Abstract
Polymer-electrolytes, used in commercial energy devices, need to have small liquid components to achieve the desired electrochemical properties. Besides this, these polymer electrolytes have a low cationic transference number and slow ion movement. To get rid of these drawbacks, polymer-in-salt-electrolytes (PISEs) were hypothesized in the 1990s. In PISEs, ion transport is decoupled from polymer segment movement and it occurs through ion cluster, resulting in much faster ion transport in comparison to SIPEs (salt-in-polymer-electrolytes) and cationic transference number is also supposed to approach 1. Unfortunately, a polymer host which can accommodate a large amount of salt above the threshold value required for continuous ion cluster formation, and retain mechanical properties, is still to be identified. Till now, the approach has been to get a mixture of salts in the molten state and then add a small amount of polymer to get a solid morphology. Even after trying a variety of permutation combinations of salt, polymers, and additives, the targeted conductivity (10–4 S/cm) along with good mechanical properties is rarely reported. Owing to the state-of-art of electronic device technology which has reached to flexible device stage, the present-day energy devices (and hence the electrolytes) need to be flexible. Recently, a facile protocol, which does not use any sophisticated instruments and/or complicated chemical procedures, for the synthesis of PISEs using starch (a renewable polymer) as host polymer, has been reported. Conductivity up to 0.1 S/cm has been achieved in the flexible (bendable, stretchable, and twistable) morphology which can be easily cut into different shapes and sizes. Electrochemical-Stability-Window (ESW) is also quite good (>2.5 V). These electrolytes are quite stable with respect to ambient change. Presently, a new concept of Water-In-Polymer-Salt-Electrolyte (WIPSE) is being investigated. Because of the water-absorbing nature of starches, starch-based PISEs seem to inherently have this benefit also, and probably it is the reason for the exceptionally high conductivity observed in these materials. To the best of the author’s knowledge such high conducting, flexible, and economical PISE membranes were not reported in literature except for crosslinked-starch polymer host-based membranes.
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References
L. Long, S. Wang, M. Xiao, Y. Meng, J. Mater. Chem. A 4, 10038 (2016)
W. Münchgesang, P. Meisner, G. Yushin, AIP Conf. Proc. 1597, 196 (2014)
K. Fic, A. Platek, J. Piwek, E. Frackowiak, Materials Today, 21(4) (2018)
V.A. Oltean, S. Renault, M. Valvo, D. Brandell, Materials 9, 142 (2016)
F. B. Dias, L. Plomp, Jakobert, B.J. Veldhuis, Journal of Power Sources 88, 169–191 (2000)
P. Yao, H. Yu, Z. Ding, Y. Liu, J. Lu, M. Lavorgna, J. Wu, X. Liu, Front. Chem. 7, 522 (2019)
J.B. Kerr, Y.B. Han, G. Liu, C. Reeder, J. Xie, X. Sun, Electrochim. Acta 50, 235–242 (2004)
C.Y. Son, Z.G. Wang, J. Chem. Phys. 153, 100903 (2020)
Y. Zhang, P.S. Cremer, Curr. Opin. Chem. Biol. 10, 658–663 (2006)
Y. Lu, J. Chen, Nature Reviews Chemistry. https://doi.org/10.1038/s41570-020-0160-9
L. Wang, J. Li, G. Lu, W. Li, Q. Tao, C. Shi, H. Jin, G. Chen, S. Wang, Front. Mater. 7, 111 (2020)
