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Monitoring and Geochemical Investigations of Caves in Hungary: Implications for Climatological, Hydrological, and Speleothem Formation Processes

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Cave and Karst Systems of Hungary

Part of the book series: Cave and Karst Systems of the World ((CAKASYWO))

Abstract

Cave monitoring was conducted in the Béke and Baradla caves in the Aggtelek Karst, in the Ajándék-Ariadne cave system in the Pilis Mountain, as well as in the Szemlőhegy and Pálvölgy caves in the Buda Mountain. Climatological data outside of the cave (e.g., temperature, amount of precipitation), within the cave (temperature, humidity, CO2 concentration), as well as the geochemical data of drip water (chemical and isotopic compositions) and carbonates (stable isotope compositions) were compiled in order to constrain the processes that influence the cave air, drip waters, and the precipitated carbonates. The monitoring activities in the Béke and Baradla caves revealed that the speleothems formed in these caves are able to record temperature and hydrological changes, and hence the measured trace element and isotopic compositions together with petrographic characteristics can be used to reconstruct past climate and environmental fluctuations. In addition, the equations that best describe the carbonate-water oxygen isotope fractionation and best reflect the temperature dependence of the isotopic composition of precipitations were identified for paleotemperature reconstruction. The investigations conducted in the Ajándék-Ariadne cave system indicate that the isotope fractionation during carbonate formation in the Legény and Leány caves is kinetically altered. Most promising sites are assumed to be in the inner part of Vacska Cave within this system, where speleothems can be selected for future paleoclimate studies. The monitoring in the caves (Szemlőhegy and Pálvölgy caves) located under urban areas revealed a complex influence of both natural and anthropogenic factors on chemical and isotopic compositions of the drip water.

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References

  • Báldi T (1983) Magyarországi oligocén és alsó-miocén formációk. (Oligocen and lower Miocen Formation in Hungary) Akadémia Kiadó, Budapest, p 293. (in Hungarian)

    Google Scholar 

  • Benkovics L, Török Á, Nádor A (1995) A Ferenc-hegyi vonulat barlangjainak geológiája. (Geology of caves in Ferenc Hill) Karszt- és barlangkutatás 10:193–207. (in Hungarian)

    Google Scholar 

  • Boch R, Spötl C, Frisia S (2011) Origin and palaeoenvironmental significance of lamination in stalagmites from Katerloch Cave, Austria. Sedimentology 58:508–531

    Article  Google Scholar 

  • Borsato A, Johnston VE, Frisia S, Miorandi R, Corradini F (2016) Temperature and altitudinal influence on karst dripwater chemistry: implications for regional-scale palaeoclimate reconstructions from speleothems. Geochim Cosmochim Acta 177:275–297

    Article  Google Scholar 

  • Bottyán E, Gy C, Weidinger T, Haszpra L, Kármán K (2013) Determination of air moisture source region for precipitation in Hungary. Cent Eur Geol 56:273

    Google Scholar 

  • Bottyán E, Czuppon G, Weidinger T, Haszpra L, Kármán K (2017) Moisture source diagnostics and isotope characteristics for precipitation in east Hungary: implications for their relationship. Hydrol Sci J 62(12):2049–2060. https://doi.org/10.1080/02626667.2017.1358450

    Article  Google Scholar 

  • Breitenbach SFM, Lechleitner FA, Meyer H, Diengdoh G, Mattey D, Marwan N (2015) Cave ventilation and rainfall signals in dripwater in a monsoonal setting—a monitoring study from NE India. Chem Geol 402:111–124

    Article  Google Scholar 

  • Cheng H, Spötl C, Breitenbach SFM, Sinha A, Wassenburg JA, Jochum KP, Scholz D, Li X, Yi L, Peng Y, Lv Y, Zhang P, Votintseva A, Loginov V, Ning Y, Kathayat G, Edwards RL (2016) Climate variations of Central Asia on orbital to millennial timescales. Sci Rep 6:36975. https://doi.org/10.1038/srep36975

    Article  Google Scholar 

  • Coplen TB (1996) New guidelines for reporting stable hydrogen, carbon, and oxygen isotope-ratio data. Geochim Cosmochim Acta 60:3359–3360

