Skip to main content

Significance of Intermetallic Compound (IMC) Layer to the Reliability of a Solder Joint, Methods of IMC Layer Thickness Measurements

  • Chapter
  • First Online:
Recent Progress in Lead-Free Solder Technology

Part of the book series: Topics in Mining, Metallurgy and Materials Engineering ((TMMME))

Abstract

Intermetallic compound (IMC) growth is being analyzed due to its significant effect on solder joint reliability. It appears that from various works conducted whereby the excessive growth of IMC could lead to solder joint failure. Thus, many attempts have been made to determine the actual IMC thickness. Average values of IMC thickness are always used to represent the IMC layer. However, precise, and true representation of the IMC layer growth in the actual 3D phenomenon from 2D images remains unclear. Leading to this, the stereometry should be considered in determining the actual IMC thickness layer. The accuracy of the IMC layer thickness measurement is important as the IMC layer thickness values will be used for the next analysis such as for growth rate and activation energy calculation. Type of measurement to represent the actual IMC layer thickness based on 2D observation and nature of the IMC structure which contains hillocks and valleys is suggested.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 149.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 199.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 199.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  • Ab Rahim, R. A. A., Zulkifli, M. N., Jalar, A., Afdzaluddin, A. M., & Shyong, K. S. (2020). Effect of isothermal aging and copper substrate roughness on the SAC305 solder joint intermetallic layer growth of high temperature storage (HTS) [Kesan penuaan isoterma dan kekasaran permukaan substrat kuprum ke atas pertumbuhan lapisan antara logam sambungan pateri SAC305 pada penyimpanan suhu tinggi (HTS)]. Sains Malaysiana, 49(12), 3045–3054.

    Article  Google Scholar 

  • Alam, M. O., & Chan, Y. (2005). Solid-state growth kinetics of Ni3Sn4 at the Sn–3.5Ag solder∕Ni interface. Internatinal Journal of Applied Physics, 98, 123527.

    Google Scholar 

  • ASTM E-11. (2017). Standard guide for preparation of metallographic specimens. ASTM International

    Google Scholar 

  • Bakar, M. A., Jalar, A., Abdullah, M. Z., Ibrahim, N. S., & Ambak, M. A. (2018a). Controlling of intermetallic compound solder interconnection-printed circuit board using nickel coating [Pengawalan pertumbuhan sebatian antara logam sambungan pateri-papan litar bercetak menggunakan salutan nikel]. Sains Malaysiana, 47(9), 2157–2162.

    Article  Google Scholar 

  • Bakar, M. A., Jalar, A., & Ismail, R. (2018b). Effect of different surface finishes on micromechanical properties of sac 0307 solder joint using nanoindentation approach [Kesan kemasan permukaan berbeza terhadap sifat mikromekanik sambungan pateri sac 0307 menggunakan pendekatan pelekukan nano]. Sains Malaysiana, 47(5), 1011–1016.

    Google Scholar 

  • Bakar, M. A., Jalar, A., & Ismail, R. (2018c). Reassessment of stereometric quantitative measurements on the growth of intermetallic compound for solder connections [Penilaian semula pengukuran kuantitatif stereometri terhadap pertumbuhan sebatian antara logam bagi sambungan pateri]. Sains Malaysiana, 47(4), 805–810.

    Article  Google Scholar 

  • Chang, T. H., & Wu, H. F. (2011). Effects of Ce addition on the microstructure and mechanical properties of Sn-58Bi solder joints. Journal of Electronic Materials, 40, 71–77.

    Article  Google Scholar 

  • Che Ani, F., Jalar, A., Saad, A. A., Khor, C. Y., Abas, M. A., Bachok, Z., & Othman, N. K. (2019). Characterization of SAC—x NiO nano-reinforced lead-free solder joint in an ultra-fine package assembly. Soldering and Surface Mount Technology, 31(2), 109–124.

    Article  Google Scholar 

  • Che Ani, F., Jalar, A., Saad, A. A., Khor, C. Y., Ismail, R., Abas, M. A., Bachok, Z., & Othman, N. K. (2018a). The influence of Fe2O3 nano-reinforced SAC lead-free solder in the ultra-fine electronics assembly. The International Journal of Advanced Manufacturing Technology, 96, 717–733.

    Article  Google Scholar 

  • Che Ani, F., Jalar, A., Saad, A. A., Khor, C. Y., Ismail, R., Abas, M. A., Bachok, Z., & Othman, N. K. (2018b). SAC–xTiO2 nano-reinforced lead-free solder joint characterizations in ultra-fine package assembly. Soldering Surface Mount Technology, 30(1), 1–13.

