Skip to main content

Effect of SnO2 Doping on the Performance of High Voltage ZnO Varistors

  • Conference paper
  • First Online:
Smart Grid and Innovative Frontiers in Telecommunications (SmartGIFT 2022)

Abstract

The effect of the SnO2 doping on the structure and the electrical performance of ZnO varistors with high voltage was systematically studied. When the doping amount of SnO2 was small, the main effect was to promote the growth of grains. As the doping amount increased, SnO2 led to the formation of the Zn2SnO4 spinel, inhibiting the growth of ZnO grains. The donor concentration, the boundary barrier and the surface state density decreased first and then increased, respectively. By proper SnO2 doping, the key performance parameters of the high voltage varistors were improved, where the breakdown voltage gradient was increased from 193.0 to 208.5 V \( \cdot \) mm−1, the voltage ratio was reduced from 1.74 to 1.73, and the 2 ms square waveform impulse energy withstanding capacity was increased from 200 to 250 A.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Wang, M., et al.: High improvement of degradation behavior of ZnO varistors under high current surges by appropriate Sb2O3 doping. J. Eur. Ceram. Soc. 41(1), 436–442 (2021)

    Article  Google Scholar 

  2. Ruan, X., et al.: Effects of dispersant content and pH on dispersion of suspension, microstructures and electrical properties of ZnO varistors. Ceram. Int. 46(9), 14134–14142 (2020)

    Article  Google Scholar 

  3. Liu, W., Zhang, L., Kong, F., Wu, K., Li, S., Li, J.: Enhanced voltage gradient and energy absorption capability in ZnO varistor ceramics by using nano-sized ZnO powders. J. Alloys Compd. 828, 154252 (2020)

    Google Scholar 

  4. Meng, P., Zhao, X., Fu, Z., Wu, J., Hu, J., He, J.: Novel zinc-oxide varistor with superior performance in voltage gradient and aging stability for surge arrester. J. Alloys Compd. 789, 948–952 (2019)

    Google Scholar 

  5. Roy, S., Das, D., Roy, T.K.: Nonlinear electrical properties of ZnO-V2O5 based rare earth (Er2O3) added varistors. J. Electron. Mater. 48(9), 5650–5661 (2019)

    Article  Google Scholar 

  6. Zhao, M., Li, X., Li, T.Y., Shi, Y., Li, B.W.: Effect of Y2O3, Nd2O3 or Sm2O3 on the microstructure and electrical properties of ZnVMnNbO varistor ceramics. J. Mater. Sci. Mater. Electron. 30(1), 450–456 (2019)

    Article  Google Scholar 

  7. Roy, S., Roy, T.K., Das, D.: Grain growth kinetics of Er2O3 doped ZnO-V2O5 based varistor ceramics. Ceram. Int. 45(18), 24835–24850 (2019)

    Article  Google Scholar 

  8. Zhao, M., Wang, Y.-H., Sun, T.-T., Song, H.-H.: Effect of bismuth and vanadium as the varistor forming element in ZnO-based ceramics. J. Mater. Sci. Mater. Electron. 31(11), 8206–8211 (2020)

    Google Scholar 

  9. Gunnewiek, R.F.K., Perdomo, C.P.F., Cancellieri, I.C., Cardoso, A.L.F., Kiminami, R.H.G.A.: Microwave sintering of a nanostructured low-level additive ZnO-based varistor. Ceram. Int. 46(10), 15044–15053 (2020)

    Article  Google Scholar 

  10. Roy, S., Das, D., Roy, T.K.: Influence of sintering temperature on microstructure and electrical properties of Er2O3 added ZnO-V2O5-MnO2-Nb2O5 varistor ceramics. J. Alloys Compd. 749, 687–696 (2018)

    Google Scholar 

  11. Meng, P., et al.: Stable electrical properties of ZnO varistor ceramics with multiple additives against the AC accelerated aging process. Ceram. Int. 45(8), 11105–11108 (2019)

