Abstract
In this chapter, the properties, application areas, production techniques, and production of magnetic polymer nanocomposite materials in commercial and industrial fields are discussed. Researchers and manufacturers give an important role in additive manufacturing by magnetic polymer nanocomposite materials due to prototyping to high-throughput mass production. Magnetic nanocomposite polymers in additive materials in 4D and 3D printing techniques are used today in industrial and academic fields. In this chapter, information was given about the production, properties, usage areas, and industrial situation of nanocomposites (iron, nickel, cobalt, and their bimetallic and trimetallic alloys/salts) with magnetic properties by confining them into polymers. Magnetic polymer nanocomposites are formed by dissolving the magnetic properties of metals such as nickel, iron, and cobalt or their salts in a polymer matrix. With this method, it is preferred to be used in numerous commercial and industrial areas today. Because these nanocomposite materials, which we call smart substances, have the properties of self-renewal by adapting to the environment they enter. They are not affected by heat, temperature, pH, and humidity. This provides great convenience in the commercial and industrial fields today.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Similar content being viewed by others
References
Acidereli H, Karataş Y, Burhan H, Gülcan M, Şen F (2021) Magnetic nanoparticles. In: Nanoscale processing. Elsevier, Cham, pp 197–236
Altuner EE, Gur T, Şen F (2021a) Ternary/quaternary nanomaterials for direct alcohol fuel cells. Nanomater Direct Alcohol Fuel Cells:157–172. https://doi.org/10.1016/B978-0-12-821713-9.00001-9
Altuner EE, Bekmezci M, Bayat R, Akin M, Isik I, Şen F (2021b) Dendrimer-based nanocomposites for alcohol fuel cells. Nanomater Direct Alcohol Fuel Cells:337–352. https://doi.org/10.1016/B978-0-12-821713-9.00007-X
Altuner EE, Ozalp VC, Yilmaz MD, Bekmezci M, Sen F (2022) High-efficiency application of CTS-Co NPs mimicking peroxidase enzyme on TMB(ox). Chemosphere 292:133429. https://doi.org/10.1016/J.CHEMOSPHERE.2021.133429
Antonenko YN et al (2014) Photodynamic activity of the boronated chlorin e6 amide in artificial and cellular membranes. Biochim Biophys Acta Biomembr 1838(3):793–801. https://doi.org/10.1016/j.bbamem.2013.11.012
Aygun A et al (2022) Highly active PdPt bimetallic nanoparticles synthesized by one-step bioreduction method: characterizations, anticancer, antibacterial activities and evaluation of their catalytic effect for hydrogen generation. Int J Hydrog Energy. https://doi.org/10.1016/J.IJHYDENE.2021.12.144
Barrera G et al (2019) Magnetic properties of nanocomposites. Appl Sci 9(2):212. https://doi.org/10.3390/app9020212
Behrens S (2011) Preparation of functional magnetic nanocomposites and hybrid materials: recent progress and future directions. Nanoscale 3(3):877–892. https://doi.org/10.1039/c0nr00634c
Blok LG, Longana ML, Yu H, Woods BKS (2018) An investigation into 3D printing of fibre reinforced thermoplastic composites. Addit Manuf 22:176–186. https://doi.org/10.1016/j.addma.2018.04.039
Burke NAD, Stöver HDH, Dawson FP (2002) Magnetic nanocomposites: preparation and characterization of polymer-coated iron nanoparticles. Chem Mater 14(11):4752–4761. https://doi.org/10.1021/cm020126q