    Google Scholar 

  • Deillon, L., Hessler, T., Wyser, A. H., & Rappaz, M. (2014). Growth of intermetallic compounds in the Au–In system: Experimental study and 1-D modelling. Acta Materialia, 79, 258–267.

    Google Scholar 

  • Dele-Afolabi, T. T., Azmah, M. A., Norkhairunnisa, M., Yusoff, H. M., & Suraya, M. T. (2015). Investigating the effect of isothermal aging on the morphology and shear strength of Sn-5Sb solder reinforced with carbon nanotubes. Journal of Alloys and Compounds, 649, 368–374.

    Google Scholar 

  • Flanders, D. R., Jacobs, E. G., & Pinizzotto, R. F. (1997). Activation energies of intermetallic growth of Sn–Ag eutectic solder on copper substrates. Journal of Electronic Materials, 26, 883–887.

    Article  CAS  Google Scholar 

  • Hang, C. J., Wang, C. Q., Mayer, M., Tian, Y. H., Zhou, Y., & Wang, H. H. (2008). Growth behavior of Cu/Al intermetallic compounds and cracks in copper ball bonds during isothermal aging. Microelectronics Reliability, 48(3), 416–424.

    Article  CAS  Google Scholar 

  • Ismail, N., Jalar, A., Abu Bakar, M., & Ismail, R. (2018). Kesan Penambahan Tiubnano Karbon terhadap Pertumbuhan Lapisan Sebatian antara Logam Sistem Pateri Sn–Ag–Cu/Cu akibat Penuaan Terma (Effect of carbon nanotube addition on the growth of intermetallic layer of Sn-Ag-Cu solder system under thermal aging). Sains Malaysiana, 47(07), 1585–1590.

    Article  CAS  Google Scholar 

  • Ismail, N., Jalar, A., Abu Bakar, M., Safee, N. S., Wan Yusoff, W. Y., & Ismail, A. (2021). Microstructural evolution and micromechanical properties of SAC305/CNT/CU solder joint under blast wave condition. Soldering and Surface Mount Technology, 33(1), 47–56.

    Article  Google Scholar 

  • Ismail, N., Jalar, A., Bakar, M. A., Ismail, R., Safee, N. S., Ismail, A. G., & Ibrahim, N. S. (2019). Effect of isothermal aging on microhardness properties of Sn-Ag-Cu/CNT/Cu using nanoindentation [Kesan penuaan sesuhu terhadap sifat mikro kekerasan pempaterian Sn-Ag-Cu/cnt/cu menggunakan pelekukan nano]. Sains Malaysiana, 48(6), 1267–1272.

    Article  CAS  Google Scholar 

  • Jalar, A., Bakar, M. A., Ismail, R., & Daud, A. R. (2016). Statistical aspect on the measuring of intermetallic compound thickness of lead-free solders. Journal of Scientific Research and Development, 3(4), 49–54.

    Google Scholar 

  • Jalar, A., Bakar, M. A., & Ismail, R. (2020). Temperature dependence of elastic-plastic properties of fine-pitch SAC 0307 solder joint using nanoindentation approach. Metallurgical and Materials Transactions a: Physical Metallurgy and Materials Science, 51, 1221–1228.

    Article  CAS  Google Scholar 

  • JESD22-A103D. High temperature storage life. JEDEC Solid State Technology Association

    Google Scholar 

  • JESD22-A104F. Temperature cycling. JEDEC Solid State Technology Association

    Google Scholar 

  • JESD22-A110E. Highly accelerated temperature and humidity stress test (HAST). JEDEC Solid State Technology Association

    Google Scholar 

  • JESD22-B117A. Solder ball shear. JEDEC Solid State Technology Association

    Google Scholar 

  • Johansson, J., Belov, I., Johnson, E., Dudek, R., & Leisner, P. (2014). Investigation on thermal fatigue of SnAgCu, Sn100C, and SnPbAg solder joints in varying temperature environments. Microelectronics Reliability, 54, 2523–2535.

    Article  CAS  Google Scholar 

  • Kammerer, C. C., Behdad, S., Zhou, L., Betancor, F., Gonzalez, M., Boesl, B., & Sohn, Y. H. (2015). Diffusion kinetics, mechanical properties, and crystallographic characterization of intermetallic compounds in the Mg-Zn binary system. Intermetallics, 67, 145–155.

    Google Scholar 

  • Kang, M. S., Kim, D. S., & Shin, Y. E. (2019). Suppression of the growth of intermetallic compound layers with the addition of graphene nano-sheets to an epoxy Sn–Ag–Cu solder on a Cu substrate. Mater, 12(6), 936.

