Abstract
The objective of our work is to evaluate the synergistic effect of the essential oil of Allium Sativum and diethylthiourea to inhibit the corrosion of carbon steel against an aggressive medium of 0.5 M sulfuric acid. After extraction and identification of the essential oil by gas chromatography coupled to mass spectrometry (GC MS), a study was carried out by different electrochemical techniques (impedance spectroscopy (EIS), potentiodynamic polarization (PDP), and surface analysis by scanning electron microscopy associated with X-ray Dispersive Energy microanalysis (SEM/EDX). The polarization curves indicate that the mixture used acts as an excellent inhibitor significantly slowing down the corrosion rate. The results obtained show that the inhibiting efficiency depends on the concentration of the compound as well as the temperature used. It reached 98.11% at a concentration of 1.5 g/l of DT alone, and it overcomes to 99.19% when adding 1 g/l of the essential oil of Allium Sativum. Other thermodynamic parameters of the activation process and metal dissolution are also calculated and discussed.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Abdallah, M., H.M Al-Tass, B.A. AL Jahdaly, et A.S. Fouda. 2016. « Inhibition Properties and Adsorption Behavior of 5-Arylazothiazole Derivatives on 1018 Carbon Steel in 0.5 M H2SO4 Solution ». Journal of Molecular Liquids 216 (avril): 590–97. https://doi.org/10.1016/j.molliq.2016.01.077.
Anaee, Rana Afif, Ivan Hameed R. Tomi, Majid Hameed Abdulmajeed, Shaimaa Alaa Naser, et Mustafa Mohammed Kathem. 2019. « Expired Etoricoxib as a Corrosion Inhibitor for Steel in Acidic Solution ». Journal of Molecular Liquids 279 (avril): 594–602. https://doi.org/10.1016/j.molliq.2019.01.169.
Aramaki, Kunitsugu, Minori Hagiwara, et Hiroshi Nishihara. 1987a. « The Synergistic Effect of Anions and the Ammonium Cation on the Inhibition of Iron Corrosion in Acid Solution ». Corrosion Science 27 (5): 487–97. https://doi.org/10.1016/0010-938X(87)90092-8.
Aramaki, Kunitsugu, Minori Hagiwara, et Hiroshi Nishihara. 1987b. « Adsorption and Corrosion Inhibition Effect of Anions Plus an Organic Cation on Iron in 1M HClO4 and the HSAB Principle ». Journal of The Electrochemical Society 134 (8): 1896–1901. https://doi.org/10.1149/1.2100785.
Batah, A., M. Belkhaouda, L. Bammou, A. Anejjar, R. Salghi, A. Chetouani, L. Bazzi, et B. Hammouti. 2017. « Corrosion Inhibition of Carbon Steel in Acidic Medium by Grapefruit Oil Extract ». Moroccan Journal of Chemistry 5 (4): 5–589. https://doi.org/10.48317/IMIST.PRSM/morjchem-v5i4.9797.
Bentiss, F., M. Lebrini, et M. Lagrenée. 2005. « Thermodynamic Characterization of Metal Dissolution and Inhibitor Adsorption Processes in Mild Steel/2,5-Bis(n-Thienyl)-1,3,4-Thiadiazoles/Hydrochloric Acid System ». Corrosion Science 47 (12): 2915–31. https://doi.org/10.1016/j.corsci.2005.05.034.
Boughoues, Y., M. Benamira, L. Messaadia, et N. Ribouh. 2020. « Adsorption and Corrosion Inhibition Performance of Some Environmental Friendly Organic Inhibitors for Mild Steel in HCl Solution via Experimental and Theoretical Study ». Colloids and Surfaces A: Physicochemical and Engineering Aspects 593 (mai): 124610. https://doi.org/10.1016/j.colsurfa.2020.124610.
Chafai, Nadjib, Salah Chafaa, Khalissa Benbouguerra, Djamel Daoud, Abdelkader Hellal, et Mouna Mehri. 2017. « Synthesis, Characterization and the Inhibition Activity of a New α-Aminophosphonic Derivative on the Corrosion of XC48 Carbon Steel in 0.5M H2SO4: Experimental and Theoretical Studies ». Journal of the Taiwan Institute of Chemical Engineers 70 (janvier): 331–44. https://doi.org/10.1016/j.jtice.2016.10.026.