Çelik B, Kuzu S, Erken E, Sert H, Koşkun Y, Şen F (2016) Nearly monodisperse carbon nanotube furnished nanocatalysts as highly efficient and reusable catalyst for dehydrocoupling of DMAB and C1 to C3 alcohol oxidation. Int J Hydrog Energy 41(4):3093–3101. https://doi.org/10.1016/j.ijhydene.2015.12.138
Charmot D et al (1993) Magnetizable composite microspheres of hydrophobic crosslinked polymer, process for preparing them and their application in biology, U.S. Pat. No. 5,356,713
Credi C et al (2016) 3D printing of cantilever-type microstructures by stereolithography of ferromagnetic photopolymers. ACS Appl Mater Interfaces 8(39):26332–26342. https://doi.org/10.1021/acsami.6b08880
D’Amora U et al (2017) 3D additive-manufactured nanocomposite magnetic scaffolds: effect of the application mode of a time-dependent magnetic field on hMSCs behavior. Bioact Mater 2(3):138–145. https://doi.org/10.1016/j.bioactmat.2017.04.003
De Leon AC, Chen Q, Palaganas NB, Palaganas JO, Manapat J, Advincula RC (2016) High performance polymer nanocomposites for additive manufacturing applications. React Funct Polym 103:141–155. https://doi.org/10.1016/j.reactfunctpolym.2016.04.010
Demir E, Sen B, Sen F (2017) Highly efficient Pt nanoparticles and f-MWCNT nanocomposites based counter electrodes for dye-sensitized solar cells. Nano-Struct Nano-Objects 11:39–45. https://doi.org/10.1016/j.nanoso.2017.06.003
Dresco PA, Zaitsev VS, Gambino RJ, Chu B (1999) Preparation and properties of magnetite and polymer magnetite nanoparticles. Langmuir 15(6):1945–1951. https://doi.org/10.1021/la980971g
Eris S, Daşdelen Z, Sen F (2018) Enhanced electrocatalytic activity and stability of monodisperse Pt nanocomposites for direct methanol fuel cells. J Colloid Interface Sci 513:767–773. https://doi.org/10.1016/j.jcis.2017.11.085
Erol Taygun M, Hatinoğlu G, Öztürk P, Yerli N, Küçükbayrak S (2018) Characterization of the rheology of polymer/bioactive glass solutions and fabrication of nanocomposite materials. Eurasian J Biol Chem Sci [online]. Available: www.dergipark.gov.tr/ejbcs. Accessed 15 Feb 2021
Falahati M et al (2020) Smart polymers and nanocomposites for 3D and 4D printing. Mater Today 40:215–245. https://doi.org/10.1016/j.mattod.2020.06.001
Gacitua W, Ballerini A, Zhang J (2005) Polymer nanocomposites: synthetic and natural fillers: a review. Maderas Cienc Tecnol 7(3):159–178. https://doi.org/10.4067/s0718-221x2005000300002
Gandha K et al (2018) Additive manufacturing of anisotropic hybrid NdFeB-SmFeN nylon composite bonded magnets. J Magn Magn Mater 467:8–13. https://doi.org/10.1016/j.jmmm.2018.07.021
Godovski DY (1995) Electron behavior and magnetic properties of polymer nanocomposites. Adv Polym Sci 119:78–122. https://doi.org/10.1007/bfb0021281
Google Kitaplar (2021) Comprehensive materials processing. https://books.google.com.tr/books?hl=tr&lr=&id=OV9-AgAAQBAJ&oi=fnd&pg=PP1&dq=(Comprehensive+materials+processing&ots=_2zfKAHFHS&sig=cUxM8VCLYjenX96ea7VkY7vjELA&redir_esc=y#v=onepage&q=(Comprehensive materials processing&f=false. Accessed 19 Feb 2021
Gupta M, Srivatsan TS, Lim CYH, Varim RA (2005) Processing and fabrication of advanced materials XIII. Stallion Press, pp 367–375
Horák D (2001) Magnetic polyglycidylmethacrylate microspheres by dispersion polymerization. J Polym Sci A Polym Chem 39(21):3707–3715. https://doi.org/10.1002/pola.10000
Huang Y, Chen X, Wang Z et al (2002) Enhanced magnetoresistance in granular La2/3Ca1/3MNO3/polymer composites. J Appl Phys 91:7733–7735. Available: https://aip.scitation.org/doi/abs/10.1063/1.1448302. Online: aip.scitation.org. Accessed 15 Feb 2021
