Skip to main content

Preparation and Characterization of Amine Modified Activated Carbon from Corncobs for Carbon Dioxide Capture

  • Conference paper
  • First Online:
Advances in Chemical, Bio and Environmental Engineering (CHEMBIOEN 2021)

Part of the book series: Environmental Science and Engineering ((ESE))

  • 1018 Accesses

Abstract

Carbon dioxide adsorption was carried out using a specific bio-adsorbent. The bio-adsorbent was prepared from corncobs. In the present study attempt was made to prepare, characterize and to develop low cost adsorbent. The structure and physical characteristics were outlined and described in details after defining the activated carbon. Moreover, surface modification of the prepared activated carbon was carried out using Methyl diethanol amine (MDEA) solution with impregnation ratio 0.4. Different Characterizations technique like Proximate Analysis, Ultimate Analysis, BET, and Scanning Electron Microscope (SEM) of adsorbents were studied extensively in order to predict the composition, surface area, porosity and surface topography. The experimental work is focused on removal of CO2 gas using prepared activated carbon and amine impregnated activated carbon. From the experiment it has been seen that the adsorption capacity of Methyl diethanol amine impregnated activated carbon is much more than simple activated carbon. Thus, the given activated carbon prepared from corncob impregnated with MDEA in a ratio 0.4 can be extensively used for the removal of CO2 from industrial flue gases.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 139.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 179.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 179.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  • Ben-Mansour R, Habib MA, Bamidele OE, Basha M, Qasem NAA, Peedikakkal A et al (2016) Carbon capture by physical adsorption: materials, experimental investigations and numerical modeling and simulations—a review. Appl Energy 161:225–255

    Google Scholar 

  • Das D, Meikap BC (2018) Comparison of adsorption capacity of mono-ethanolamine and di-ethanolamine impregnated activated carbon in a multi-staged fluidized bed reactor for carbon-dioxide capture. Fuel 224:47–56

    Article  CAS  Google Scholar 

  • Das D, Meikap BC (2019a) Removal of CO2 in a multistage fluidized bed reactor by monoethanol amine impregnated activated carbon. Miner Process Extr Metall Rev 1–7

    Google Scholar 

  • Das D, Meikap BC (2019b) Removal of CO2 in a multistage fluidized bed reactor by amine impregnated activated carbon: optimization using response surface methodology. Int J Coal Sci Technol 6(3):445–458

    Google Scholar 

  • Das D, Samal DP, Meikap BC (2015) Preparation of activated carbon from green coconut shell and its characterization. J Chem Eng Process Technol 6(5):1–7

    Article  Google Scholar 

  • Das D, Samal DP, Meikap BC (2016) Removal of CO2 in a multistage fluidized bed reactor by diethanol amine impregnated activated carbon. J Environ Sci Health Part A 51(9):769–775

    Article  CAS  Google Scholar 

  • Fang M, Yi N, Di W, Wang T, Wang Q (2020) Emission and control of flue gas pollutants in CO2 chemical absorption system—a review. Int J Greenh Gas Control 93:102904

    Google Scholar 

  • Gholidoust A, Atkinson JD, Hashisho Z (2017) Enhancing CO2 adsorption via amine-impregnated activated carbon from oil sands coke. Energy Fuel 31(2):1756–1763

    Google Scholar 

  • Hussain A (2012) Single stage membrane process for CO2 capture from flue gas by a facilitated transport membrane. Sep Sci Technol 47(13):1857–1865

    Article  CAS  Google Scholar 

  • Lee YC, Lee SM, Hong WG, Huh YS, Park SY, Lee SC, Kimba HJ (2015) Carbon dioxide capture on primary amine groups entrapped in activated carbon at low temperatures. J Ind Eng Chem 23:16–20

    Article  CAS  Google Scholar 

  • Parshetti GK, Chowdhury S, Balasubramanian R (2015) Biomass derived low-cost microporous adsorbents for efficient CO2 capture. Fuel 148:246–254

    Article  CAS  Google Scholar 

  • Peters GP, Andrew RM, Canadell JG, Friedlingstein P, Jackson RB, Korsbakken JI et al (2020) Carbon dioxide emissions continue to grow amidst slowly emerging climate policies. Nat Clim Change 10(1):3–6

    Google Scholar 

  • Ping T, Dong Y, Shen S (2020) Energy-efficient CO2 capture using nonaqueous absorbents of secondary alkanolamines with a 2-butoxyethanol cosolvent. Sustain Chem Eng 8(49):18071–18082

    Article  CAS  Google Scholar 

  • Resnik KP, Yeh JT, Pennline HW (2004) Aqua ammonia process for simultaneous removal of CO2, SO2 and NOx. Int J Environ Technol Manag 4(1):89–104

    Google Scholar 

  • Song C, Liu Q, Ji N, Deng S, Zhao J, Li Y et al (2018) Alternative pathways for efficient CO2 capture by hybrid processes—a review. Renew Sustain Energy Rev 82:215–231

    Google Scholar 

  • Yeh JT, Resnik KP, Rygle K, Pennline HW (2005) Semi-batch absorption and regeneration studies for CO2 capture by aqueous ammonia. Fuel Process Technol 86(14–15):1533–1546

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Dipa Das .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2022 The Author(s), under exclusive license to Springer Nature Switzerland AG

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Das, D., Swain, L. (2022). Preparation and Characterization of Amine Modified Activated Carbon from Corncobs for Carbon Dioxide Capture. In: Ratan, J.K., Sahu, D., Pandhare, N.N., Bhavanam, A. (eds) Advances in Chemical, Bio and Environmental Engineering. CHEMBIOEN 2021. Environmental Science and Engineering. Springer, Cham. https://doi.org/10.1007/978-3-030-96554-9_16

Download citation

Publish with us

Policies and ethics