Abstract
A thermodynamic analysis of the reduction process of iron-based oxide systems with nickel and cobalt additives in various gaseous media (coke oven gas, carbon monoxide(II), and hydrogen) has been carried out. The method of minimizing the total thermodynamic potentials was used to calculate the equilibrium compositions of the products of the process under study. The expediency of using hydrogen for the reduction of iron oxide is shown. Its optimal concentration and process temperature are established.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Tanwar R, Kumar S, Mandal UK (2017) Photocatalytic activity of PANI/Fe0 doped BiOCl under visible light-degradation of Congo red dye. J Photochem Photobiol A: Chem 333:105–116
Zhou M et al (2005) Preparation and photocatalytic activity of Fe-doped mesoporous titanium dioxide nanocrystalline photocatalysts. Mater Chem Phys 93(1):159–163
Hu B et al (2018) Co/Fe-bimetallic organic framework-derived carbon-incorporated cobalt–ferric mixed metal phosphide as a highly efficient photocatalyst under visible light. J Colloid Interface Sci 531:148–159
Till BA, Weathers LJ, Alvarez PJJ (1998) Fe(0)-supported autotrophic denitrification. Environ Sci Technol 32(5):634–639
Cheng R, Wang J, Zhang W (2007) Comparison of reductive dechlorination of p-chlorophenol using Fe0 and nanosized Fe0. J Hazard Mater 144(1–2):334–339
Son HS, Im JK, Zoh KD (2009) A Fenton-like degradation mechanism for 1, 4-dioxane using zero-valent iron (Fe0) and UV light. Water Res 43(5):1457–1463
Scorzelli RB (1997) A study of phase stability in invar Fe–Ni alloys obtained by non-conventional methods. Hyperfine Interact 110(1):143–150
Yao LH et al (2010) Core–shell structured nanoparticles (M@ SiO2, Al2O3, MgO; M= Fe, Co, Ni, Ru) and their application in COx-free H2 production via NH3 decomposition. Catal Today 158(3–4):401–408
Frolova L, Kharytonov M (2019) Synthesis of magnetic biochar for efficient removal of Cr(III) cations from the aqueous medium. Adv Mater Sci Eng 2019
Nguyen TH et al (2021) Impact of iron on the Fe–Co–Ni ternary nanocomposites structural and magnetic features obtained via chemical precipitation followed by reduction process for various magnetically coupled devices applications. Nanomaterials 11(2):341
Bilgilisoy E et al (2021) Low energy electron-and ion-induced surface reactions of Fe(CO)5 thin films. J Phys Chem C 125(32):17749–17760
Kwak YJ, Park HR, Song MY (2017) Analysis of the metal hydride decomposition temperatures of Zn(BH4)2–MgH2–Tm (Tm = Ni, Ti or Fe) using a sievert’s type volumetric apparatus. Mater Sci 23(1):21–26
Toneguzzo P et al (2000) CoNi and FeCoNi fine particles prepared by the polyol process: physico-chemical characterization and dynamic magnetic properties. J Mater Sci 35(15):3767–3784
Frolova LA, Hrydnieva TV (2020) Influence of various factors on the ferric oxyhydroxide synthesis. J Chem Technol 28(1):61–67
Frolova LA, Khmelenko OV (2021) The study of Co–Ni–Mn ferrites for the catalytic decomposition of 4-nitrophenol. Catal Lett 151(5):1522–1533
Wang D et al (2017) Innovative evaluation of CO–H2 interaction during gaseous wustite reduction controlled by external gas diffusion. Int J Hydrogen Energy 42(20):14047–14057
Yang JM, Tsuo WJ, Yen FS (1999) Preparation of ultrafine nickel ferrite powders using mixed Ni and Fe tartrates. J Solid State Chem 145(1):50–57
Orth WS, Gillham RW (1995) Dechlorination of trichloroethene in aqueous solution using Fe0. Environ Sci Technol 30(1):66–71
Geng B et al (2009) Kinetics of hexavalent chromium removal from water by chitosan-Fe0 nanoparticles. Chemosphere 75(6):825–830
Mikhalichenko AI, Nefedova NV, Karateeva EY (1998) Hydrogen reduction of ultrafine α–Fe2O3 powders. Russ J Inorg Chem 43(2):138–141
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2023 The Author(s), under exclusive license to Springer Nature Switzerland AG
About this paper
Cite this paper
Frolova, L., Blyuss, B. (2023). Thermodynamic Analysis of the Process Obtaining Promoted Iron in Various Gaseous Media. In: Fesenko, O., Yatsenko, L. (eds) Nanomaterials and Nanocomposites, Nanostructure Surfaces, and Their Applications . Springer Proceedings in Physics, vol 279. Springer, Cham. https://doi.org/10.1007/978-3-031-18096-5_3
Download citation
DOI: https://doi.org/10.1007/978-3-031-18096-5_3
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-031-18095-8
Online ISBN: 978-3-031-18096-5
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)