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Direct Production of Aluminum Manganese and Silicon Alloys in Aluminum Reduction Cells: A Laboratory Test

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Light Metals 2022

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

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Abstract

Aluminum smelters produce pure aluminum in reduction cells by the Hall-Héroult process but supply a variety of alloys to their customers. The alloys are produced in the cast house, as master alloys containing the desired alloying elements are added to the primary aluminum from the potroom before casting. In this work, the concept of producing silicon- or manganesecontaining master alloys directly in the aluminum reduction cells, by feeding silicon or manganese oxides into the electrolyte, along with the alumina raw material was investigated. The results in this paper are obtained from a laboratory cell, and the current efficiency for the alloy deposition is estimated.

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References

  1. K. Grjotheim and Halvor. Kvande, Introduction to aluminium electrolysis: Understanding the Hall-Herloult process. Dusseldorf: Aluminium-Verlag, 1993.

    Google Scholar 

  2. J. R. Davis, Alloying: Understanding the Basics. ASM International, 2001. [Online]. Available: https://books.google.is/books?id=Sg9fAVdf8WoC.

  3. James D. Kline, William C. T. Yeh, and Ulysses A. Preston, “Method of adding manganese to aluminum,” 3,865,583, Feb. 19, 1974.

    Google Scholar 

  4. William R. King, “Aluminium-Manganese Alloy,” 3951764, Apr. 20, 1976.

    Google Scholar 

  5. J. G. Kaufman, E. L. Rooy, and A. F. Society, Aluminum Alloy Castings: Properties, Processes, and Applications. ASM International, 2004. [Online]. Available: https://books.google.is/books?id=JM0u1vwrS5UC.

  6. D. R. Askeland, P. P. Fulay, and W. J. Wright, The Science and Engineering of Materials. Cengage Learning, 2010. [Online]. Available: https://books.google.is/books?id=wUYIAAAAQBAJ.

  7. D. Elwell and G. M. Rao, “Electrolytic production of silicon,” J. Appl. Electrochem., vol. 18, no. 1, pp. 15–22, Jan. 1988, doi: https://doi.org/10.1007/BF01016199.

  8. K. Grjotheim, and K. Matiasovsky, “Impurities in the aluminium electrolyte,” Aluminium, vol. 59, no. 9, pp. 687–693, 1983.

    Google Scholar 

  9. G. M. Haarberg and P. Cui, “Mass Transfer Reactions Near the Cathode During Aluminium Electrolysis,” in Light Metals 2014, J. Grandfield, Ed. Cham: Springer International Publishing, 2016, pp. 749–752. doi: https://doi.org/10.1007/978-3-319-48144-9_126.

  10. R. Boen and J. Bouteillon, “The electrodeposition of silicon in fluoride melts,” J. Appl. Electrochem., vol. 13, no. 3, pp. 277–288, May 1983, doi: https://doi.org/10.1007/BF00941599.

  11. O. Awayssa, G. M. Haarberg, R. Meirbekova, and G. Saevarsdottir, “Electrochemical production of Al–Mn alloys during the electrodeposition of aluminium in a laboratory cell,” Electrochem. Commun., vol. 125, p. 106985, Apr. 2021, doi: https://doi.org/10.1016/j.elecom.2021.106985.

  12. O. Awayssa, G. Saevarsdottir, R. Meirbekova, and G. M. Haarberg, “Electrochemical Production of Al–Si Alloys in Cryolitic Melts in a Laboratory Cell,” J. Electrochem. Soc., vol. 168, no. 4, p. 046506, Apr. 2021, doi: https://doi.org/10.1149/1945-7111/abf40e.

  13. P. A. Solli, T. Eggen, S. Rolseth, E. Skybakmoen, and Å. Sterten, “Design and performance of a laboratory cell for determination of current efficiency in the electrowinning of aluminium,” J. Appl. Electrochem., vol. 26, no. 10, pp. 1019–1025, Oct. 1996, doi: https://doi.org/10.1007/BF00242196.

  14. A. Solheim, S. Rolseth, E. Skybakmoen, L. Støen, Å. Sterten, and T. Støre, “Liquidus temperatures for primary crystallization of cryolite in molten salt systems of interest for aluminum electrolysis,” Metall. Mater. Trans. B, vol. 27, no. 5, p. 739, Oct. 1996, doi: https://doi.org/10.1007/BF02915602.

  15. P. Fellner, G. M. Haarberg, J. Hives, H. Kvande, A. Sterten, and J. Thonstad, Aluminium Electrolysis: Fundamentals of the Hall-Héroult Process. Beuth Verlag GmbH, 2011. [Online]. Available: https://books.google.is/books?id=7MW1pwAACAAJ.

  16. O. Awayssa, G. Saevarsdottir, R. Meirbekova, and G. M. Haarberg, “Electrodeposition of aluminium-titanium alloys from molten fluoride-oxide electrolytes,” Electrochem. Commun., vol. 123, p. 106919, Feb. 2021, doi: https://doi.org/10.1016/j.elecom.2021.106919.

  17. Weill, D.F. and Fyfe, W.J, J Electrochem Soc, vol. III, no. 582, 1964.

    Google Scholar 

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Acknowledgements

The financial support from the Norwegian University of Science and Technology (NTNU) is greatly acknowledged, as is the Icelandic Technology Development Fund.

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Correspondence to Gudrun Saevarsdottir .

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Saevarsdottir, G., Awayssa, O., Meirbekova, R., Haarberg, G.M. (2022). Direct Production of Aluminum Manganese and Silicon Alloys in Aluminum Reduction Cells: A Laboratory Test. In: Eskin, D. (eds) Light Metals 2022. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-92529-1_54

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