide Additive

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Physics and Mechanics of New Materials and Their Applications (PHENMA 2023)

Part of the book series: Springer Proceedings in Materials ((SPM,volume 41))

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Abstract

Ferroelectric and dielectric characteristics of multiferroics solid solutions ceramics of the (1 – x)BiFeO3 − xPbFe0.5Nb0.5O3 composition with x = 0.3, modified superstoichiometrically with GeO2 in amounts (0.5–1.0) wt.%, were studied. It is noted that the temperature dependencies of the real part of the complex dielectric permittivity and the dielectric loss tangent exhibit anomalies in the vicinity of the ferroelectric phase transition, while the nature of their changes in the vicinity of the latter allows us to classify the studied objects as ferroelectrics with a diffuse phase transition. The ferroelectric properties of the modified objects at room temperature indicate that it was not possible to obtain saturated dielectric hysteresis loops for all samples in the analyzed field range. This is apparently due to high coercive fields indicating improved electrical strength of ceramics. In this regard, it is advisable to use materials, based on 0.7BiFeO3 − 0.3PbFe0.5Nb0.5O3 solid solutions, developed during the research, to create and study new multifunctional media with special electrophysical parameters, promising for applications in innovative areas of electronics.

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Acknowledgments

The study was carried out with the financial support of the Ministry of Science and Higher Education of the Russian Federation (State task in the field of scientific activity in 2023). Project No. FENW-2023–0010/(GZ0110/23–11-IF). The equipment of the Center for Collective Use of the Research Institute of Physics of the Southern Federal University “Electromagnetic, electromechanical and thermal properties of solids” was used.

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Authors and Affiliations

  1. Research Institute of Physics, Southern Federal University, Rostov-on-Don, 344090, Russia

    K. M. Zhidel, A. V. Pavlenko, E. V. Glazunova & L. A. Reznichenko

  2. Federal Research Centre, The Southern Scientific Centre of the Russian Academy of Sciences, Rostov-on-Don, 344006, Russia

    A. V. Pavlenko

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  1. K. M. Zhidel
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  2. A. V. Pavlenko
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  3. E. V. Glazunova
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  4. L. A. Reznichenko
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Correspondence to K. M. Zhidel .

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Editors and Affiliations

  1. I. I. Vorovich Institute of Mathematics, Mechanics and Computer Science, Southern Federal University, Rostov-on-Don, Russia

    Ivan A. Parinov

  2. Department of Microelectronic Engineering, National Kaohsiung University of Science and Technology, Kaohsiung, Taiwan

    Shun-Hsyung Chang

  3. Institute for Research and Community Service, Universitas 17 Agustus 1945 Surabaya, Surabaya, Indonesia

    Erni Puspanantasari Putri

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Zhidel, K.M., Pavlenko, A.V., Glazunova, E.V., Reznichenko, L.A. (2024). Ferroelectric and Dielectric Properties of Solid Solution Ceramics Based on Bismuth Ferrite and Lead Ferroniobate Multiferroics with Germanium Dioxide Additive. In: Parinov, I.A., Chang, SH., Putri, E.P. (eds) Physics and Mechanics of New Materials and Their Applications. PHENMA 2023. Springer Proceedings in Materials, vol 41. Springer, Cham. https://doi.org/10.1007/978-3-031-52239-0_24

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