Cruz, J., R. Martınez, J. Genesca, et E. Garcıa-Ochoa. 2004. « Experimental and theoretical study of 1-(2-ethylamino)-2-methylimidazoline as an inhibitor of carbon steel corrosion in acid media ». Journal of Electroanalytical Chemistry 566 (1): 111–121.
Dkhirech, N., Mouhsine Galai, Younes El Kacimi, Mohamed Rbaa, Mo Ouakki, Brahim Lakhrissi, et Merzougui Touhami. 2017. « New Quinoline derivatives as sulfuric acid inhibitor’s for mild steel ». Analytical and Bioanalytical Electrochemistry 9 (octobre).
El Ouali, I., Chetouani, A., Hammouti, B., Aouniti, A., Touzani, R., El Kadiri, S., Nlate, S., 2013. Thermodynamic Study and Characterization by Electrochemical Technique of Pyrazole Derivatives as Corrosion Inhibitors for C38 Steel in Molar Hydrochloric Acid: Port. Electrochimica Acta 31, 53–78. https://doi.org/10.4152/pea.201302053.
Epelboin, Israel, et Michel Keddam. 1970. « Faradaic Impedances: Diffusion Impedance and Reaction Impedance ». Journal of The Electrochemical Society 117 (8): 1052. https://doi.org/10.1149/1.2407718.
Essaadaoui, Youness, Mouhsine Galai, Mo Ouakki, Lamya Kadiri, Abdelkarim Ouass, Mohammed Cherkaoui, Housseine Rifi, Ahmed Lebkiri, et El Rifi. 2018. « STUDY OF THE ANTICORROSIVE ACTION OF EUCALYPTUS CAMALDULENSIS EXTRACT IN CASE OF MILD STEEL IN 1.0 M HCl. », décembre, 431‑42.
Ferraa, N., Ouakki, M., Cherkaoui, M. et al. Synthesis, Characterization and Evaluation of Apatitic Tricalcium Phosphate as a Corrosion Inhibitor for Carbon Steel in 3 wt% NaCl .J Bio Tribo Corros 8, 23 (2022). https://doi.org/10.1007/s40735-021-00622-4.
Guo, Wenjuan, Ahmad Umar, Qi Zhao, Mabkhoot A. Alsaiari, Yas Al-Hadeethi, Luyan Wang, et Meishan Pei. 2020. « Corrosion Inhibition of Carbon Steel by Three Kinds of Expired Cephalosporins in 0.1 M H2SO4 ». Journal of Molecular Liquids 320 (décembre): 114295. https://doi.org/10.1016/j.molliq.2020.114295.
Hmamou, D. Ben, R. Salghi, A. Zarrouk, H. Zarrok, R. Touzani, B. Hammouti, et A. El Assyry. 2015. « Investigation of Corrosion Inhibition of Carbon Steel in 0.5 M H2SO4 by New Bipyrazole Derivative Using Experimental and Theoretical Approaches ». Journal of Environmental Chemical Engineering 3 (3): 2031–41. https://doi.org/10.1016/j.jece.2015.03.018.
Keleş, Hülya, Mustafa Keleş, et Koray Sayın. 2021. « Experimental and Theoretical Investigation of Inhibition Behavior of 2-((4-(Dimethylamino)Benzylidene)Amino)Benzenethiol for Carbon Steel in HCl Solution ». Corrosion Science 184 (mai): 109376. https://doi.org/10.1016/j.corsci.2021.109376.
Kesri, Fatima, Abed Affoune, et Ilhem Djaghout. 2019. « Effects of Thiourea on the Kinetics and Electrochemical Nucleation of Tin Electrodeposition from Stannous Chloride Bath in Acidic Medium ». Journal of the Serbian Chemical Society 84 (1): 41–53. https://doi.org/10.2298/JSC180325107K.
