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Fundamentals of Hierarchically Porous Materials and Its Catalytic Applications

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Advanced Functional Porous Materials

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Abstract

The evolution of hierarchical porous materials has enhanced the productivity of the energy storage system owing to their higher surface area, space availability, low density, interconnected porosity at diverse scales, variable chemical composition, and excellent accommodation capability with thermal variation and space volume. The hierarchical porous structure benefits ion and electron transport, and diffusion, and mass transfer. With the varying pore structures, the electrochemical properties of hierarchical porous material vary. With the exact knowledge on the dependency of the pore dimensions and structures, the highly effective hierarchical porous structured materials could be fabricated with enriched catalytic performance. In this chapter, we have deliberated the characteristic properties of the hierarchically structured pores to summarize their recent development which mainly emphasized their catalytic applications. The first section of this chapter included brief discussions on the fundamentals, classification, and synthesis of the hierarchical porous materials. In the next section of this chapter, we mainly emphasized on application of hierarchical porous based on their catalytic activity. In the final section, the conclusion and the future aspects of hierarchical porous materials are included.

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References

  • Bronstein, L.M., Goerigk, G., Kostylev, M., Pink, M., Khotina, I.A., Valetsky, P.M., Matveeva, V.G., Sulman, E.M., Sulman, M.G., Bykov, A.V., Lakina, N.V., Spontak, R.J.: Structure and catalytic properties of Pt-modified hyper-cross-linked polystyrene exhibiting hierarchical porosity. J. Phys. Chem. B 108, 18234–18242 (2004). https://doi.org/10.1021/jp046459n

    Article  CAS  Google Scholar 

  • Cao, J., Zhu, C., Aoki, Y., Habazaki, H.: Starch-derived hierarchical porous carbon with controlled porosity for high performance supercapacitors. ACS Sustain. Chem. Eng. 6, 7292–7303 (2018). https://doi.org/10.1021/acssuschemeng.7b04459

    Article  CAS  Google Scholar 

  • Chai, G.S., Shin, I.S., Yu, J.S.: Synthesis of ordered, uniform, macroporous carbons with mesoporous walls templated by aggregates of polystyrene spheres and silica particles for use as catalyst supports in direct methanol fuel cells. Adv. Mater. 16, 2057–2061 (2004). https://doi.org/10.1002/adma.200400283

    Article  CAS  Google Scholar 

  • Chen, L.H., Li, X.Y., Tian, G., Li, Y., Rooke, J.C., Zhu, G.S., Qiu, S.L., Yang, X.Y., Su, B.L.: Highly stable and reusable multimodal zeolite TS-1 based catalysts with hierarchically interconnected three-level micro-meso-macroporous structure. Angew. Chem. Int. Ed. 50, 11156–11161 (2011). https://doi.org/10.1002/anie.201105678

    Article  CAS  Google Scholar 

  • Clauset, A., Moore, C., Newman, M.E.J.: Hierarchical structure and the prediction of missing links in networks. Nature 453, 98–101 (2008). https://doi.org/10.1038/nature06830

    Article  CAS  Google Scholar 

  • Czernik, S., Bridgwater, A.V.: Overview of applications of biomass fast pyrolysis oil. Energy Fuels 18, 590–598 (2004). https://doi.org/10.1021/ef034067u

    Article  CAS  Google Scholar 

  • Dhainaut, J., Dacquin, J.P., Lee, A.F., Wilson, K.: Hierarchical macroporous–mesoporous SBA-15 sulfonic acid catalysts for biodiesel synthesis. Green Chem. 12, 296–330 (2010). https://doi.org/10.1039/b919341c

    Article  CAS  Google Scholar 

  • Dong, F., Lee, S.C., Wu, Z., Huang, Y., Fu, M., Ho, W.K., Zou, S., Wang, B.: Rose-like monodisperse bismuth subcarbonate hierarchical hollow microspheres: one-pot template-free fabrication and excellent visible light photocatalytic activity and photochemical stability for NO removal in indoor air. J. Hazard. Mater. 195, 346–354 (2011). https://doi.org/10.1016/j.jhazmat.2011.08.050