    Article  CAS  Google Scholar 

  • Kotadia, H. R., Mokhtari, O., Clode, M. P., Green, M. A., & Mannan, S. H. (2012). Intermetallic compound growth suppression at high temperature in SAC solders with Zn addition on Cu and Ni-P substrates. Journals of Alloys Compounds, 511(1), 176–188.

    Article  CAS  Google Scholar 

  • Lee, H. T., & Chen, M. H. (2002). Influence of intermetallic compounds on the adhesive strength of solder joints. Materials Science and Engineering A, 333, 24–34.

    Article  Google Scholar 

  • Lee, L. M., & Mohamad, A. A. (2013). Interfacial reaction of Sn–Ag–Cu lead-free solder Alloy on Cu: A Review. Advanced in Materials Science and Engineering, 2013, 1–11.

    Google Scholar 

  • Liu, J. C., Zhang, G., Wang, Z. H., Ma, J. S., & Suganuma, K. (2015). Thermal property, wettability and interfacial characterization of novel Sn–Zn–Bi–In alloys as low-temperature lead-free solders. Materials and Design, 84, 331–339.

    Article  CAS  Google Scholar 

  • Meilunas, M., Primavera, A., Dunford, S. O. (2002). Reliability and failure analysis of lead-free solder joints. In Proceedings, IPC Conference (pp. 2–3).

    Google Scholar 

  • Nishikawa, H., & Iwata, N. (2015). Formation and growth of intermetallic compound layers at the interface during laser soldering using Sn–Ag Cu solder on a Cu Pad. Journal of Materials Processing Technology, 215, 6–11.

    Article  CAS  Google Scholar 

  • Pang, J. H. L., Tan, K. H., Shi, X. Q., & Wang, Z. P. (2001). Microstructure and intermetallic growth effects on shear and fatigue strength of solder joints subjected to thermal cycling aging. Materials Science and Engineering A, 307, 42–50.

    Article  Google Scholar 

  • Sayyadi, R., & Naffakh-Moosavy, H. (2019). The role of intermetallic compounds in controlling the microstructural, physical and mechanical properties of Cu-[Sn-Ag-Cu-Bi]-Cu solder joints. Scientific Reports, 9, 8389.

    Article  Google Scholar 

  • Thompson, P. B., Johnson, R., & Nadimpalli, S. P. V. (2018). Effect of temperature on the fracture behavior of Cu/SAC305/Cu solder joints. Engineering Fracture Mechanics, 199, 730–738.

    Article  Google Scholar 

  • Wang, Y., Zhao, X. C., Liu, Y., Wang, Y., & Li, D. M. (2021). Microstructure, wetting property of Sn–Ag–Cu–Bi–xCe solder and IMC growth at solder/Cu interface during thermal cycling. Rare Metals, 40, 714–719.

    Article  Google Scholar 

  • Yin, L, Zhang Z, Su Z, Zhang H, Zuo C, Yao Z, Wang G, Zhang L, Zhang Y (2021) Interfacial microstructure evolution and properties of Sn-0.3Ag-0.7Cu–xSiC solder joints. Materials Science and Engineering A, 809, 140995

    Google Scholar 

  • Yoon, J. W., Kim, S. W., & Jung, S. B. (2005). Interfacial reaction and mechanical properties of eutectic Sn–0.7Cu/Ni BGA solder joints during isothermal long-term aging. Journal of Alloys Compounds, 391, 82–89.

    Article  CAS  Google Scholar 

  • Zhao, J., Yang, P., Zhu, F., & Cheng G. Q. (2006). The effect of high magnetic field on the growth behavior of Sn–3Ag–0.5Cu/Cu IMC layer. Scripta Materialia, 54(6), 1077–1080.

    Google Scholar 

  • Zhong, Y., Zhao, N., Ma, H. T., Dong, W., & Huang, M. L. (2017). Retardation of thermomigration-induced Cu substrate consumption in Pb-free solder joints by Zn addition. Journal of Alloys and Compounds, 695, 1436–1443.

    Google Scholar 

Download references

Acknowledgements

Authors would like to acknowledge Universiti Kebangsaan Malaysia for financial support (grant number GGPM-2019-056).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. A. Bakar .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2022 The Author(s), under exclusive license to Springer Nature Switzerland AG

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Bakar, M.A., Jalar, A., Atiqah, A., Ismail, N. (2022). Significance of Intermetallic Compound (IMC) Layer to the Reliability of a Solder Joint, Methods of IMC Layer Thickness Measurements. In: Salleh, M.A.A.M., Abdul Aziz, M.S., Jalar, A., Izwan Ramli, M.I. (eds) Recent Progress in Lead-Free Solder Technology. Topics in Mining, Metallurgy and Materials Engineering. Springer, Cham. https://doi.org/10.1007/978-3-030-93441-5_11

Download citation

Publish with us

Policies and ethics