S. Palchoudhury, K. Ramasamy, R.K. Gupta, A. Gupta, Flexible supercapacitors: a materials perspective. Front. Mater. 5, 83 (2019). https://doi.org/10.3389/fmats.2018.00083
H. Gao, N.S. Grundish, Y. Zhao, A. Zhou, J.B. Goodenough, Energy Material Advances 2021, Article ID 1932952, 10 pages. https://doi.org/10.34133/2021/1932952
F.S. Genier, I.D. Hosein, Macromolecules 54, 8553–8562 (2021)
H.K. Yoona, W.S. Chungb, N.J. Joa, Electrochemica Acta 50, 289–293 (2004)
K.K. Kar (ed.), Handbook of Nanocomposite Supercapacitor Materials III: Selection 1st ed. (Springer Series in Materials Science 313, 2021)
K.K. Kar (ed.), Handbook of Nanocomposite Supercapacitor Materials II: Selection 1st ed. (Springer Series in Materials Science 313, 2021)
K.K. Kar (ed.), Handbook of Nanocomposite Supercapacitor Materials I: Selection 1st ed. (Springer Series in Materials Science 313, 2021)
J.L.O. Martínez, L. Porcarelli, G.G. González, I. Calafel, M. Forsyth, D. Mecerreyes, A.J. Müller, A.C.S. Appl, Polym. Mater. 3(12), 6326–6337 (2021)
F. Makhlooghiazad, L.A. O’Dell, L. Porcarelli, C. Forsyth, N. Quazi, M. Asadi, O. Hutt, D. Mecerreyes, M. Forsyth, J.M Pringle, Nat Mater. 1–9 (2021)
H. Zhu, G. Huang, L.A. O’Dell, M. Forsyth, J. Phys. Chem. Lett. 12(40), 9853–9858 (2021)
A.S. Vega, C.A. Saenz, L.A. O’Dell, F. Brusciotti, A. Somers, M. Forsyth, Applied Surface Science 561, 149881 (2021)
A.H. Shah, U.A. Rana, H. Zhu, J. Li, R. Vijayaraghavan, D.R. Macfarlane, M. Forsyth, H.M. Siddiqi, J. Phys. Chem. B 125(39), 11005–11016 (2021)
G. Huang, L. Porcarelli, Y. Liang, M. Forsyth, H. Zhu, A.C.S. Appl, Energy Mater. 4(10), 10593–10602 (2021)
B. Roy, P. Cherepanov, C. Nguyen, C. Forsyth, U. Pal, T.C. Mendes, P. Howlett, M. Forsyth, D. MacFarlane, M. Kar, Adv. Energy Mater. 11(36), 2101422 (2021)
C.M. Cholant, M.P. Rodrigues, L.L. Peres, R.D.C. Balboni, L.U. Krüger, D.N. Placido, W.H. Flores, A. Gündel, A. Pawlicka, C.O. Avellaneda, Journal of Solid State Electrochemistry 24, 1867–1875 (2020)
F.C. Sentanin, W.R. Caliman, R.C. Sabadini, C.C.S. Cavalheiro, R.F.P. Pereira, M.M. Silva, A. Pawlicka, Molecules 26, 2139 (2021)
C.M. Cholant, L.U. Krüger, R.D.C. Balboni, M.P. Rodrigues, F.C. Tavares, L.L. Peres, W.H. Flores, A. Gündel, A. Pawlicka, C.O. Avellaneda, Ionics 26, 2941–2948 (2020)
T. Winie, A.K. Arof, S.Thomas (ed.), Polymer Electrolytes: Characterization Techniques and Energy Applications (WILEY-VCH, December 2019)
H.J. Kang, J.W. Park, H.J. Hwang, H. Kim, K.S. Jang, X. Ji, H.J. Kim, W.B. Im, Y.S. Jun, Carbon Energy. 3, 976–990 (2021)
X. Ji, C. Zhang, US Patent App. 17, 283,184 (2021)
X. Yu, A. Manthiram, Energy Adv., Advance Article (2022),
F. Zou, H.C. Nallan, A. Dolocan, Q. Xie, J. Li, B.M. Coffey, J.G. Ekerdt, A. Manthiram, Energy Storage Materials 43, 499–508 (2021)
E. Quartarone, P. Mustarelli, J. Electrochem. Soc. 167, 050508 (2020)
P.B. Balbuena, AIP Conf. Proc. 82, 1597 (2014)
M.B. Armand, J.M. Chabango, M. Duclot, Second international meeting on solid electrolytes (St. Andrews, Scotland, 1978), pp.20–22
D. Bresser, S. Lyonnard, C. Iojoiu, L. Picard, S. Passerini, Mol. Syst. Des. Eng. 4, 779 (2019)
H. Du, Z. Wu, Y. Xu, S. Liu, H. Yang, Polymers 12, 297 (2020)