    Article  CAS  Google Scholar 

  • Du, J., Lai, X., Yang, N., Zhai, J., Kisailus, D., Su, F., Wang, D., Jiang, L.: Hierarchically ordered macro-mesoporous TiO2-graphene composite films: improved mass transfer, reduced charge recombination, and their enhanced photocatalytic activities. ACS Nano 5, 590–596 (2011). https://doi.org/10.1021/nn102767d

    Article  CAS  Google Scholar 

  • Florea, I., Houllé, M., Ersen, O., Roiban, L., Deneuve, A., Janowska, I., Nguyen, P., Pham, C., Pham-Huu, C.: Selective deposition of palladium nanoparticles inside the bimodal porosity of-SiC investigated by electron tomography. J. Phys. Chem. C 113, 17711–17719 (2009). https://doi.org/10.1021/jp905968n

  • Fu, A., Wang, C., Pei, F., Cui, J., Fang, X., Zheng, N.: Recent advances in hollow porous carbon materials for lithium–sulfur batteries (2019)

    Google Scholar 

  • Géraud, E., Rafqah, S., Sarakha, M., Forano, C., Prevot, V., Leroux, F.: Three dimensionally ordered macroporous layered double hydroxides: preparation by templated impregnation/coprecipitation and pattern stability upon calcination. Chem. Mater. 20, 1116–1125 (2008). https://doi.org/10.1021/cm702755h

    Article  CAS  Google Scholar 

  • Holladay, J.D., Wang, Y., Jones, E.: Review of developments in portable hydrogen production using microreactor technology. Chem. Rev. 104, 4767–4789 (2004). https://doi.org/10.1021/cr020721b

    Article  CAS  Google Scholar 

  • Jang, I.J., Shin, H.S., Shin, N.R., Kim, S.H., Kim, S.K., Yu, M.J., Cho, S.J.: Macroporous-mesoporous alumina supported iridium catalyst for hydrazine decomposition. Catal. Today 185, 198–204 (2012)

    Google Scholar 

  • Kamegawa, T., Suzuki, N., Che, M., Yamashita, H.: Synthesis and unique catalytic performance of single-site Ti-containing hierarchical macroporous silica with mesoporous frameworks. Langmuir 27, 2873–2879 (2011). https://doi.org/10.1021/la1048634

    Article  CAS  Google Scholar 

  • Kamperman, M., Burns, A., Weissgraeber, R., Van Vegten, N., Warren, S.C., Gruner, S.M., Baiker, A., Wiesner, U.: Integrating structure control over multiple length scales in porous high temperature ceramics with functional platinum nanoparticles. Nano Lett. 9, 2756–2762 (2009). https://doi.org/10.1021/nl901293p

    Article  CAS  Google Scholar 

  • Kim, Y.-S., Guo, X.-F., Kim, G.-J.: Asymmetric ring opening reaction of catalyst immobilized on silica monolith with bimodal meso/macroscopic pore structure. Top. Catal. (2009). https://doi.org/10.1007/s11244-008-9140-x

  • Lal, H.M., Xian, G., Thomas, S., Zhang, L., Zhang, Z., Wang, H.: Experimental study on the flexural creep behaviors of pultruded unidirectional carbon/glass fiber-reinforced hybrid bars. Materials 13, 11–13 (2020). https://doi.org/10.3390/ma13040976

    Article  CAS  Google Scholar 

  • Lal, H.M., Thomas, S., Li, T., Maria, H.J.: Polymer Nanocomposites Based on Silver Nanoparticles. Springer International Publishing (2021a)

    Google Scholar 

  • Lal, H.M., Uthaman, A., Thomas, S.: Silver Nanoparticle as an Effective Antiviral Agent. Springer Nature (2021b)

    Google Scholar 

  • Lin, Y.G., Hsu, Y.K., Chen, S.Y., Chen, L.C., Chen, K.H.: O2 plasma-activated CuO-ZnO inverse opals as high-performance methanol microreformer. J. Mater. Chem. 20, 10611–10614 (2010). https://doi.org/10.1039/c0jm02605k

    Article  CAS  Google Scholar 

  • Louis, B., Ocampo, F., Yun, H.S., Tessonnier, J.P., Pereira, M.M.: Hierarchical pore ZSM-5 zeolite structures: from micro- to macro-engineering of structured catalysts. Chem. Eng. J. 161, 397–402 (2010). https://doi.org/10.1016/j.cej.2009.09.041