    Article  Google Scholar 

  • Coplen TB (2007) Calibration of the calcite-water oxygen-isotope geothermometer at Devils Hole, Nevada, a natural laboratory. Geochim Cosmochim Acta 71:3948–3957

    Article  Google Scholar 

  • Craig H (1961) Isotopic variations in meteoric waters. Science 133:1702–1703

    Article  Google Scholar 

  • Czuppon G, Bottyán E, Haszpra L, Weidinger T, Kármán K (2017) Significance of the air moisture source on the stable isotope composition of the precipitation in Hungary. EGU General Assembly, Geophysical Research Abstracts, vol 19: EGU2017-13458

    Google Scholar 

  • Czuppon G, Demény A, Leél-Őssy S, Óvari M, Molnár M, Stieber J, Kármán K, Kiss K, Haszpra L (2018) Cave monitoring in the Béke and Baradla caves (Northeastern Hungary): implications for the conditions for the formation cave carbonates. Int J Speleol 47(1):13–28

    Google Scholar 

  • Czuppon Gy, Demény A, Leél-Őssy Sz, Stieber J, Óvari M, Dobosy P, Berentés Á, Kovács R (2021) Cave monitoring in Hungary: An overview. Cent Eur Geol, https://doi.org/10.1556/24.2021.00109

  • Dansgaard W (1964) Stable isotopes in precipitation. Tellus 16:436–468

    Article  Google Scholar 

  • Demény A, Németh A, Kern Z, Czuppon Gy, Molnár M, Leél-Őssy S, Óvári M, Stieber J (2017) Recently forming stalagmites from the Baradla Cave and their suitability assessment for climate-proxy relationships. Cent Eur Geol 30(1):1–34. https://doi.org/10.1556/24.60.2017.001

  • Demény A, Kern Z, Németh A, Frisia, S, Hatvani IG, Czuppon G, Leél-Őssy S, Molnár M, Óvári M, Surányi G, Gilli A, Wu CC, Shen CC (2019) North Atlantic influences on climate conditions in East-Central Europe in the late Holocene reflected by flowstone compositions. Quat Int 512:99–112

    Google Scholar 

  • Demény A, Rinyu L, Kern Z, Hatvani I, Czuppon G, Surányi G, Leél-Őssy S, Shen C-C, Koltai G (2020a) Paleotemperature reconstructions using speleothem fluid inclusion analyses from Hungary. Chem Geol (revised)

    Google Scholar 

  • Demény A, Rinyu L, Németh P, Czuppon G, Enyedi N, Makk J, Leél-Őssy S, Kesjár D, Kovács I (2020b) Bacterial and abiogenic carbonates formed in caves—no vital effect on clumped isotope compositions. PLoS One (revised)

    Google Scholar 

  • Dorale JA, Liu Z (2009) Limitations of Hendy test criteria in judging the paleoclimatic suitability of speleothems and the need for replication. J Cave Karst Stud 71:73–80

    Google Scholar 

  • Eaton AD, Clesceri LS, Rice EW, Greenberg AE (eds) (2005) Standard methods for the examination of water and wastewater, 21st edn. APHA, AWWA, WEF, Washington, DC USA

    Google Scholar 

  • Fairchild IJ, Borsato A, Tooth AF, Frisia S, Hawkesworth CJ, Huang YM, McDermott F, Spiro B (2000) Controls on trace element (Sr–Mg) compositions of carbonate cave waters: implications for speleothem climatic records. Chem Geol 166:255–269

    Article  Google Scholar 

  • Fairchild IJ, Smith CL, Baker A, Fuller L, Spötl C, Mattey D, McDermott F, EIMF (2006) Modification and preservation of environmental signals in speleothems. Earth Sci Rev 75:105–153

    Article  Google Scholar 

  • Fairchild IJ, Baker A (2012) Speleothem science. Wiley-Blackwell

    Google Scholar 

  • Fehér K, Kovács J, Márkus L, Borbás E, Tanos P, Hatvani IG (2016) Analysis of drip water in an urban karst cave beneath the Hungarian Capital (Budapest). Acta Carsologica 45(3):213–231

