Abstract
Carbon dioxide adsorption was carried out using a specific bio-adsorbent. The bio-adsorbent was prepared from corncobs. In the present study attempt was made to prepare, characterize and to develop low cost adsorbent. The structure and physical characteristics were outlined and described in details after defining the activated carbon. Moreover, surface modification of the prepared activated carbon was carried out using Methyl diethanol amine (MDEA) solution with impregnation ratio 0.4. Different Characterizations technique like Proximate Analysis, Ultimate Analysis, BET, and Scanning Electron Microscope (SEM) of adsorbents were studied extensively in order to predict the composition, surface area, porosity and surface topography. The experimental work is focused on removal of CO2 gas using prepared activated carbon and amine impregnated activated carbon. From the experiment it has been seen that the adsorption capacity of Methyl diethanol amine impregnated activated carbon is much more than simple activated carbon. Thus, the given activated carbon prepared from corncob impregnated with MDEA in a ratio 0.4 can be extensively used for the removal of CO2 from industrial flue gases.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Ben-Mansour R, Habib MA, Bamidele OE, Basha M, Qasem NAA, Peedikakkal A et al (2016) Carbon capture by physical adsorption: materials, experimental investigations and numerical modeling and simulations—a review. Appl Energy 161:225–255
Das D, Meikap BC (2018) Comparison of adsorption capacity of mono-ethanolamine and di-ethanolamine impregnated activated carbon in a multi-staged fluidized bed reactor for carbon-dioxide capture. Fuel 224:47–56
Das D, Meikap BC (2019a) Removal of CO2 in a multistage fluidized bed reactor by monoethanol amine impregnated activated carbon. Miner Process Extr Metall Rev 1–7
Das D, Meikap BC (2019b) Removal of CO2 in a multistage fluidized bed reactor by amine impregnated activated carbon: optimization using response surface methodology. Int J Coal Sci Technol 6(3):445–458
Das D, Samal DP, Meikap BC (2015) Preparation of activated carbon from green coconut shell and its characterization. J Chem Eng Process Technol 6(5):1–7
Das D, Samal DP, Meikap BC (2016) Removal of CO2 in a multistage fluidized bed reactor by diethanol amine impregnated activated carbon. J Environ Sci Health Part A 51(9):769–775
Fang M, Yi N, Di W, Wang T, Wang Q (2020) Emission and control of flue gas pollutants in CO2 chemical absorption system—a review. Int J Greenh Gas Control 93:102904
Gholidoust A, Atkinson JD, Hashisho Z (2017) Enhancing CO2 adsorption via amine-impregnated activated carbon from oil sands coke. Energy Fuel 31(2):1756–1763
Hussain A (2012) Single stage membrane process for CO2 capture from flue gas by a facilitated transport membrane. Sep Sci Technol 47(13):1857–1865
Lee YC, Lee SM, Hong WG, Huh YS, Park SY, Lee SC, Kimba HJ (2015) Carbon dioxide capture on primary amine groups entrapped in activated carbon at low temperatures. J Ind Eng Chem 23:16–20
Parshetti GK, Chowdhury S, Balasubramanian R (2015) Biomass derived low-cost microporous adsorbents for efficient CO2 capture. Fuel 148:246–254
Peters GP, Andrew RM, Canadell JG, Friedlingstein P, Jackson RB, Korsbakken JI et al (2020) Carbon dioxide emissions continue to grow amidst slowly emerging climate policies. Nat Clim Change 10(1):3–6
Ping T, Dong Y, Shen S (2020) Energy-efficient CO2 capture using nonaqueous absorbents of secondary alkanolamines with a 2-butoxyethanol cosolvent. Sustain Chem Eng 8(49):18071–18082
Resnik KP, Yeh JT, Pennline HW (2004) Aqua ammonia process for simultaneous removal of CO2, SO2 and NOx. Int J Environ Technol Manag 4(1):89–104
Song C, Liu Q, Ji N, Deng S, Zhao J, Li Y et al (2018) Alternative pathways for efficient CO2 capture by hybrid processes—a review. Renew Sustain Energy Rev 82:215–231
Yeh JT, Resnik KP, Rygle K, Pennline HW (2005) Semi-batch absorption and regeneration studies for CO2 capture by aqueous ammonia. Fuel Process Technol 86(14–15):1533–1546
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2022 The Author(s), under exclusive license to Springer Nature Switzerland AG
About this paper
Cite this paper
Das, D., Swain, L. (2022). Preparation and Characterization of Amine Modified Activated Carbon from Corncobs for Carbon Dioxide Capture. In: Ratan, J.K., Sahu, D., Pandhare, N.N., Bhavanam, A. (eds) Advances in Chemical, Bio and Environmental Engineering. CHEMBIOEN 2021. Environmental Science and Engineering. Springer, Cham. https://doi.org/10.1007/978-3-030-96554-9_16
Download citation
DOI: https://doi.org/10.1007/978-3-030-96554-9_16
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-96553-2
Online ISBN: 978-3-030-96554-9
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)