    Article  CAS  Google Scholar 

  • Lu, S., Liu, Y., Wang, Y.: Meso-macro-porous monolithic Pt-Ni/Al2O3 catalysts used for miniaturizing preferential carbon monoxide oxidation reactor. Chem. Commun. 46, 634–636 (2010). https://doi.org/10.1039/b912769k

    Article  CAS  Google Scholar 

  • Ma, X., Feng, X., He, X., Guo, H., Lü, L.: Preparation, characterization and catalytic behavior of hierachically porous CuO/α-Fe2O3/SiO2 composite material for CO and o-DCB oxidation. J. Nat. Gas Chem. 20, 618–622 (2011). https://doi.org/10.1016/S1003-9953(10)60253-8

    Article  CAS  Google Scholar 

  • Martínez, A., Prieto, G., Rollán, J.: Nanofibrous γ-Al2O3 as support for Co-based Fischer-Tropsch catalysts: pondering the relevance of diffusional and dispersion effects on catalytic performance. J. Catal. 263, 292–305 (2009). https://doi.org/10.1016/j.jcat.2009.02.021

    Article  CAS  Google Scholar 

  • Mudassir, M.A., Hussain, S.Z., Rehman, A., Zaheer, W., Asma, S.T., Jilani, A., Aslam, M., Zhang, H., Ansari, T.M., Hussain, I.: Development of silver-nanoparticle-decorated emulsion-templated hierarchically porous poly(1-vinylimidazole) beads for water treatment. ACS Appl. Mater. Interfaces 9, 24190–24197 (2017). https://doi.org/10.1021/acsami.7b05311

    Article  CAS  Google Scholar 

  • Parlett, C.M.A., Wilson, K., Lee, A.F.: Hierarchical porous materials: catalytic applications. Chem. Soc. Rev. 42, 3876–3893 (2013). https://doi.org/10.1039/c2cs35378d

    Article  CAS  Google Scholar 

  • Poladi, R.H.P.R., Landry, C.C.: Oxidation of octane and cyclohexane using a new porous substrate, Ti-MMM-1. Microporous Mesoporous Mater. 52, 11–18 (2002). https://doi.org/10.1016/S1387-1811(02)00272-X

    Article  CAS  Google Scholar 

  • Schwieger, W., Machoke, A.G., Weissenberger, T., Inayat, A., Selvam, T., Klumpp, M., Inayat, A.: Hierarchy concepts: classification and preparation strategies for zeolite containing materials with hierarchical porosity. Chem. Soc. Rev. 45, 3353–3376 (2016). https://doi.org/10.1039/c5cs00599j

    Article  CAS  Google Scholar 

  • Shi, X., Yao, Y., Xu, Y., Liu, K., Zhu, G., Chi, L., Lu, G.: Imparting catalytic activity to a covalent organic framework material by nanoparticle encapsulation. ACS Appl. Mater. Interfaces 9, 7481–7488 (2017). https://doi.org/10.1021/acsami.6b16267

    Article  CAS  Google Scholar 

  • Uthaman, A., Xian, G., Thomas, S., Wang, Y., Zheng, Q., Liu, X.: Durability of an epoxy resin and its carbon fiber-reinforced polymer composite upon immersion in water, acidic, and alkaline solutions. Polymers 12 (2020). https://doi.org/10.3390/polym12030614

  • Uthaman, A., Lal, H.M., Li, C., Xian, G., Thomas, S.: Mechanical and water uptake properties of epoxy nanocomposites with surfactant-modified functionalized multiwalled carbon nanotubes. Nanomaterials 11, 1–16 (2021a). https://doi.org/10.3390/nano11051234

  • Uthaman, A., Lal, H.M., Thomas, S.: Fundamentals of Silver Nanoparticles and Their Toxicological Aspects. Springer Nature (2021b)

    Google Scholar 

  • Uthaman, A., Lal, H.M., Thomas, S.: Silver Nanoparticle on Various Synthetic Polymer Matrices: Preparative Techniques, Characterizations, and Applications. Springer Nature (2021c)