Jordan J, Jacob KI, Tannenbaum R, Sharaf MA, Jasiuk I (2005) Experimental trends in polymer nanocomposites – a review. Mater Sci Eng A 393(1–2):1–11. https://doi.org/10.1016/j.msea.2004.09.044
Kalia S, Kango S, Kumar A, Haldorai Y, Kumari B, Kumar R (2014) Magnetic polymer nanocomposites for environmental and biomedical applications. Colloid Polym Sci 292(9):2025–2052. https://doi.org/10.1007/s00396-014-3357-y
Kango S, Kalia S, Celli A, Njuguna J, Habibi Y, Kumar R (2013) Surface modification of inorganic nanoparticles for development of organic–inorganic nanocomposites – a review. Prog Polym Sci 38:1232–1261
Karaca HE, Karaman I, Basaran B, Ren Y, Chumlyakov YI, Maier HJ (2009) Magnetic field-induced phase transformation in NiMnCoIn magnetic shape-memory alloys – a new actuation mechanism with large work output. Adv Funct Mater 19(7):983–998. https://doi.org/10.1002/adfm.200801322
Khatri B, Lappe K, Noetzel D, Pursche K, Hanemann T (2018) A 3D-printable polymer-metal soft-magnetic functional composite – development and characterization. Materials 11(2):189. https://doi.org/10.3390/ma11020189
Kodama H (1981) Automatic method for fabricating a three-dimensional plastic model with photo-hardening polymer. Rev Sci Instrum 52(11):1770–1773. https://doi.org/10.1063/1.1136492
Kong I, Ahmad SH, Abdullah MH, Yusoff AN (2009) The effect of temperature on magnetic behavior of magnetite nanoparticles and its nanocomposites. AIP Conf Proc 1136(1):830–834. https://doi.org/10.1063/1.3160267
Koskun Y, Şavk A, Şen B, Şen F (2018) Highly sensitive glucose sensor based on monodisperse palladium nickel/activated carbon nanocomposites. Anal Chim Acta 1010:37–43. https://doi.org/10.1016/j.aca.2018.01.035
Li L et al (2017) A novel method combining additive manufacturing and alloy infiltration for NdFeB bonded magnet fabrication. J Magn Magn Mater 438:163–167. https://doi.org/10.1016/j.jmmm.2017.04.066
Manapat JZ, Chen Q, Ye P, Advincula RC (2017) 3D printing of polymer nanocomposites via stereolithography. Macromol Mater Eng 302(9). https://doi.org/10.1002/mame.201600553
Muhammad Imran S et al (2016) Carbon nanotube-based thermoplastic polyurethane-poly (methyl methacrylate) nanocomposites for pressure sensing applications. Polym Eng Sci. https://doi.org/10.1002/pen.24333
Nadgorny M, Collins J, Xiao Z, Scales PJ, Connal LA (2018) 3D-printing of dynamic self-healing cryogels with tuneable properties. Polym Chem 9(13):1684–1692. https://doi.org/10.1039/c7py01945a
Nas MS, Kuyuldar E, Demirkan B, Calimli MH, Demirbaş O, Sen F (2019) Magnetic nanocomposites decorated on multiwalled carbon nanotube for removal of Maxilon Blue 5G using the sono-Fenton method. Sci Rep 9(1):1–11. https://doi.org/10.1038/s41598-019-47393-0
Njuguna J, Pielichowski K, Fan J (2012) Polymer nanocomposites for aerospace applications. In: Advances in polymer nanocomposites: types and applications. Elsevier, Cham, pp 472–539
Novakova AA et al (2003) Magnetic properties of polymer nanocomposites containing iron oxide nanoparticles. J Magn Magn Mater 258–259:354–357. https://doi.org/10.1016/S0304-8853(02)01062-4
Özdemir S et al (2021) Extraction of Cu2+ and Co2+ by using Tricholoma populinum loaded onto Amberlite XAD-4. Int J Environ Sci Technol 18(1):185–194. https://doi.org/10.1007/s13762-020-02845-3
Palaganas NB et al (2017) 3D printing of photocurable cellulose nanocrystal composite for fabrication of complex architectures via stereolithography. ACS Appl Mater Interfaces 9(39):34314–34324. https://doi.org/10.1021/acsami.7b09223