J.H. Park, H.H. Rana, J.Y. Lee, H.S. Park, J. Mater. Chem. A 7, 16962 (2019)
Md.Y. Bhat, N. Yadav, S.A. Hashmi, Mater. Sci. Eng., B 262, 114721 (2020)
Z. Florjan, E.Z. Monikowska, W. Wieczorek, A. Ryszawy, A. Tomaszewska, K. Fredman, D. Golodnitsky, E. Peled, B. Scrosati, J. Phys. Chem. B 108, 14907–14914 (2004)
J. Fan, R.F. Marzke, C.A. Angell, Mat. Res. Soc. Symp. Proc. 293, 87–92 (1993)
C.A. Angell, C. Liu, E. Sanchez, Nature 362, 137 (1993)
C.A. Angell, Annu. Rev. Phys. Chern. 43, 693–717 (1992)
W. Xu, L. M. Wang, C.A. Angell, Electrochimica Acta 48, 2037/2045 (2003)
W. Liu, C. Yi, L. Li, S. Liu, Q. Gui, D. Ba, Y. Li, D. Peng, J. Liu, Angew. Chem. Int. Ed. https://doi.org/10.1002/anie.202101537
F. Chen, X.N Wang, M. Armand, M Forsyth, https://doi.org/10.21203/rs.3.rs-532893/v1
A. Zalewska, I. Pruszczyk, E. Sulek, W. Wieczorek, Solid State Ionics 157, 233–239 (2003)
C. Yi, W. Liu, L. Li, H. Dong, J. Liu, Funct. Mater. Lett. 12(6), 1930006 (2019)
L. Feng, H. Cui, J. Power Sources 63, 145–148 (1996)
M. Forsyth, J. Sun, D.R. Macfarlane, A.J. Hill, Journal of Polymer Science: Part B: Polymer. Physics 38, 341–350 (2000)
Z. Wang, W. Gao, X. Huang, Y. Mo, L. Chen, Electrochem. Solid-State Lett. 4(9), A148–A150 (2001)
O. Borodin, L. Suo, M. Gobet, X. Ren, F. Wang, A. Faraone, J. Peng, M. Olguin, M. Schroeder, M.S. Ding, E. Gobrogge, A.V.W. Cresce, S. Munoz, J.A. Dura, S. Greenbaum, C. Wang, K. Xu, ACS Nano 11(10), 10462–10471 (2017)
H. Wang, Z. Wang, B. Xue, Q. Meng, X. Huang, L. Chen, Chem. Commun. 2186–2187 (2004).
A. Tomaszewska, E. Zygadlo-Monikowska, Z. Florjanczyk, Solid Polymer-in-Salt Electrolytes, Abs. 531, 206th Meeting, © 2004 The Electrochemical Society, Inc
A.K. Łasinska, M. Marzantowicz, J.R. Dygas, F. Krok, Z. Florjanczyk, A. Tomaszewska, E. Zygadło Monikowska, Z. Zukowska, U. Lafont, Electrochmica Acta 169, 61–72 (2015)
M.K. Kim, Y.J. Lee, N.J. Jo, Surface Review and Letters 17(1), 63–68 (2010)
B. Wu, L. Wang, Z. Li, M. Zhao, K. Chen, S. Liu, Y. Pu, J. Li, J. Electrochem. Soc. 163(10), A2248–A2252 (2016)
M. Forsyth, J. Sun, D.R. Macfarlane, A.J. Hill, Journal of Polymer Science: Part B: Polymer Physics 38, 341–350 (2000)
M.M. Doeff, L. Edman, S.E. Sloop, J. Kerr, L.C. De Jonghe, J. Power Sources 89, 227–231 (2000)
A. Ferry, L. Edman, M. Forsyth, D.R. MacFarlane, J. Sun, J. Appl. Phys. 86, 2346 (1999). https://doi.org/10.1063/1.371053
Y. Wu, F. Geng, R. Peter, Yu.J. Chang, X.M. Ying, Carbohydr Polym 76, 299 (2009)
K. Bashir, M. Aggarwal, J Food Sci Technol 56(2), 513–523 (2019)
S.A. Shahzad, S. Hussain, A.A. Mohamed, M.S. Alamri, M.A. Ibraheem, A.A.A. Qasem, Foods 8(12), 687 (2019)
M.A. Villar, S.E. Barbosa, M.A. García, L.A. Castillo, O.V. López (ed.), Starch-Based Materials in Food Packaging Processing, Characterization and Applications (Academic Press, 2017)
R. Thakur, P. Pristijono, C.J. Scarlett, M. Bowyer, S.P. Singh, Q.V. Vuong, Int. J. Biol. Macromol. 132, 1079–1089 (2019)
L. Moreau, W. Bindzus, S. Hill, Starch/Starke 63, 676–682 (2011)
L. Moreau, W. Bindzus, S. Hill, Starch/Starke 63, 669–675 (2011)
C. Bircan, S.A. Barringer, Journal of food science 63(6), 983–986 (1998)
W. Samutsri, M. Suphantharika, Carbohyd. Polym. 87, 1559–1568 (2012)
D. Vieira, C. Avellaneda, A. Pawlicka, Electrochim. Acta 53, 1404 (2007)
