Abstract
Thermo-Calc and experimental analyses were carried out for the as-cast and heat-treated HK40 and HP40 steels. The as-cast steel specimens of about 1 × 1 × 1 cm were aged at 900 °C for times between 100 and 1000 h. As-cast and heat-treated specimens were characterized by X-ray diffraction, SEM, and Vickers hardness. Thermo-Calc Scheil analysis indicated an austenite matrix with the presence of Cr-rich M7C3, and M7C3 and (Nb,Ti)C carbides in the as-cast HK40 and HP40 steels, respectively, which is in agreement with X-ray diffraction, optical microscope, and scanning electron microscope results of present work. The aging treatment at 900 °C produces the precipitation of M23C6 carbides, and M23C6 and (Nb,Ti)C carbides in the austenite matrix of the as-cast HK40 and HP40 steels, respectively. This precipitation process promotes an increase in hardness. Thermo-Calc Prisma also predicted the precipitation of the same phases, and the fastest growth kinetics of precipitation was at 900 °C for the as-cast HK40 and 960 °C for the as-cast HP40 steel. In general, the aging response is better for the as-cast HK40 steel.
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References
Davis JR (1997) ASM specialty handbook: heat-resistant materials. ASM International, USA
Kaya AA (2002) Microstructure of HK40 alloy after high temperature service in oxidizing/carburizing environment, I. Oxidation phenomena and propagation of a crack. Mater Charact 49:11–21
Soares GDA, Almeida LH, Silveira TL, May IL (1992) Niobium additions in HP heat-resistant cast stainless steels. Mater Charact 29:387–396
ASTM Standard A351/A351M–03 (2004) Standard specification for casting, austenitic, austenitic-ferritic (duplex), for pressure-containing parts, ASTM
Alvino A (2014) Influence of chemical composition on microstructure and phase evolution of two HP heat resistant stainless steels after long term plant-service aging. Mater High Temp 31:1–11
Buchanan KG, Kral MV (2012) Crystallography and Morphology of niobium carbide in as-cast HP-niobium reformer tubes. Met Mater Trans A 43:1760–1765
Ribeiro EAAG, Papaleo R, Guimaraes JRC (1986) Microstructure and creep behavior of a niobium alloyed cast heat-resistant 26 pct Cr steel. Met Trans A 17:691–696
Thomas CW, Stevens KJ, Ryan MJ (1996) Microstructure and properties of alloy HP50–Nb: comparison of as cast and service exposed materials. Mater Sci Tech 12:469–475
Thermo-Calc software, TCFe7 and MoFe2, Version 2021 a, 2021
Kostorz G (2001) Phase transformations in materials. Wiley-VCH, Germany
Acknowledgements
The authors wish to thank the financial support from SIP-COFAA-IPN and CONACYT A1-S-9682.
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Lopez-Hirata, V.M., Saucedo-Muñoz, M.L., Dorantes-Rosales, H.J., Palma, C.F., Pérez-Badillo, E., Rivas-Lopez, D.I. (2022). Microstructure Evolution of HP40 and HK40 Steels After Isothermal Aging. In: TMS 2022 151st Annual Meeting & Exhibition Supplemental Proceedings. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-92381-5_137
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DOI: https://doi.org/10.1007/978-3-030-92381-5_137
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