Abstract
In this paper nanostructured thin films with thickness of 150 nm have been prepared by aerosol deposition method on p-Si in the system (MgO)x(In2O3)(1−x) with the composition range x = 0.2, 0.4 and 0.6, using indium chloride and magnesium chloride as precursors. The produced films were investigated by scanning electron microscopy (SEM) and atomic force microscopy (AFM) to determine the morphology and roughness, energy dispersive X-ray (EDX) analysis for the chemical composition estimation, and X-ray diffraction (XRD) for establishing the structural and crystallographic phases. It was found that the nano-crystallites sizes grow with increasing the Mg content, therefore influencing the roughness of the films. The film surface roughness calculated from topographic AFM images is in the RMS range from 5.7 to 7.5 nm with increasing Mg concentration, but the value of the Coefficient of Kurtosis parameter is from 0.18 to 0.64. The evolution of the crystalline phases content with increasing the x value from 0.2 to 0.6 was established. The electrical and photoelectrical properties were studied by I-V characterization under the illumination with the light with the wavelength of 365 nm. It was shown that the films are sensitive to this radiation with the ratio of the photocurrent to the dark current from 5 to 7 at the excitation density of 2.4 mW/cm−2.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Jia-Lin, Y., Ke-Wei, L., De-Zhen, S.: Recent progress of ZnMgO ultraviolet photodetector. Chin. Phys. B 26(4), 47308 (2017). https://doi.org/10.1088/1674-1056/26/4/047308
Jr-Shiang, S., Sanjaya, B., Chuan-Pu, L., Jow-Lay, H.: Ultraviolet photodetectors based on MgZnO thin film grown by RF magnetron sputtering. Thin Solid Films 620, 170–174 (2016). https://doi.org/10.1016/j.tsf.2016.09.037
Hierro A., et al.: ZnMgO-based UV photodiodes: a comparison of films grown by spray pyrolysis and MBE. In: Oxide-Based Materials and Devices VII, vol. 9749, pp. 70–75. SPIE, Bellingham, WA, USA (2016). https://doi.org/10.1117/12.2213697
Morari, V., Ursaki, V.V., Rusu, E.V., Zalamai, V.V., Colpo, P., Tiginyanu, I.M.: Spin-coating and aerosol spray pyrolysis processed Zn1−xMgxO films for UV detector applications. Nanomaterials 12(18), 3209 (2022). https://doi.org/10.3390/nano12183209
Wang, L.K., et al.: Single-crystalline cubic MgZnO films and their application in deep-ultraviolet optoelectronic devices. Appl. Phys. Lett. 95, 131113 (2009). https://doi.org/10.1063/1.3238571
Chawla, S., Jayanthi, K., Chander, H.: Enhancement of luminescence in ZnMgO thin-film nanophosphors and application for white light generation. Phys. Stat. Sol. A 205(2), 271–274 (2008). https://doi.org/10.1002/pssa.200723149
Tsay C.Y., Chen, S.T., Fan, M.T.: Solution-processed Mg-substituted ZnO thin films for metal-semiconductor-metal visible-blind photodetectors. Coatings 9(4), 277 (2019). https://doi.org/10.3390/coatings9040277
Morari, V., et al.: Band tail state related photoluminescence and photoresponse of ZnMgO solid solution nanostructured films. Beilstein J. Nanotechnol. 12(11), 899–910 (2020). https://doi.org/10.3762/bjnano.11.75
Moses Ezhil, R.A., Selvan, G., Ravidhas, C., Jayachandran, M., Sanjeeviraja, C.: Magnesium indium oxide (MgIn2O4) spinel thin films: chemical spray pyrolysis (CSP) growth and materials characterizations. J. Colloid Interface Sci. 328(2), 396–401 (2008). https://doi.org/10.1016/j.jcis.2008.08.052