Paranthaman MP et al (2016) Binder jetting: a novel NdFeB bonded magnet fabrication Process. JOM 68(7):1978–1982. https://doi.org/10.1007/s11837-016-1883-4
Paul DR, Robeson LM (2008) Polymer nanotechnology: nanocomposites. Polymer 49(15):3187–3204. https://doi.org/10.1016/j.polymer.2008.04.017
Périgo EA, Jacimovic J, GarcÃa Ferré F, Scherf LM (2019) Additive manufacturing of magnetic materials. Addit Manuf 30:100870. https://doi.org/10.1016/j.addma.2019.100870
Poddar P et al (2004) Synthesis and magnetic properties of polymer nanocomposites with embedded iron nanoparticles. J Appl Phys 95(3):1439–1443. https://doi.org/10.1063/1.1637705
Rezazadeh Shirdar M, Sudin I, Taheri MM, Keyvanfar A, Yusop MZM, Kadir MRA (2015) A novel hydroxyapatite composite reinforced with titanium nanotubes coated on Co-Cr-based alloy. Vacuum 122:82–89. https://doi.org/10.1016/j.vacuum.2015.09.008
Şavk A, Aydın H, Cellat K, Şen F (2020) A novel high performance non-enzymatic electrochemical glucose biosensor based on activated carbon-supported Pt-Ni nanocomposite. J Mol Liq 300:112355. https://doi.org/10.1016/j.molliq.2019.112355
Sekol RC et al (2013) Pd-Ni-Cu-P metallic glass nanowires for methanol and ethanol oxidation in alkaline media. Int J Hydrog Energy 38(26):11248–11255. https://doi.org/10.1016/j.ijhydene.2013.06.017
Şen F, Şen S, Gökaǧaç G (2011) Efficiency enhancement of methanol/ethanol oxidation reactions on Pt nanoparticles prepared using a new surfactant, 1,1-dimethyl heptanethiol. Phys Chem Chem Phys 13(4):1676–1684. https://doi.org/10.1039/c0cp01212b
Sen B, Kuzu S, Demir E, Akocak S, Sen F (2017) Highly monodisperse RuCo nanoparticles decorated on functionalized multiwalled carbon nanotube with the highest observed catalytic activity in the dehydrogenation of dimethylamine−borane. Int J Hydrog Energy 42(36):23292–23298. https://doi.org/10.1016/j.ijhydene.2017.06.032
Sen B, Demirkan B, Şavk A, Karahan Gülbay S, Sen F (2018a) Trimetallic PdRuNi nanocomposites decorated on graphene oxide: a superior catalyst for the hydrogen evolution reaction. Int J Hydrog Energy 43(38):17984–17992. https://doi.org/10.1016/j.ijhydene.2018.07.122
Sen B, Demirkan B, Şimşek B, Savk A, Sen F (2018b) Monodisperse palladium nanocatalysts for dehydrocoupling of dimethylamineborane. Nano-Struct Nano-Objects 16:209–214. https://doi.org/10.1016/j.nanoso.2018.07.008
Sen B, Kuyuldar E, Şavk A, Calimli H, Duman S, Sen F (2019) Monodisperse ruthenium–copper alloy nanoparticles decorated on reduced graphene oxide for dehydrogenation of DMAB. Int J Hydrog Energy 44(21):10744–10751. https://doi.org/10.1016/j.ijhydene.2019.02.176
Senkov ON, Senkova SV, Scott JM, Miracle DB (2005) Compaction of amorphous aluminum alloy powder by direct extrusion and equal channel angular extrusion. Mater Sci Eng A 393(1–2):12–21. https://doi.org/10.1016/j.msea.2004.09.061
Sert H et al (2017) Activated carbon furnished monodisperse Pt nanocomposites as a superior adsorbent for methylene blue removal from aqueous solutions. J Nanosci Nanotechnol 17(7):4799–4804. https://doi.org/10.1166/jnn.2017.13776
Shannigrahi SR, Pramoda KP, Nugroho FAA (2012) Synthesis and characterizations of microwave sintered ferrite powders and their composite films for practical applications. J Magn Magn Mater 324(2):140–145. https://doi.org/10.1016/j.jmmm.2011.07.050
Shen A, Bailey CP, Ma AWK, Dardona S (2018) UV-assisted direct write of polymer-bonded magnets. J Magn Magn Mater 462:220–225. https://doi.org/10.1016/j.jmmm.2018.03.073