    Article  Google Scholar 

  • Fehér K, Borbás E (2014) Long-term monitoring of cave drip water at two sampling locations in Pálvölgy Cave. Karsztfejlődés XIX:51–62

    Google Scholar 

  • Fehér K, Kiss K, Kovács J, Kiss A (2009) Beszivárgás vizsgálatok a rózsadombi termálkarszton. (Investigations of infiltrating waters in Rózsadomb thermalkarst) Karsztfejlődés XVI:203–221. (in Hungarian)

    Google Scholar 

  • Fehér K (2011) Újabb adatok a budai termálkarszt beszivárgó vizeinek minőségéről. (New data on the quality of the infiltrating waters in Buda thermalkarst) Karsztfejlődés XIV:45–55. (in Hungarian)

    Google Scholar 

  • Friedman I, O’Neil JR (1977) Compilation of stable isotope fractionation factors of geochemical interest. In: Fleisher M, Chap KK (eds) Data of geochemistry, 6th edn. US Geological Survey Professional Paper, vol 440, pp 1–12

    Google Scholar 

  • Győri O, Poros Zs, Mindszenty A, Molnár F, Fodor L, Szabó R (2011) Budai-hegységi paleogén karbonátos kőzetek diagenezistörténete. (Diagenetic history of the Palaeogene carbonates, Buda Hills, Hungary) Földtani Közlöny 141(1):341–361. (in Hungarian)

    Google Scholar 

  • Hendy CH (1971) The isotopic geochemistry of speleothems 1. The calculation of the effects of the different modes of formation on the isotopic composition of speleothems and their applicability as palaeoclimatic indicators. Geochim Cosmochim Acta 35:801–824

    Article  Google Scholar 

  • Hips K (2003) Gutenstein formation in the Aggtelek facies of the Silica nappe. Földtani Közlöny 133(4):445–468

    Google Scholar 

  • Holloway JM, Dahlgren RA (2002) Nitrogen in rock: occurrences and biogeochemical implications. Glob Biogeochem Cycles 16(4):1118. https://doi.org/10.1029/2002GB001862

    Article  Google Scholar 

  • Kennett DJ, Breitenbach SFM, Aquino VV, Asmerom Y, Awe J, Baldini JUL, Bartlein P, Culleton NJ, Ebert C, Jazwa C, Macri MJ, Marwan N, Polyak V, Prufer KM, Ridley HR, Sodemann H, Winterhalder B, Haug GH (2012) Development and disintegration of maya political systems in response to climate change. Science 338:788–791

    Article  Google Scholar 

  • Kern Z, Demény A, Persoiu A, Hatvani IG (2019) Speleothem records from the Eastern part of Europe and Turkey—discussion on stable oxygen and carbon isotopes. Quaternary 2:31

    Article  Google Scholar 

  • Kim ST, O’Neil JR (1997) Equilibrium and nonequilibrium oxygen isotope effects in synthetic carbonates. Geochim Cosmochim Acta 61:3461–3475

    Article  Google Scholar 

  • Lachniet MS (2009) Climatic and environmental controls on speleothem oxygen isotope values. Quat Sci Rev 28:412–432

    Article  Google Scholar 

  • Mangini A, Spötl C, Verdes P (2005) Reconstruction of temperature in the Central Alps during the past 2000 yr from a δ18O stalagmite record. Earth Planet Sci Lett 234:741–751

    Article  Google Scholar 

  • Mattey D, Lowry D, Duffet J, Fisher R, Hodge E, Frisia S (2008) A 53 year seasonally resolved oxygen and carbon isotope record from a modern Gibraltar speleothem: reconstructed drip water and relationship to local precipitation. Earth Planet Sci Lett 269:80–95

    Article  Google Scholar 

  • McGillen MR, Fairchild IJ (2005) An experimental study of incongruent dissolution of CaCO3 under analogue glacial conditions. J Glaciol 51(174):383–390