Korkmaz, Neslihan, Oday A. Obaidi, Murat Senturk, Demet Astley, Deniz Ekinci, et Claudiu T. Supuran. 2015. « Synthesis and Biological Activity of Novel Thiourea Derivatives as Carbonic Anhydrase Inhibitors ». Journal of Enzyme Inhibition and Medicinal Chemistry 30 (1): 75‑80. https://doi.org/10.3109/14756366.2013.879656.
Kumar, C.B.P., Prashanth, M.K., Mohana, K.N., Jagadeesha, M.B., Raghu, M.S., Lokanath, N.K., Mahesha, Kumar, K.Y., 2020. Protection of mild steel corrosion by three new quinazoline derivatives: experimental and DFT studies. Surf. Interfaces 18, 100446. https://doi.org/10.1016/j.surfin.2020.100446.
Loto, R T, C A Loto, et A P I Popoola. 2012. « Corrosion Inhibition of Thiourea and Thiadiazole Derivatives : A Review », 10.
Mzioud, K., A. Habsaoui, M. Ouakki, M. Galai, S. El Fartah, et M. Ebn Touhami. 2020. « Inhibition of Copper Corrosion by the Essential Oil of Allium Sativum in 0.5M H2SO4 Solutions ». SN Applied Sciences 2 (9): 1611. https://doi.org/10.1007/s42452-020-03393-8.
Ouakki, Mo, Mouhsine Galai, Mohammed Cherkaoui, E.-H Rifi, et Z. Hatim. 2018. « Inorganic compound (Apatite doped by Mg and Na) as a corrosion inhibitor for mild steel in phosphoric acidic medium ». Analytical and Bioanalytical Electrochemistry 10 (juillet): 943–60.
Ouakki, M., Galai, M., Benzekri, Z., Aribou, Z., Ech-chihbi, E., Guo, L., Dahmani, K., Nouneh, K., Briche, S., Boukhris, S., Cherkaoui, M., 2021. A detailed investigation on the corrosion inhibition effect of by newly synthesized pyran derivative on mild steel in 1.0 M HCl: Experimental, surface morphological (SEM-EDS, DRX& AFM) and computational analysis (DFT & MD simulation). J. Mol. Liq. 344, 117777. https://doi.org/10.1016/j.molliq.2021.117777.
Ouchrif, A., M. Zegmout, B. Hammouti, S. El-Kadiri, et A. Ramdani. 2005. « 1,3-Bis(3-Hyroxymethyl-5-Methyl-1-Pyrazole) Propane as Corrosion Inhibitor for Steel in 0.5M H2SO4 Solution ». Applied Surface Science 252 (2): 339–44. https://doi.org/10.1016/j.apsusc.2005.01.005.
Ouici, H., M. Tourabi, O. Benali, C. Selles, C. Jama, A. Zarrouk, et F. Bentiss. 2017. « Adsorption and Corrosion Inhibition Properties of 5-Amino 1,3,4-Thiadiazole-2-Thiol on the Mild Steel in Hydrochloric Acid Medium: Thermodynamic, Surface and Electrochemical Studies ». Journal of Electroanalytical Chemistry 803 (octobre): 125–34. https://doi.org/10.1016/j.jelechem.2017.09.018.
Paul, P.K., Yadav, M., 2020. Investigation on corrosion inhibition and adsorption mechanism of triazine-thiourea derivatives at mild steel / HCl solution interface: Electrochemical, XPS, DFT and Monte Carlo simulation approach. J. Electroanal. Chem. 877, 114599. https://doi.org/10.1016/j.jelechem.2020.114599
Popoola, L.T., 2019. Progress on pharmaceutical drugs, plant extracts and ionic liquids as corrosion inhibitors. Heliyon 5, e01143. https://doi.org/10.1016/j.heliyon.2019.e01143
Quy Huong, Dinh, Tran Duong, et Pham Cam Nam. 2019. « Effect of the Structure and Temperature on Corrosion Inhibition of Thiourea Derivatives in 1.0 M HCl Solution ». ACS Omega 4 (11): 14478–89. https://doi.org/10.1021/acsomega.9b01599.
