Abstract
The preparation of aluminum-vanadium (Al-V) intermediate alloys through the electrolysis of NaVO3 in the Na3AlF6-K3AlF6-AlF3 molten salt system using liquid aluminum as cathode is a novel process. In the present study, the forms of the Al-V intermetallic compounds and the contents of vanadium in the intermediate alloys were investigated at different current densities. The results showed that the cathode product contained aluminum matrix and Al10V at a current density of 0.6 A/cm2. As the current density increased to 0.7 A/cm2, the Al3V phase started to form while the vanadium content was still very low in the cathode product. At 0.8 A/cm2, the vanadium content in the cathode alloy product reached 7.83 wt.% with a current efficiency of 34.54%. However, no significant change in the vanadium content was noticed at current densities of 0.9 and 1.0 A/cm2.
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References
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Acknowledgements
This work was financially supported by the National Natural Science Foundation of China (grant no. 51974081) and the Fundamental Research Funds for the Central Universities (grant number N2225045).
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© 2024 The Minerals, Metals & Materials Society
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Hu, X., Zhang, Y., Shi, Z., Wang, Z. (2024). Direct Preparation of Aluminum-Vanadium Intermediate Alloy Through Electrolysis in Na3AlF6-K3AlF6-AlF3-NaVO3 Molten Salts. In: Forsberg, K., et al. Rare Metal Technology 2024. TMS 2024. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-031-50236-1_31
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DOI: https://doi.org/10.1007/978-3-031-50236-1_31
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