    Article  Google Scholar 

  • Mingram B, Hoth P, Lüders V, Harlov D (2005) The significance of fixed ammonium in Palaeozoic sediments for the generation of nitrogen-rich natural gases in the North German Basin. Int J Earth Sci 94:1010–1022

    Article  Google Scholar 

  • Riechelmann DFC, Schröder-Ritzrau A, Scholz D, Fohlmeister J, Spötl C, Richter DK, Mangini A (2011) Monitoring Bunker Cave (NW Germany): a prerequisite to interpret geochemical proxy data of speleothems from this site. J Hydrol 409:682–695

    Article  Google Scholar 

  • Riechelmann DFC, Deininger M, Scholz D, Riechelmann S, Schröder-Ritzrau A, Spötl C, Richter DK, Mangini A, Immenhauser A (2013) Disequilibrium carbon and oxygen isotope fractionation in recent cave calcite: comparison of cave precipitates and model data. Geochim Cosmochim Acta 103:232–244

    Article  Google Scholar 

  • Rozanski K, Araguás-Araguás L, Gonfiantini R (1993) Isotopic patterns in modern global precipitation, in Climate Change. In: Swart PK, Lohmann KC, McKenzie J, Savin S (eds) Continental isotopic records, geophysical monograph series 78:1–36. American Geophysical Union, Washington D.C.

    Google Scholar 

  • Sebastian FM, Breitenbach Jess F, Adkins H, Meyer N, Marwan KK, Kumar GH, Haug (2010) Strong influence of water vapor source dynamics on stable isotopes in precipitation observed in Southern Meghalaya NE India. Earth and Planetary Science Letters 292(1–2):212–220. https://doi.org/10.1016/j.epsl.2010.01.038

    Article  Google Scholar 

  • Sherwin CM, Baldini JUL (2011) Cave air and hydrological controls on prior calcite precipitation and stalagmite growth rates: implications for palaeoclimate reconstructions using speleothems. Geochim Cosmochim Acta 75:3915–3929. https://doi.org/10.1016/j.gca.2011.04.020

    Article  Google Scholar 

  • Simonsson M, Hillier S, Öborn I (2009) Changes in clay minerals and potassium fixation capacity as a result of release and fixation of potassium in long-term field experiments. Geoderma 151:109–120

    Article  Google Scholar 

  • Spötl C, Vennemann TW (2003) Continuous-flow isotope ratio mass spectrometric analysis of carbonate minerals. Rapid Commun Mass Spectrom 19(9):1004–1006

    Article  Google Scholar 

  • Spötl C, Fairchild I, Tooth AF (2005) Cave air control on dripwater geochemistry, Obir Caves (Austria): implications for speleothem deposition in dynamically ventilated caves. Geochim Cosmochim Acta 69(10):2451–2468

    Article  Google Scholar 

  • Szalai S, Auer I, Hiebl J, Milkovich J, Radim T, Stepanek P, Zahradnicek P, Bihari Z, Lakatos M, Szentimrey T, Limanowka D, Kilar P, Cheval S, Deak Gy, Mihic D, Antolovic I, Mihajlovic V, Nejedlik P, Stastny P, Mikulova K, Nabyvanets I, Skyryk O, Krakovskaya S, Vogt J, Antofie T. Spinoni J (2013) Climate of the Greater Carpathian region. Final Technical Report. www.carpatclim-eu.org

  • Takácsné Bolner K (2013) Az 1987–1994 közötti időszak csepegővíz-vizsgálatainak tanulságai. (Investigation of drip waters in the period of 1987–1994) In: Mindszenty A (ed) Budapest: földtani értékek és az ember (Budapest: geoheritage and humans - urban geological studies). ELTE Eötvös Kiadó Budapest 234–236. (in Hungarian)

    Google Scholar 

  • Tan L, Cai Y, An Y, Cheng H, Shen CC, Breitenbach SFM, Gao Y, Edwards RL, Zhang H, Du (2015) A Chinese cave links climate change, social impacts, and human adaptation over the last 500 years. Sci Rep 5:12284. https://doi.org/10.1038/srep12284

  • Tremaine DM, Froelich PN (2013) Speleothem trace element signatures: a hydrologic geochemical study of modern cave dripwaters and farmed calcite. Geochim Cosmochim Acta 121:522–545