    Article  Google Scholar 

  12. Zhao, H., Hu, J., Chen, S., Xie, Q., He, J.: Improving age stability and energy absorption capabilities of ZnO varistors ceramics. Ceram. Int. 42(15), 17880–17883 (2016)

    Article  Google Scholar 

  13. Ruan, X., et al.: Effects of SiO2/Cr2O3 ratios on microstructures and electrical properties of high voltage gradient ZnO varistors. J. Mater. Sci. Mater. Electron. 30(13), 12113–12121 (2019)

    Article  Google Scholar 

  14. Cheng, L.-H., et al.: Electrical properties of Al2O3-doped ZnO varistors prepared by sol–gel process for device miniaturization. Ceram. Int. 38, S457–S461 (2012)

    Google Scholar 

  15. Zhu, J., Qi, G., Yang, H., Wang, F.: Microstructure and electrical properties of Pr 6 O 11 doped ZnO-Bi2O3-based varistors. J. Mater. Sci. Mater. Electron. 22(1), 96–100 (2011)

    Article  Google Scholar 

  16. He, J., Hu, J., Lin, Y.: ZnO varistors with high voltage gradient and low leakage current by doping rare-earth oxide. Sci. China Ser. E Technol. Sci. 51(6), 693–701 (2008)

    Article  Google Scholar 

  17. Canikoğlu, N., Toplan, N., Yıldız, K., Toplan, H.Ö.: Densification and grain growth of SiO2-doped ZnO. Ceram. Int. 32(2), 127–132 (2006)

    Article  Google Scholar 

  18. Qingwen, Z.: Study on the amelioration of the formula of ZnO varistor, Xidian University (2012)

    Google Scholar 

  19. Shuai, M., Xu, Z., Chu, R., Hao, J., Li, G.: Influence of SnO2 on ZnO–Bi2O3–Co2O3 based varistor ceramics. Ceram. Int. 41(9), 12490–12494 (2015)

    Article  Google Scholar 

  20. He, J., Long, W., Hu, J., Liu, J.: Nickel oxide doping effects on electrical characteristics and microstructural phases of ZnO varistors with low residual voltage ratio. J. Ceram. Soc. Jpn. 119(1385), 43–47 (2011)

    Article  Google Scholar 

  21. Wang, X., Ren, X., Li, Z., You, W., Shi, L.: A unique tuning effect of Mg on grain boundaries and grains of ZnO varistor ceramics. J. Eur. Ceram. Soc. 41(4) (2020)

    Google Scholar 

  22. Zhao, H., Hu, J., Chen, S., Xie, Q., He, J.: Tailoring the high-impulse current discharge capability of ZnO varistor ceramics by doping with Ga2O3. Ceram. Int. 42(4), 5582–5586 (2016)

    Article  Google Scholar 

  23. Meng, P., et al.: Stable electrical properties of ZnO varistor ceramics with multiple additives against the AC accelerated aging process. Ceram. Int. (2019)

    Google Scholar 

Download references

Acknowledgements

We acknowledge the fund support of Science and Technology Project of State Grid Hunan Electric Power Company (grant 5216AF210004).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Zhiyao Fu .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2023 ICST Institute for Computer Sciences, Social Informatics and Telecommunications Engineering

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Wang, B., Fu, Z., Kong, A. (2023). Effect of SnO2 Doping on the Performance of High Voltage ZnO Varistors. In: Yang, H., Fei, J., Qiang, T. (eds) Smart Grid and Innovative Frontiers in Telecommunications. SmartGIFT 2022. Lecture Notes of the Institute for Computer Sciences, Social Informatics and Telecommunications Engineering, vol 483. Springer, Cham. https://doi.org/10.1007/978-3-031-31733-0_15

Download citation

  • DOI: https://doi.org/10.1007/978-3-031-31733-0_15

  • Published:

  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-031-31732-3

  • Online ISBN: 978-3-031-31733-0

  • eBook Packages: Computer ScienceComputer Science (R0)

Publish with us

Policies and ethics