Skip to main content

Nanostructured Graphene Thin Films: A Brief Review of Their Fabrication Techniques and Corrosion Protective Performance

  • Conference paper
  • First Online:
TMS 2022 151st Annual Meeting & Exhibition Supplemental Proceedings

Abstract

Graphene oxide has attracted so much attention over the last few years owing to its astonishing features and has proven to have a major contribution to the anticorrosive coating industry. A great deal of this attention is motivated by the necessity to realize additional functionalities, to boost the anti-corrosion performance of the graphene oxides, and to eventually lengthen the service life of metallic structures. This review covers the properties, fabrication techniques, corrosion protective performance, realistic problems, and modification of graphene corrosion protective films.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 229.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 299.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 299.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. He J, Schoenung JM (2002) Nanostructured coatings. Mater Sci Eng A 336:274–319

    Article  Google Scholar 

  2. Santos J, Moschetta M, Rodrigues J, Alpuim P, Capasso A (2021) Interactions between 2D materials and living matter: a review on graphene and hexagonal boron nitride coatings. Front Bioeng Biotechnol 9:612669

    Google Scholar 

  3. Ferhan AR, Ma GR, Jackman JA, Sut TN, Park JH, Cho NJ (2017) Probing the interaction of dielectric nanoparticles with supported lipid membrane coatings on nanoplasmonic arrays. Sensors (Basel) 17(7):1484

    Google Scholar 

  4. Ifijen HI, Ikhuoria EU (2020) A simple technique for the fabrication of colour tunable P(StBA-AA) colloidal crystal microdots on ink-jet paper. Heliyon 6:e04196

    Google Scholar 

  5. Ifijen IH, Odi HD, Maliki M, Omorogbe SO, Aigbodion AI, Ikhuoria EU (2020) Correlative studies on the properties of rubber seed and soybean oil based-alkyd resins and their blends. J Coating Techn Res 18:459–467

    Article  Google Scholar 

  6. Ifijen IH, Ikhuoria EU, Omorogbe SO, Aigbodion AI (2019) Ordered colloidal crystals fabrication and studies on the properties of poly (Styrene–Butyl Acrylate–Acrylic Acid) and polystyrene latexes. In: Srivatsan T, Gupta M (eds) Nanocomposites VI: nanoscience and nanotechnology in advanced composites. The minerals, metals & materials series. Springer, Cham, pp 155–164

    Google Scholar 

  7. Ifijen IH, Maliki M, Ovonramwen OB, Aigbodion AI, Ikhuoria EU (2019) Brilliant coloured monochromatic photonic crystals films generation from poly(Styrene-Butyl Acrylate-Acrylic Acid) latex. J Appl Sci Environ Mgt 23(9):1661–1664

    CAS  Google Scholar 

  8. Ifijen IH, Ikhuoria EU (2019) Generation of highly ordered 3D vivid monochromatic coloured photonic crystal films using evaporative induced technique. Tanz J Sci 45(3):439–449

    Google Scholar 

  9. Ifijen IH, Omorogbe SO, Maliki M, Odiachi IJ, Aigbodion AI, Ikhuoria EU (2020) Stabilizing capability of gum Arabic on the synthesis of poly (Styrene-Methylmethacrylate-Acrylic Acid) latex for the generation of colloidal crystal films. Tanz J Sci 46(2):345–435

    Google Scholar 

  10. Ifijen IH, Ikhuoria EU (2020) Monodisperse polystyrene microspheres: studies on the effects of reaction parameters on particle diameter. Tanz J Sci 46(1):19–30

    Google Scholar 

  11. Jaya Verma AS, Sahney KR, Bhattacharya A (2020) Super protective anti-bacterial coating development with silica–titania nano core–shells. Nanoscale Adv 2:4093–4105

    Article  Google Scholar 

  12. Otabor GO, Ifijen IH, Mohammed FU, Aigbodion AI, Ikhuoria EU (2019) Alkyd resin from rubber seed oil/linseed oil blend: a comparative study of the blend properties. Heliyon 5(5)15:e01621

    Google Scholar 

  13. Ifijen HI, Nkwor AN (2020) Selected under-exploited plant oils in Nigeria: a correlative study of their physiochemical properties. Tanz J Sci 46(3):817–827