H. Mallick, A. Sarkar, J Non-Cryst Solids 352, 795 (2006)
S.S. Pradhan, A. Sarkar, Mater Sci Eng, C 29, 1790 (2009)
Y. Zhang, J. Zheng, Electrochim Acta 54, 749 (2008)
X. Kang, J. Wang, Z. Tang, H. Wu, Y. Lin, Talanta 78, 120 (2009)
S.C. Pang, C.L. Tay, S.F. Chin, Ionics 20(10), 1455–1462 (2014)
V.L. Finkenstadt, Appl. Microbiol. Biotechnol. 67, 735 (2005)
V.L. Finkenstadt, J.L. Willett, J. Polym. Environ. 2, 43 (2004)
W. Ning, Z. Xingxiang, L. Haihui, W. Jianping, Carbohyd. Polym. 77, 607–611 (2009)
P.K. Singh, B. Bhattacharya, R.K. Nagarale, K.W. Kim, H.W Rhee, Synthetic Metals, 160, 139–142 (2010)
T. Tiwari, K.P. Pandey, N. Srivastava, P.C. Srivastava, J. Appl. Polym. Sci. 121(1), 1 (2011)
V.L. Finkenstadt, J.L. Willett, Adv Biopolymers, ACS Symposium Series, Chapter 17, 935, p. 256 (2006)
M.E. Gomes, A.S. Ribeiro, P.B. Malafaya, R.L. Reis, A.M. Chuha, Biomaterials 22, 883–889 (2001)
T. Tiwari, M. Kumar, N. Srivastava, P.C. Srivastava, Mater. Sci. Eng., B 182, 6–13 (2014)
T. Tiwari, N. Srivastava, P.C. Srivastava, Ionics 17, 353 (2011)
M. Yadav, G. Nautiyal, A. Verma, M. Kumar, T. Tiwari, N. Srivastava, Ionics 25, 2693–2700 (2019)
M. Yadav, M. Kumar, N. Srivastava, Electrochemica Acta 283, 1551–1559 (2018)
J.K. Chauhan, D. Yadav, M. Yadav, M. Kumar, T. Tiwari, N. Srivastava, S.N. Appl, Sci. 2, 899 (2020)
B. Komal, M. Yadav, M. Kumar, T. Tiwari, N. Srivastava, e-Polymers 19, 453–461 (2019)
T. Tiwari, M. Kumar, M. Yadav, N. Srivastava, Macromolecular Symposia 388(1), 1900033 (2019)
Z. Khan, U. Ail, F.N. Ajjan, J. Phopase, Z.U. Khan, N. Kim, J. Nilsson, O. Inganäs, M. Berggren, X. Crispin, Adv. Energy Sustainability Res. 2100165 (2021)
T. Tiwari, N. Srivastava, Macromol. Symp. 388(1), 1900041 (2019)
T. Tiwari, J.K. Chauhan, M. Yadav, M. Kumar, N. Srivastava, Ionics 23, 2809–2815 (2017)
M. Yadav, M. Kumar, T. Tiwari, N. Srivastava, Ionics 23, 2871–2880 (2016)
T. Tiwari, M. Kumar, M. Yadav, N. Srivastava, Starch-Stärke 1800313 (2019)
J.K. Chauhan, M. Kumar, M. Yadav, T. Tiwari, N. Srivastava, Ionics 23, 2943–2949 (2017)
N. Srivastava, in Supercapacitor Technology: Materials, Processes and Architectures. ed. by Inamuddin, R. Boddula, M.I. Ahamed and A.M. Asiri (Materials Research Foundations US 2019) p.121
R. Sadeghi, F. Jahani, J. Phys. Chem. B 116, 5234–5241 (2012)
Acknowledgements
The author is thankful to University Grant Commission (New Delhi) for supporting the project entitled “Synthesis & Electrical Characterization of Starch-based Electrolyte Systems” through project sanction no 42-814/2013 (SR) dated 22.03.2016. and to BHU-Varanasi for providing an “Incentive grant to senior faculties” under IoE Scheme (Year 2021–2022) to carryout crosslinked starch-based electrolytes work. Author is thankful to Ms. Dipti Yadav (Ph.D. scholar) for helping in manuscript preparation.
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Srivastava, N. (2023). Flexible-High-Conducting Polymer-In-Salt-Electrolyte (PISE) Membranes: A Reality Due to Crosslinked-Starch Polymer Host. In: Kar, K.K. (eds) Handbook of Nanocomposite Supercapacitor Materials IV. Springer Series in Materials Science, vol 331. Springer, Cham. https://doi.org/10.1007/978-3-031-23701-0_10
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