Ouakki, M., Galai, M., Rbaa, M., Abousalem, A.S., Lakhrissi, B., Rifi, E.H., Cherkaoui, M. (2019). Quantum chemical and experimental evaluation of the inhibitory action of two imidazole derivatives on mild steel corrosion in sulphuric acid medium. Heliyon, 5(11), e02759. https://doi.org/10.1016/j.heliyon.2019.e02759
Rbaa, M., Galai, M., Benhiba, F., Obot, I.B., Oudda, H., Ebn Touhami, M., Lakhrissi, B., Zarrouk, A., 2019. Synthesis and investigation of quinazoline derivatives based on 8-hydroxyquinoline as corrosion inhibitors for mild steel in acidic environment: experimental and theoretical studies. Ionics 25, 3473–3491. https://doi.org/10.1007/s11581-018-2817-7.
Robinson, J. S. 1979. « Corrosion inhibitors 1979: recent developments ».
Stern, M., Geaby, A.L., 1957. Electrochemical Polarization. J. Electrochem. Soc. 104, 56. https://doi.org/10.1149/1.2428496.
Tarfaoui, K., Brhadda, N., Ouakki, M., Galai, M., Ech-chihbi, E., Atfaoui, K., Khattabi, M., Nehiri, M., Lachhab, R., Ebn Touhami, M., Ouhssine, M., 2021. Natural Elettaria cardamomum Essential Oil as a Sustainable and a Green Corrosion Inhibitor for Mild Steel in 1.0 M HCl Solution: Electrochemical and Computational Methods. J. Bio- Tribo-Corros. 7, 131. https://doi.org/10.1007/s40735-021-00567-8.
Trachli, B, M Keddam, H Takenouti, et A Srhiri. 2002. « Protective Effect of Electropolymerized 3-Amino 1,2,4-Triazole towards Corrosion of Copper in 0.5 M NaCl ». Corrosion Science 44 (5): 997–1008. https://doi.org/10.1016/S0010-938X(01)00124-X.
Verma, C., Saji, V.S., Quraishi, M.A., Ebenso, E.E., 2020. Pyrazole derivatives as environmental benign acid corrosion inhibitors for mild steel: Experimental and computational studies. J. Mol. Liq. 298, 111943. https://doi.org/10.1016/j.molliq.2019.111943.
Umoren, Saviour, Ying Li, et Fiona Wang. 2010. « Synergistic effect of iodide ion and polyacrylic acid on corrosion inhibition of iron in H2SO4 investigated by electrochemical techniques ». Corrosion Science 52 (juillet): 2422–29. https://doi.org/10.1016/j.corsci.2010.03.021.
Yadav, M., Kumar, S., Sinha, R.R., Bahadur, I., Ebenso, E.E., 2015. New pyrimidine derivatives as efficient organic inhibitors on mild steel corrosion in acidic medium: Electrochemical, SEM, EDX, AFM and DFT studies. J. Mol. Liq. 211, 135–145. https://doi.org/https://doi.org/10.1016/j.molliq.2015.06.063
Yıldırım, A., et M. Çetin. 2008. « Synthesis and Evaluation of New Long Alkyl Side Chain Acetamide, Isoxazolidine and Isoxazoline Derivatives as Corrosion Inhibitors ». Corrosion Science 50 (1): 155‑65. https://doi.org/10.1016/j.corsci.2007.06.015.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2022 The Author(s), under exclusive license to Springer Nature Switzerland AG
About this paper
Cite this paper
Mzioud, K. et al. (2022). Synergistic Effect from Allium Sativum Essential Oil and Diethylthiourea for Corrosion Inhibition of Carbon Steel in 0.5 M H2SO4 Medium. In: Vaseashta, A., Achour, M.E., Mabrouki, M., Fasquelle, D., Tachafine, A. (eds) Proceedings of the Sixth International Symposium on Dielectric Materials and Applications (ISyDMA’6). Springer, Cham. https://doi.org/10.1007/978-3-031-11397-0_23
Download citation
DOI: https://doi.org/10.1007/978-3-031-11397-0_23
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-031-11396-3
Online ISBN: 978-3-031-11397-0
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)