Spanhel L, Anderson MA (1990) Synthesis of porous quantum-size CdS membranes: photoluminescence phase shift and demodulation measurements. J Am Chem Soc 112(6):2278–2284. https://doi.org/10.1021/ja00162a031
Talapin DV, Lee JS, Kovalenko MV, Shevchenko EV (2010) Prospects of colloidal nanocrystals for electronic and optoelectronic applications. Chem Rev 110(1):389–458. https://doi.org/10.1021/cr900137k
Tjong SC (2012) Polymer composites with carbonaceous nanofillers: properties and applications. Wiley, New York
Tripathy J (2017) Polymer nanocomposites for biomedical and biotechnology applications. In: Properties and applications of polymer nanocomposites: clay and carbon based polymer nanocomposites. Springer, Berlin/Heidelberg, pp 57–76
Tripathy A, Raichur AM, Chandrasekaran N, Prathna TC, Mukherjee A (2010) Process variables in biomimetic synthesis of silver nanoparticles by aqueous extract of Azadirachta indica (neem) leaves. J Nanopart Res 12(1):237–246. https://doi.org/10.1007/s11051-009-9602-5
Ugelstad J et al (1993) Monodisperse magnetic polymer particles. Blood Purif 11(6):349–369. https://doi.org/10.1159/000170129
Ullakko K, Huang JK, Kantner C, O’Handley RC, Kokorin VV (1996) Large magnetic-field-induced strains in Ni2MnGa single crystals. Appl Phys Lett 69(13):1966–1968. https://doi.org/10.1063/1.117637
Williams KR, Burstein GT (1997) Low temperature fuel cells: interactions between catalysts and engineering design. Catal Today 38(4):401–410. https://doi.org/10.1016/S0920-5861(97)00051-5
Wilson JL et al (2004) Synthesis and magnetic properties of polymer nanocomposites with embedded iron nanoparticles. J Appl Phys 95(3):1439–1443. https://doi.org/10.1063/1.1637705
Wing Mai Y, Yu Z-Z (2006) Polymer nanocomposites
Wu H et al (2020) Recent developments in polymers/polymer nanocomposites for additive manufacturing. Prog Mater Sci 111:100638. https://doi.org/10.1016/j.pmatsci.2020.100638
Yang TI, Brown RNC, Kempel LC, Kofinas P (2008) Magneto-dielectric properties of polymer-Fe3O4 nanocomposites. J Magn Magn Mater 320(21):2714–2720. https://doi.org/10.1016/j.jmmm.2008.06.008
Yun HM et al (2016) Magnetic nanocomposite scaffolds combined with static magnetic field in the stimulation of osteoblastic differentiation and bone formation. Biomaterials 85:88–98. https://doi.org/10.1016/j.biomaterials.2016.01.035
Zaidi NA, Giblin SR, Terry I, Monkman AP (2004) Room temperature magnetic order in an organic magnet derived from polyaniline. Polymer 45(16):5683–5689. https://doi.org/10.1016/j.polymer.2004.06.002
Ziolo RF et al (1992) Matrix-mediated synthesis of nanocrystalline γ-Fe2O3: a new optically transparent magnetic material. Science 257(5067):219–223. https://doi.org/10.1126/science.257.5067.219
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Section Editor information
Rights and permissions
Copyright information
© 2022 Springer Nature Switzerland AG
About this entry
Cite this entry
Altuner, E.E., Bekmezci, M., Sen, F. (2022). Manufacturing Techniques of Magnetic Polymer Nanocomposites. In: Thomas, S., Rezazadeh Nochehdehi, A. (eds) Handbook of Magnetic Hybrid Nanoalloys and their Nanocomposites. Springer, Cham. https://doi.org/10.1007/978-3-030-90948-2_12
Download citation
DOI: https://doi.org/10.1007/978-3-030-90948-2_12
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-90947-5
Online ISBN: 978-3-030-90948-2
eBook Packages: Physics and AstronomyReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics