Abstract
The research provides the key concept for construction of new type of the potentiometric sensor to automate the measurement procedure of the ion species in the industrial waters and environmental samples to serve prospective screening purposes. In this work the possibility of automation of determination of ion species in the industrial waters such as the chloride and nitrate ions concentration is considered with help of combined potentiometric sensors. The design of the measuring equipment supposes its installation into flowing system. Measurement of the ion concentration is implemented by the combined sensors with two ion-selective electrodes used as working and reference electrodes. This work studies the possibility to control the ion-selective electrode calibration and the workability by use of the system of electrogeneration of the required ion in the measured medium. This study shows the possibility of developing a potentiometric sensor that has the advantages of high simplicity, designability, stability of potential and can be easily installed on the automated system to monitor the ion species in the industrial waters. The performance of the proposed sensor, such as stability, the effect of stirring and concrete admixtures was investigated. The potentiometric sensor can be used to monitor chloride and nitrate ions in the industrial waters and wastewaters within the 11–3540 and 6.2–6200 mg/dm3 range. Accuracy of the proposed technique is verified by the added-found method. Recovery errors are within the acceptable range (4–22%) for the screening purposes. The results are in good agreement with the classic ionometry method. The proposed potentiometric system is to be constructed taking into account the effect of temperature, the shift of the potential, the effect of stirring and the presence of interfering substances.
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Vtorushina, A., Larionova, E., Romanenko, E., Romanenko, S. (2023). Potentiometric Sensor for the Ion Speciation in the Industrial Waters. In: Lysenko, E., Rogachev, A., Starý, O. (eds) Recent Developments in the Field of Non-Destructive Testing, Safety and Materials Science. ICMTNT 2021. Studies in Systems, Decision and Control, vol 433. Springer, Cham. https://doi.org/10.1007/978-3-030-99060-2_5
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