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Nanostructuring by Photochemistry: Laser-Induced Type A Modification

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Ultrafast Laser Nanostructuring

Part of the book series: Springer Series in Optical Sciences ((SSOS,volume 239))

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Abstract

The femtosecond direct laser writing technique provides a robust and efficient way to directly inscribe embedded 3D photonic devices in bulk glasses. Following direct laser writing, a local optical properties change is induced that is generally classified under three distinguished types (type I, type II, and type III). Each type allows for the fabrication of its own variety of 3D photonic components.

Glasses containing photosensitive metal salts such as silver open a whole field of tailored optical applications. This photosensitivity allows for fine control of the defects generated during femtosecond laser interaction. In practice, direct laser writing induces the creation of a new type of optical properties change, called type Argentum (Type A). It is based on the development of silver clusters that allow the creation of many optical properties such as positive refractive index (RI) change, fluorescence, and second-order nonlinear properties at the nanoscale. In this chapter, we report that type Argentum modifications could be triggered in silver-containing glasses by finely choosing the inscription parameters. The multiphysical mechanisms of optical properties changes and the consequences on the regimes of interaction will be discussed. The numerous applications of the Type A laser modification will be addressed.

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Authors and Affiliations

  1. Universite Bordeaux, Talence, France

    Lionel Canioni

  2. Institut de Chimie de la Matière Condensée de Bordeaux, University de Bordeaux, Pessac, France

    Yannick Petit & Thierry Cardinal

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  1. Lionel Canioni
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  2. Yannick Petit
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Correspondence to Lionel Canioni .

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  1. Laboratoire Hubert Curien, Université Jean Monnet, Saint Etienne, France

    Razvan Stoian

  2. Bundesanstalt für Materialforschung und -prüfung (BAM), Berlin, Germany

    Jörn Bonse

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Canioni, L., Petit, Y., Cardinal, T. (2023). Nanostructuring by Photochemistry: Laser-Induced Type A Modification. In: Stoian, R., Bonse, J. (eds) Ultrafast Laser Nanostructuring. Springer Series in Optical Sciences, vol 239. Springer, Cham. https://doi.org/10.1007/978-3-031-14752-4_19

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