Morari, V., Zalamai, V., Rusu, E.V., Ursaki, V.V., Colpo, P., Tiginyanu, I.M.: Study of (In1−xGax)2O3 thin films produced by aerosol deposition method. Advanced Topics in Optoelectronics, Microelectronics, and Nanotechnologies XI. In: Proceedings of SPIE, vol. 12493, pp. 324–330 (2023). https://doi.org/10.1117/12.2642127
Chih-Chiang, Y., Kuan-Yu, C., Wei-Sheng, Y., Yan-Kuin, S., Zi-Hao, W.: Ultraviolet photodetection application in magnesium indium oxide thin film transistors via co-sputtering deposition. Appl. Sci. 10(15), 5128 (2020). https://doi.org/10.3390/app10155128
Xiaobin, B., Jianke, Y., Shengdong, Z.: Magnesium-doped indium oxide thin film transistors for ultraviolet detection. In: IEEE International Conference on Electron Devices and Solid State Circuits, 14986075 (2014). https://doi.org/10.1109/EDSSC.2014.7061093
Florian, S., Daniel, S., Stefan, M., von Holger, W., Marius, G.: Electronic defects in In2O3 and In2O3: Mg thin films on r-plane sapphire. Phys. Stat. Sol. B 252(10), 2304–2308 (2015). https://doi.org/10.1002/pssb.201552328
Tarsa, E.J., English, J.H., Speck, J.S.: Pulsed laser deposition of oriented ln2O3 on (001) InAs, MgO, and yttria-stabilized zirconia. Appl. Phys. Lett. 62(2332) (1993). https://doi.org/10.1063/1.109408
Suzy, S., Dominique, G., Mickaël, D., Gianguido, B., Stéphane, U., David, S.: Rapidly synthesis of nanocrystalline MgIn2O4 spinel using combustion and solidvstate chemistry. Solid State Sci. 13, 42–48 (2011). https://doi.org/10.1016/j.solidstatesciences.2010.10.004
Oliver, B., James, S.S.: Mg acceptor doping of In2O3 and overcompensation by oxygen vacancies. Appl. Phys. Lett. 101, 102107 (2012). https://doi.org/10.1063/1.4751854
Jun, N., Lian, W., Yu, Y., He, Y., Shu, J., Tobin, J.M.: Charge transport and optical properties of MOCVD-derived highly transparent and conductive Mg and Sn doped In2O3 thin films. Inorg. Chem. 44(17), 6071–6076 (2005). https://doi.org/10.1021/ic0501364
Prasad, K.H., et al.: Structural, magnetic and gas sensing activity of pure and Cr doped In2O3 thin films grown by pulsed laser deposition. Coatings 11(5), 558 (2021). https://doi.org/10.3390/coatings11050588
Moses, E.R.A., Subramanian, B., Senthilkumar, V., Jayachandran, M., Sanjeeviraja, C.: Synthesis and characterization of spray pyrolysed MgIn2O4 spinel thin films for novel applications. Physica E 40(3), 467–473 (2008). https://doi.org/10.1016/j.physe.2007.07.004
Wei, S.H., Zhang, S.B.: First-principles study of cation distribution in eighteen closed-shell AIIBIII2O4 and AIVBII2O4 spinel oxides. Phys. Rev. B 63, 045112 (2001). https://doi.org/10.1103/PhysRevB.63.045112
Acknowledgments
This work was supported financially by the ANCD through grant no. #20.80009.5007.02.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Ethics declarations
Conflict of Interest
The authors declare that they have no conflict of interest.
Rights and permissions
Copyright information
© 2024 The Author(s), under exclusive license to Springer Nature Switzerland AG
About this paper
Cite this paper
Morari, V., Rusu, D., Rusu, E.V., Ursaki, V.V., Tiginyanu, I.M. (2024). Characterization of Films Prepared by Aerosol Spray Deposition in the (MgO)x(In2O3)(1−x) System. In: Sontea, V., Tiginyanu, I., Railean, S. (eds) 6th International Conference on Nanotechnologies and Biomedical Engineering. ICNBME 2023. IFMBE Proceedings, vol 91. Springer, Cham. https://doi.org/10.1007/978-3-031-42775-6_6
Download citation
DOI: https://doi.org/10.1007/978-3-031-42775-6_6
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-031-42774-9
Online ISBN: 978-3-031-42775-6
eBook Packages: EngineeringEngineering (R0)