    Article  Google Scholar 

  • Tremaine DM, Froelich PN, Wang Y (2011) Speleothem calcite farmed in situ: modern calibration of δ18O and δ13C paleoclimate proxies in a continuously-monitored natural cave system. Geochim Cosmochim Acta 75:4929–4950

    Article  Google Scholar 

  • Virág M, Mádl-Szőnyi J (2013) A Szemlő-hegyi-barlang csepegővizeinek vizsgálata a rózsadombi törmeléktakaró beszivárgásmódosító hatásának értékelése céljából. (Investigation of drip waters in Szemlőhegy Cave in order to evaluate the influence of the overburden on the infiltration). In: Mindszenty A (ed) Budapest: földtani értékek és az ember (Budapest: geoheritage and humans—urban geological studies). ELTE Eötvös Kiadó Budapest: 239–243. (in Hungarian)

    Google Scholar 

  • Virág M, Mádl-Szőnyi J, Mindszenty A, Zihné Perényi K, Leél-Őssy Sz, Erőss A, Siklósy Z (2009) Az urbanizáció hatása a budai barlangok csepegő vizeire a Szemlő-hegyi-barlang példáján. (Urban influence on the drip waters of Szemlőhegy Cave). Karsztfejlődés XIV:57–81. (in Hungarian)

    Google Scholar 

  • Wong CI, Banner JL, Musgrove M (2011) Seasonal dripwater Mg/Ca and Sr/Ca variations driven by cave ventilation: implications for and modeling of speleothem paleoclimate records. Geochim Cosmochim Acta 75:3514–3529. https://doi.org/10.1016/j.gca.2011.03.025

    Article  Google Scholar 

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Acknowledgements

The study was financially supported by the National Research, Development and Innovation Office, Hungary (OTKA 101664, OTKA 123871 and PD 121387), the Hungarian Academy of Sciences (NANOMIN project, KEP-8/2018), and the Eötvös Loránd Research Network (KEP-1/2020). We are also thankful for the support and permission to the Aggtelek National Park Directorate and Duna-Ipoly National Park Directorate. The János Bolyai Research Scholarship of the Hungarian Academy of Sciences financially supported György Czuppon’s work. The work was language-edited by Iain Coulthard.

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Authors and Affiliations

  1. Institute for Geological and Geochemical Research, Research Centre for Astronomy and Earth Sciences, Eötvös Loránd Research Network, Budaörsi út 45., Budapest, H-1112, Hungary

    György Czuppon, Attila Demény & Ágnes Berentés

  2. Department of Physical and Applied Geology, Eötvös Loránd University, Pázmány Péter sétány 1/C, Budapest, H-1117, Hungary

    Szabolcs Leél-Őssy

  3. Stieber Environmental Ltd, Nyerges u. 6, H-1181, Budapest, Hungary

    József Stieber

  4. Nuclear Security Department, Centre of Energy Research, Eötvös Loránd Research Network, Konkoly-Thege Miklós út 29-33, Budapest, H-1121, Hungary

    Mihály Óvári

  5. Institute of Aquatic Ecology, Centre for Ecological Research, Eötvös Loránd Research Network, Karolina str. 29., Budapest, H-1113, Hungary

    Péter Dobosy

  6. Duna-Ipoly National Park Directorate, Költő u. 21, Budapest, H-1121, Hungary

    Richard Kovács

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  1. György Czuppon
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Correspondence to György Czuppon .

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  1. SEK, Department of Geography, Eötvös Loránd University, Szombathely, Hungary

    Márton Veress

  2. Department of Physical and Applied Geology, Eötvös Loránd University, Budapest, Hungary

    Szabolcs Leél-Őssy

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Czuppon, G. et al. (2022). Monitoring and Geochemical Investigations of Caves in Hungary: Implications for Climatological, Hydrological, and Speleothem Formation Processes. In: Veress, M., Leél-Őssy, S. (eds) Cave and Karst Systems of Hungary . Cave and Karst Systems of the World. Springer, Cham. https://doi.org/10.1007/978-3-030-92960-2_16

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