Skip to main content

MXenes-Based Composites for Pseudocapacitors

  • Chapter
  • First Online:
Pseudocapacitors

Part of the book series: Engineering Materials ((ENG.MAT.))

  • 193 Accesses

Abstract

MXenes, a family of two-dimensional (2D) transition metal carbides/nitrides with a general formula of Mn+1XnTx (n = 1–3), are demonstrated to act as a suitable electrode for high-performance energy storage devices owing to 2D lamellar structure, impressive density, metallic-like conductivity, availability of abundant active edge sites and tunable electrochemical properties, especially in supercapacitors. Nevertheless, MXenes have some demerits due to the aggregation and restacking of nanosheets, which hinder their further exploration. MXenes with the unique 2D layered surface and rich surface functional groups are easy to combine with other functional materials (transition metal oxides, transition metal disulfide compounds, conductive polymers, etc.) to construct composites, which can prevent MXenes aggregation, thereby promoting the formation of stable dispersions. Furthermore, owing to synergistic effects, the electrochemical performance of MXenes-based composites is superior to that of two precursors. In this chapter, the latest research progress of MXenes-based composites is elaborated and discussed. This chapter reviews various methods for preparing MXenes-based composites, introduces their applications in supercapacitors, and analyzes their excellent electrochemical properties. Similarly, we mainly focus on the current development, challenges, and prospects of MXenes-based composites for pseudocapacitors application.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. R. Ma, Z. Chen, D. Zhao, X. Zhang, J. Zhuo, Y. Yin, X. Wang, G. Yang, F. Yi, Ti3C2Tx MXene for electrode materials of supercapacitors. J. Mater. Chem. A 9, 11501–11529 (2021)

    Article  CAS  Google Scholar 

  2. Y. Wang, Y. Wang, Recent progress in MXene layers materials for supercapacitors: high-performance electrodes. SmartMat. 4, e1130 (2022)

    Article  Google Scholar 

  3. S. Sahoo, R. Kumar, E. Joanni, R.K. Singh, J.-J. Shim, Advances in pseudocapacitive and battery-like electrode materials for high performance supercapacitors. J. Mater. Chem. A 10, 13190–13240 (2022)

    Article  CAS  Google Scholar 

  4. Q. Zhu, J. Li, P. Simon, B. Xu, Two-dimensional MXenes for electrochemical capacitor applications: progress, challenges and perspectives. Energy Storage Mater. 35, 630–660 (2021)

    Article  Google Scholar 

  5. V.M. Hong Ng, H. Huang, K. Zhou, P.S. Lee, W. Que, J.Z. Xu, L.B. Kong, Recent progress in layered transition metal carbides and/or nitrides (MXenes) and their composites: synthesis and applications. J. Mater. Chem. A 5, 3039–3068 (2017)

    Google Scholar 

  6. Y. Cui, J. Zhu, H. Tong, R. Zou, Advanced perspectives on MXene composite nanomaterials: Types synthetic methods, thermal energy utilization and 3D-printed techniques. iScience 26, 105824 (2023)

    Google Scholar 

  7. S.A. Thomas, A. Patra, B.M. Al-Shehri, M. Selvaraj, A. Aravind, C.S. Rout, MXene based hybrid materials for supercapacitors: Recent developments and future perspectives. J. Energy Storage 55 (2022)

    Google Scholar 

  8. J. Yang, W. Bao, P. Jaumaux, S. Zhang, C. Wang, G. Wang, MXene-based composites: synthesis and applications in rechargeable batteries and supercapacitors. Adv. Mater. Interfaces 6, 1802004 (2019)

    Article  Google Scholar 

  9. M.S. Javed, A. Mateen, I. Hussain, A. Ahmad, M. Mubashir, S. Khan, M.A. Assiri, S.M. Eldin, S.S.A. Shah, W. Han, Recent progress in the design of advanced MXene/metal oxides-hybrid materials for energy storage devices. Energy Storage Mater. 53, 827–872 (2022)

    Article  Google Scholar 

  10. M. Ramezani Farani, B. Nourmohammadi Khiarak, R. Tao, Z. Wang, S. Ahmadi, M. Hassanpour, M. Rabiee, M.R. Saeb, E.C. Lima, N. Rabiee, 2D MXene nanocomposites: Electrochemical and biomedical applications. Environ. Sci.-Nano 9, 4038–4068 (2022)

    Google Scholar 

  11. L. Li, D. Zhang, J. Deng, Y. Gou, J. Fang, H. Cui, C. Zhang, M. Cao, Application of MXene-based materials in hybrid capacitors. Sustain Energ. Fuels 5, 3278–3291 (2021)

    Article  CAS  Google Scholar 

  12. W. Luo, Y. Ma, T. Li, H.K. Thabet, C. Hou, M.M. Ibrahim, S.M. El-Bahy, B.B. Xu, Z. Guo, Overview of MXene/conducting polymer composites for supercapacitors. J. Energy Storage 52, 105008 (2022)

    Article  Google Scholar 

  13. N.R. Hemanth, T. Kim, B. Kim, A.H. Jadhav, K. Lee, N.K. Chaudhari, Transition metal dichalcogenide-decorated MXenes: promising hybrid electrodes for energy storage and conversion applications. Mater. Chem. Front. 5, 3298–3321 (2021)

    Article  CAS  Google Scholar 

  14. Y. Luo, W. Que, X. Bin, C. Xia, B. Kong, B. Gao, L.B. Kong, Flexible MXene-based composite films: Synthesis, modification, and applications as electrodes of supercapacitors. Small 18, e2201290 (2022)

    Article  Google Scholar 

  15. J. Zhou, J. Yu, L. Shi, Z. Wang, H. Liu, B. Yang, C. Li, C. Zhu, J. Xu, A conductive and highly deformable all-pseudocapacitive composite paper as supercapacitor electrode with improved areal and volumetric capacitance. Small 14, e1803786 (2018)

    Article  Google Scholar 

  16. X. Zhang, B. Shao, A. Guo, Z. Sun, J. Zhao, F. Cui, X. Yang, MnO2 nanoshells/Ti3C2Tx MXene hybrid film as supercapacitor electrode. Appl. Surf. Sci. 560, 150040 (2021)

    Article  CAS  Google Scholar 

  17. Y. Ma, H. Sheng, W. Dou, Q. Su, J. Zhou, E. Xie, W. Lan, Fe2O3 nanoparticles anchored on the Ti3C2Tx MXene paper for flexible supercapacitors with ultrahigh volumetric capacitance. ACS Appl. Mater. Interf. 12, 41410–41418 (2020)

    Article  CAS  Google Scholar 

  18. R.A. Chavan, G.P. Kamble, S.B. Dhavale, A.S. Rasal, S.S. Kolekar, J.-Y. Chang, A.V. Ghule, NiO@MXene nanocomposite as an anode with enhanced energy density for asymmetric supercapacitors. Energy Fuels 37, 4658–4670 (2023)

    Article  CAS  Google Scholar 

  19. B. Shen, X. Liao, X. Zhang, H.-T. Ren, J.-H. Lin, C.-W. Lou, T.-T. Li, Synthesis of Nb2C MXene-based 2D layered structure electrode material for high-performance battery-type supercapacitors. Electrochim. Acta 413, 140144 (2022)

    Article  CAS  Google Scholar 

  20. W. Luo, Y. Sun, Z. Lin, X. Li, Y. Han, J. Ding, T. Li, C. Hou, Y. Ma, Flexible Ti3C2Tx MXene/V2O5 composite films for high-performance all-solid supercapacitors. J. Energy Storage 62, 106807 (2023)

    Article  Google Scholar 

  21. Y. Wang, X. Wang, X. Li, R. Liu, Y. Bai, H. Xiao, Y. Liu, G. Yuan, Intercalating ultrathin MoO3 nanobelts into MXene film with ultrahigh volumetric capacitance and excellent deformation for high-energy-density devices. Nanomicro Lett. 12, 115 (2020)

    CAS  Google Scholar 

  22. S.B. Ambade, R.B. Ambade, W. Eom, S.H. Noh, S.H. Kim, T.H. Han, 2D Ti3C2 MXene/WO3 hybrid architectures for high-rate supercapacitors. Adv. Mater. Interfaces 5, 1801361 (2018)

    Article  Google Scholar 

  23. X. Zhang, B. Shao, A. Guo, Z. Gao, Y. Qin, C. Zhang, F. Cui, X. Yang, Improved electrochemical performance of CoOx–NiO/Ti3C2Tx MXene nanocomposites by atomic layer deposition towards high capacitance supercapacitors. J. Alloy. Compd. 862, 158546 (2021)

    Article  CAS  Google Scholar 

  24. P. Asen, A. Esfandiar, H. Mehdipour, Urchin-like hierarchical ruthenium cobalt oxide nanosheets on Ti3C2Tx MXene as a binder-free bifunctional electrode for overall water splitting and supercapacitors. Nanoscale 14, 1347–1362 (2022)