    Google Scholar 

  14. Nkwor AN, Ukoha PO, Ifijen HI (2021) Synthesis of sulfonated Sesamum indicum L. seed oil and its application as a fatliquor in leather processing. J Leather Sci Eng Springer Nature 3(16):1–13

    Google Scholar 

  15. Nkwor AN, Ukoha PO, Ifijen HI, Ikhuoria EU (2020) The use of sulfonated Jatropha Curcas oil for the processing of mechanically improved leather. Chem Afri. 3:911–925

    Article  CAS  Google Scholar 

  16. De Lima LRM, Martins FP, Lagarinhos JN, Santos L, Lima P, Torcato R, Marques PAAP, Rodriguez DL, Melo S, Grilo J et al (2020) Characterization of commercial graphene-based materials for application in thermoplastic nanocomposites. Mater Today Proc 20:383–390

    Article  Google Scholar 

  17. Calovi M, Rossi S, Deflorian F, Dirè S, Ceccato R (2020) Effect of functionalized graphene oxide concentration on the corrosion resistance properties provided by cataphoretic acrylic coatings. Mater Chem Phys 239:121984

    Google Scholar 

  18. Alammar A, Park SH, Williams CJ, Derby B, Szekely G (2020) Oil-in-water separation with graphene-based nanocomposite membranes for produced water treatment. J Memb Sci 603:118007

    Google Scholar 

  19. Cataldi P, Steiner P, Raine T, Lin K, Kocabas C, Young RJ, Bissett M, Kinloch IA, Papageorgiou DG (2020) Multifunctional biocomposites based on polyhydroxyalkanoate and graphene/carbon nanofiber hybrids for electrical and thermal applications. ACS Appl Polym Mater 2:3525–3534

    Article  CAS  Google Scholar 

  20. Khazaee A, Jahanshahi R, Sobhani S, Skibsted J, Sansano JM (2020) Immobilized piperazine on the surface of graphene oxide as a heterogeneous bifunctional acid-base catalyst for the multicomponent synthesis of 2-amino-3-cyano-4: H-chromenes. Green Chem 22:4604–4616

    Article  CAS  Google Scholar 

  21. Kweon H, Lin CW, Faruque Hasan MM, Kaner R, Sant GN (2019) Highly permeable polyaniline–grapheme oxide nanocomposite membranes for CO2 separations. ACS Appl Polym Mater 1:3233–3241

    Article  CAS  Google Scholar 

  22. Ma L, Zhou M, He C, Li S, Fan X, Nie C, Luo H, Qiu L, Cheng C (2019) Graphene-based advanced nanoplatforms and biocomposites from environmentally friendly and biomimetic approaches. Green Chem 21:4887–4918

    Article  CAS  Google Scholar 

  23. Cseri L, Baugh J, Alabi A, AlHajaj A, Zou L, Dryfe RAW, Budd PM, Szekely G (2018) Graphene oxide-polybenzimidazolium nanocomposite anion exchange membranes for electrodialysis. J Mater Chem 6:24728–24739

    Article  CAS  Google Scholar 

  24. Xuan Lim CHY, Sorkin A, Bao Q, Li A, Zhang K, Nesladek M, Loh KP (2013) A hydrothermal anvil made of graphene nanobubbles on diamond. Nat Commun 4:1556–1558

    Article  Google Scholar 

  25. Kyhl L, Nielsen SF, Cabo AG, Cassidy A, Miwa JA, Hornekær L (2015) Graphene as an anti-corrosion coating layer. Faraday Discuss 180:495–509

    Article  CAS  Google Scholar 

  26. Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang Y, Dubonos SV, Grigorieva IV, Firsov AA (2004) Electric field effect in atomically thin carbon films. Science 306:666–669

    Article  CAS  Google Scholar 

  27. Berger C, Song Z, Li X, Wu X, Brown N, Naud C, Mayou D, Li T, Hass J, Marchenkov AN, Conrad EH, First PN, de Heer WA (2006) Electronic confinement and coherence in patterned epitaxial graphene. Science 312:1191–1196

    Article  CAS  Google Scholar 

  28. Balandin AA (2020) Phononics of graphene and related materials. ACS Nano 14:5170–5178

    Article  CAS  Google Scholar 

  29. Emtsev KV, Bostwick A, Horn K, Jobst J, Kellogg GL, Ley L, McChesney JL, Ohta T, Reshanov SA, R€ohrl J et al (2009) Towards wafer-size graphene layers by atmospheric pressure graphitization of silicon carbide. Nat Mater 8:203–207

    Google Scholar 

  30. Hass J, Feng R, Li T, Li X, Zong Z, de Heer WA, First PN, Conrad EH, Jeffrey CA, Berger C (2006) Highly ordered graphene for two dimensional electronics. Appl Phys Lett 89:143106

    Google Scholar 

  31. Ferrari AC, Bonaccorso F, Falko V, Novoselov KS, Roche S, Bøggild P, Borini S, Koppens FHL, Palermo V, Pugno N et al (2015) Science and technology roadmap for graphene, related two-dimensional crystals and hybrid systems. Nanoscale 7:4598–4810

    Article  CAS  Google Scholar 

  32. Mishra N, Boeckl J, Motta N, Iacopi F (2016) Graphene growth on silicon carbide: a review. Phys Status Solidi A 213:2277–2289

    Article  CAS  Google Scholar 

  33. Yu Q, Lian J, Siriponglert S, Li H, Chen YP, Pei SS (2008) Graphene segregated on Ni surfaces and transferred to insulators. Appl Phys Lett 93:113103

    Google Scholar 

  34. Giovanneteti G, Khomyakov PA, Brocks G, Karpan VM, Vam DBJ, Kelly PJ (2008) Doping grapheme with metal contacts. Phys Rev Lett 101:026803

    Google Scholar 

  35. Ramezanzadeh M, Ramezanzadeh B, Mahdavian M, Bahlakeh G (2020) Development of metal-organic framework (MOF) decorated graphene oxide nanoplatforms for anti-corrosion epoxy coatings. Carbon 161:231–251

    Article  CAS  Google Scholar 

  36. Li X, Zhu Y, Cai W, Borysiak M, Han B, Chen D, Piner RD, Colombo L, Ruoff RS (2009) Transfer of large-area graphene films for high-performance transparent conductive electrodes. Nano Lett 9:4359–4363

    Article  CAS  Google Scholar 

  37. Kim Y, Song W, Lee SY, Jeon C, Jung W, Kim M, Park CY (2011) Low-temperature synthesis of large-area graphene-based transparent conductive films using surface wave plasma chemical vapor deposition. Appl Phys Lett 98:263106

    Google Scholar 

  38. Kulyk B, Carvalho AF, Fernandes AJS, Costa FM (2020) Millimeter sized graphene domains through in-situ oxidation/reduction treatment of the copper substrate. Carbon 169:403–415

    Article  CAS  Google Scholar 

  39. Xu X, Zhang Z, Dong J, Yi D, Niu J, Wu M, Lin L, Yin R, Li M, Zhou J et al (2017) Ultrafast epitaxial growth of metre-sized single-crystal graphene on industrial Cu foil. Sci Bull 62:1074–1080

    Article  CAS  Google Scholar 

  40. Munoz R, Gomez-Aleixandre C (2013) Review of CVD synthesis of graphene. Chem Vap Deposition 19:297–322

    Article  CAS  Google Scholar 

  41. Suk JW, Kitt A, Magnuson CW, Hao Y, Ahmed S, An J, Swan AK, Goldberg BB, Ruoff RS (2011) Transfer of CVD-grown monolayer graphene onto arbitrary substrates. ACS Nano 5:6916–6924

    Article  CAS  Google Scholar 

  42. Wang Y, Zheng Y, Xu X, Dubuisson E, Bao Q, Lu J, Loh KP (2011) Electrochemical delamination of CVD grown graphene film: toward the recyclable use of copper catalyst SI. ACS Nano 5:9927–9933

    Article  CAS  Google Scholar 

  43. Banszerus L, Schmitz M, Engels S, Goldsche M, Watanabe K, Taniguchi T, Beschoten B, Stampfer C (2011) Ballistic transport exceeding 28 lm in CVD grown graphene. Nano Lett 16:1387–1391

    Article  Google Scholar 

  44. Pirkle A, Chan J, Venugopal A, Hinojos D, Magnuson CW, McDonnell S, Colombo L, Vogel EM, Ruoff RS, Wallace RM (2011) The effect of chemical residues on the physical and electrical properties of chemical vapor deposited graphene transferred to SiO2. Appl Phys Lett 99:122108

    Google Scholar 

  45. Zhang Z et al (2018) Rosin-enabled ultraclean and damage-free transfer of graphene for large-area flexible organic light-emitting diodes. Nat Commun 8:1–9

    Google Scholar 

  46. Luo D, You X, Li BW, Chen X, Park HJ, Jung M, Ko TY, Wong K, Yousaf M, Chen X et al (2017) Role of graphene in water-assisted oxidation of copper in relation to dry transfer of graphene. Chem Mater 29:4546–4556

    Article  CAS  Google Scholar 

  47. Pu NW, Shi GN, Liu YM, Sun X, Chang JK, Sun CL, Ger MD, Chen CY, Wang PC, Peng YY (2015) Graphene grown on stainless steel as a high-performance and ecofriendly anti-corrosion coating for polymer electrolyte membrane fuel cell bipolar plates. J Power Sources 282:248–256

    Article  CAS  Google Scholar 

  48. Singh Raman RK, Chakraborty BP, Lobo DE, Gullapalli H, Sumandasa M, Kumar A, Choudhary L, Tkacz R, Ajayan PM, Majumder M (2012) Protecting copper from electrochemical degradation by graphene coating. Carbon 50:4040–4045

    Article  CAS  Google Scholar 

  49. Prasai D, Tuberquia JC, Harl RR, Jennings GK, Rogers BR, Bolotin KI (2012) Graphene: corrosion-inhibiting coating. ACS Nano 6:1102–1108

    Article  CAS  Google Scholar 

  50. Zhao Y, Xie Y, Hui YY, Tang L, Jie W, Jiang Y, Xu L, Shu PL, Chai Y (2013) Highly impermeable and transparent graphene as an ultra-thin protection barrier for Ag thin films. J Mater Chem C 1:4956–4961

    Article  CAS  Google Scholar 

  51. Zhang W, Lee S, Mcnear KL, Chung TF, Lee S, Lee K, Crist SA, Ratliff TL, Zhong Z, Chen YP (2014) Use of graphene as protection film in biological environments. Sci Rep 4:4097

    Article  Google Scholar 

  52. Hsieh YP, Hofmann M, Chang KW, Jian GJ, Li YY, Chen KY, Yang CC, Chang WS, Chen LC (2014) Complete corrosion inhibition through graphene defect passivation. ACS Nano 8(1):443–448

    Article  Google Scholar 

  53. Schriver M, Regan W, Gannett WJ, Zaniewski AM, Crommie MF, Zettl A (2013) Graphene as a long-term metal oxidation barrier: worse than nothing. ACS Nano 7:5763–5768

    Article  CAS  Google Scholar 

  54. Mirmohseni A, Azizi M, Dorraji MSS (2020) Cationic graphene oxide nanosheets intercalated with polyaniline nanofibers: a promising candidate for simultaneous anticorrosion, antistatic, and antibacterial applications. Prog Org Coat 139:105419

    Google Scholar 

  55. Ye Y, Chen H, Zou Y, Ye Y, Zhao H (2020) Corrosion protective mechanism of smart graphene-based self-healing coating on carbon steel. Corros Sci 174:108825

    Google Scholar 

  56. Zhang H, Zhou H, Yang J, Song Y, Zhao L (2019) Synergism of modified graphene oxide to aircraft structural corrosion inhibiting compounds coatings. Prog Org Coat 132:490–498

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2022 The Minerals, Metals & Materials Society

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Ifijen, I.H., Aghedo, O.N., Odiachi, I.J., Omorogbe, S.O., Olu, E.L., Onuguh, I.C. (2022). Nanostructured Graphene Thin Films: A Brief Review of Their Fabrication Techniques and Corrosion Protective Performance. In: TMS 2022 151st Annual Meeting & Exhibition Supplemental Proceedings. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-92381-5_33

Download citation

Publish with us

Policies and ethics