    Article  CAS  Google Scholar 

  25. H. Liu, R. Hu, J. Qi, Y. Sui, Y. He, Q. Meng, F. Wei, Y. Ren, Y. Zhao, W. Wei, One-step synthesis of nanostructured CoS2 grown on titanium carbide MXene for high-performance asymmetrical supercapacitors. Adv. Mater. Interfaces 7, 1901659 (2020)

    Article  CAS  Google Scholar 

  26. H. Liu, R. Hu, J. Qi, Y. Sui, Y. He, Q. Meng, F. Wei, Y. Ren, Y. Zhao, A facile method for synthesizing NiS nanoflower grown on MXene (Ti3C2Tx) as positive electrodes for “supercapattery.” Electrochim. Acta 353, 136526 (2020)

    Article  CAS  Google Scholar 

  27. W. Hou, Y. Sun, Y. Zhang, T. Wang, L. Wu, Y. Du, W. Zhong, Mixed-dimensional heterostructure of few-layer MXene based vertical aligned MoS2 nanosheets for enhanced supercapacitor performance. J. Alloy. Compd. 859, 157797 (2021)

    Article  CAS  Google Scholar 

  28. M.S. Javed, X. Zhang, S. Ali, A. Mateen, M. Idrees, M. Sajjad, S. Batool, A. Ahmad, M. Imran, T. Najam, W. Han, Heterostructured bimetallic-sulfide@layered Ti3C2T-MXene as a synergistic electrode to realize high-energy-density aqueous hybrid-supercapacitor. Nano Energy 101, 107624 (2022)

    Article  CAS  Google Scholar 

  29. X. Chen, H. Ge, W. Yang, P. Yang, Construction of Ti3C2Tx MXene wrapped urchin-like CuCo2S4 microspheres for high-performance asymmetric supercapacitors. Dalton Trans. 52, 3746–3754 (2023)

    Article  CAS  Google Scholar 

  30. J.-Q. Qi, C.-C. Zhang, H. Liu, L. Zhu, Y.-W. Sui, X.-J. Feng, W.-Q. Wei, H. Zhang, P. Cao, MXene-wrapped ZnCo2S4 core-shell nanospheres via electrostatic self-assembly as positive electrode materials for asymmetric supercapacitors. Rare Met. 41, 2633–2644 (2022)

    Article  CAS  Google Scholar 

  31. J. Zhang, Z. Yao, W. Zou, Q. Shen, M. Fan, T. Ma, Trimetal NiCoMn sulfides cooperated with two-dimensional Ti3C2 for high performance hybrid supercapacitor. J. Solid State Chem. 308, 122909 (2022)

    Article  CAS  Google Scholar 

  32. R.S. Karmur, D. Gogoi, M.R. Das, N.N. Ghosh, High-performance flexible supercapacitor device composed of a hierarchical 2D MXene-Ni(OH)2 nanocomposite and biomass-derived porous carbon electrodes. Energy Fuels 36, 8488–8499 (2022)

    Article  CAS  Google Scholar 

  33. C. Zhu, C. Pei, H.S. Park, X. Yu, Design of 2D/2D heterostructure by coupling cobalt hydroxides with MXene on nickel foam for high energy density supercapacitors. J. Alloy. Compd. 948, 169809 (2023)

    Article  CAS  Google Scholar 

  34. X. Zhang, S. Yang, S. Liu, X. Che, W. Lu, Y. Tian, Z. Liu, Y. Zhao, J. Yang, Ti3C2Tx MXene-coupled NiCo-layered double hydroxide nanosheets with entire contact for high-performance supercapacitors. ACS Appl. Energy Mater. 6, 636–643 (2022)

    Article  Google Scholar 

  35. Y. Zhang, J. Cao, J. Li, Z. Yuan, D. Li, L. Wang, W. Han, Self-assembled Cobalt-doped NiMn-layered double hydroxide (LDH)/V2CT MXene hybrids for advanced aqueous electrochemical energy storage properties. Chem. Eng. J. 430, 132992 (2022)

    Article  CAS  Google Scholar 

  36. F. Liu, C. Wang, L. Wang, F. Huang, J. Fan, N. Shi, M. Han, Z. Dai, Oxygen-vacancy-rich NiMnZn-layered double hydroxide nanosheets married with Mo2CTx MXene for high-efficiency all-solid-state hybrid supercapacitors. ACS Appl. Energy Mater. 5, 3346–3358 (2022)

    Article  CAS  Google Scholar 

  37. K. Li, X. Wang, S. Li, P. Urbankowski, J. Li, Y. Xu, Y. Gogotsi, An ultrafast conducting polymer@MXene positive electrode with high volumetric capacitance for advanced asymmetric supercapacitors. Small 16, e1906851 (2020)

    Article  Google Scholar 

  38. X. Wang, Y. Wang, D. Liu, X. Li, H. Xiao, Y. Ma, M. Xu, G. Yuan, G. Chen, Opening MXene ion transport channels by intercalating PANI nanoparticles from the self-assembly approach for high volumetric and areal energy density supercapacitors. ACS Appl. Mater. Interf. 13, 30633–30642 (2021)

    Article  CAS  Google Scholar 

  39. L. Li, N. Zhang, M. Zhang, X. Zhang, Z. Zhang, Flexible Ti3C2Tx/PEDOT:PSS films with outstanding volumetric capacitance for asymmetric supercapacitors. Dalton Trans. 48, 1747–1756 (2019)

    Article  CAS  Google Scholar 

  40. W. Luo, Y. Sun, Y. Han, J. Ding, T. Li, C. Hou, Y. Ma, Flexible Ti3C2Tx MXene/polypyrrole composite films for high-performance all-solid asymmetric supercapacitors. Electrochim. Acta 441, 141818 (2023)

    Article  CAS  Google Scholar 

  41. H. Wang, L. Li, C. Zhu, S. Lin, J. Wen, Q. Jin, X. Zhang, In situ polymerized Ti3C2Tx/PDA electrode with superior areal capacitance for supercapacitors. J. Alloy. Compd. 778, 858–865 (2019)

    Article  CAS  Google Scholar 

  42. L. Yue, L. Chen, X. Wang, D. Lu, W. Zhou, D. Shen, Q. Yang, S. Xiao, Y. Li, Ni/Co-MOF@aminated MXene hierarchical electrodes for high-stability supercapacitors. Chem. Eng. J. 451, 138687 (2023)

    Article  CAS  Google Scholar 

  43. L. Yu, W. Li, C. Wei, Q. Yang, Y. Shao, J. Sun, 3D printing of NiCoP/Ti3C2 MXene architectures for energy storage devices with high areal and volumetric energy density. Nanomicro Lett. 12, 143 (2020)

    CAS  Google Scholar 

  44. Z. Pan, L. Kang, T. Li, M. Waqar, J. Yang, Q. Gu, X. Liu, Z. Kou, Z. Wang, L. Zheng, J. Wang, Black phosphorus@Ti3C2Tx MXene composites with engineered chemical bonds for commercial-level capacitive energy storage. ACS Nano 15, 12975–12987 (2021)

    Article  CAS  Google Scholar 

  45. Y. Yang, X. Huang, C. Sheng, Y. Pan, Y. Huang, X. Wang, In-situ formation of MOFs derivatives CoSe2/Ni3Se4 nanosheets on MXene nanosheets for hybrid supercapacitor with enhanced electrochemical performance. J. Alloy. Compd. 920, 165908 (2022)

    Article  CAS  Google Scholar 

  46. J. Yu, J. Zhou, P. Yao, H. Xie, M. Zhang, M. Ji, H. Liu, Q. Liu, C. Zhu, J. Xu, Antimonene engineered highly deformable freestanding electrode with extraordinarily improved energy storage performance. Adv. Energy Mater. 9, 1902462 (2019)

    Article  CAS  Google Scholar 

  47. A.S. Etman, J. Halim, J. Rosen, Mixed MXenes: Mo1.33CTz and Ti3C2Tz freestanding composite films for energy storage. Nano Energy 88, 106271 (2021)

    Google Scholar 

  48. M.Q. Long, K.K. Tang, J. Xiao, J.Y. Li, J. Chen, H. Gao, W.H. Chen, C.T. Liu, H. Liu, Recent advances on MXene based materials for energy storage applications. Mater. Today Sustain. 19, 100163 (2022)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Chunxu Pan .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2024 The Author(s), under exclusive license to Springer Nature Switzerland AG

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Sun, L., Pan, C. (2024). MXenes-Based Composites for Pseudocapacitors. In: Gupta, R.K. (eds) Pseudocapacitors. Engineering Materials. Springer, Cham. https://doi.org/10.1007/978-3-031-45430-1_11

Download citation

Publish with us

Policies and ethics