    Google Scholar 

  • Valtchev, V., Balanzat, E., Mavrodinova, V., Diaz, I., El Fallah, J., Goupil, J.M.: High energy ion irradiation-induced ordered macropores in zeolite crystals. J. Am. Chem. Soc. 133, 18950–18956 (2011). https://doi.org/10.1021/ja208140f

    Article  CAS  Google Scholar 

  • Wang, D., Liu, Z., Wang, H., Xie, Z., Tang, Y.: Shape-controlled synthesis of monolithic ZSM-5 zeolite with hierarchical structure and mechanical stability. Microporous Mesoporous Mater. 132, 428–434 (2010). https://doi.org/10.1016/j.micromeso.2010.03.023

    Article  CAS  Google Scholar 

  • Witoon, T., Chareonpanich, M., Limtrakul, J.: Effect of hierarchical meso-macroporous silica supports on Fischer-Tropsch synthesis using cobalt catalyst. Fuel Process. Technol. 92, 1498–1505 (2011). https://doi.org/10.1016/j.fuproc.2011.03.011

    Article  CAS  Google Scholar 

  • Woodford, J.J., Dacquin, J.P., Wilson, K., Lee, A.F.: Better by design: nanoengineered macroporous hydrotalcites for enhanced catalytic biodiesel production. Energy Environ. Sci. 5, 6145–6150 (2012). https://doi.org/10.1039/c2ee02837a

    Article  CAS  Google Scholar 

  • Wu, L., Li, Y., Fu, Z., Su, B.L.: Hierarchically structured porous materials: synthesis strategies and applications in energy storage. Natl. Sci. Rev. 7, 1667–1701 (2020). https://doi.org/10.1093/nsr/nwaa183

    Article  CAS  Google Scholar 

  • Xu, L., Sithambaram, S., Zhang, Y., Chen, C.H., Jin, L., Joesten, R., Suib, S.L.: Novel urchin-like CuO synthesized by a facile reflux method with efficient olefin epoxidation catalytic performance. Chem. Mater. 21, 1253–1259 (2009). https://doi.org/10.1021/cm802915m

    Article  CAS  Google Scholar 

  • Yan, Z., He, G., Zhang, G., Meng, H., Shen, P.K.: Pd nanoparticles supported on ultrahigh surface area honeycomb-like carbon for alcohol electrooxidation. Int. J. Hydrogen Energy 35, 3263–3269 (2010). https://doi.org/10.1016/j.ijhydene.2010.01.031

    Article  CAS  Google Scholar 

  • Yang, X.Y., Tian, G., Chen, L.H., Li, Y., Rooke, J.C., Wei, Y.X., Liu, Z.M., Deng, Z., Van Tendeloo, G., Su, B.L.: Well-organized zeolite nanocrystal aggregates with interconnected hierarchically micro-meso-macropore systems showing enhanced catalytic performance. Chem. A Eur. J. 17, 14987–14995 (2011). https://doi.org/10.1002/chem.201101594

    Article  CAS  Google Scholar 

  • Yang, X.Y., Chen, L.H., Li, Y., Rooke, J.C., Sanchez, C., Su, B.L.: Hierarchically porous materials: synthesis strategies and structure design (2017). www.rsc.org/chemsocrev

  • Yu, Y., Hou, S., Meng, M., Tao, X., Liu, W., Lai, Y., Zhang, B.: Converting inorganic-organic hybrid sulfides into oxides: a general strategy to hierarchical-porous-structured thermal-stable metal oxides with improved catalytic performance. J. Mater. Chem. 21, 10525–10531 (2011). https://doi.org/10.1039/c1jm11057h

    Article  CAS  Google Scholar 

  • Zaman, A., Huang, F., Jiang, M., Wei, W., Kadhim, N., Zhou, Z.: Fabrication of enhanced epoxy composite by embedded hierarchical porous lignocellulosic foam. Renew. Energy 150, 1066–1073 (2020). https://doi.org/10.1016/j.renene.2019.10.146

    Article  CAS  Google Scholar 

  • Zhang, W., Sherrell, P., Minett, A.I., Razal, J.M., Chen, J.: Carbon nanotube architectures as catalyst supports for proton exchange membrane fuel cells (2010). https://pubs.rsc.org/en/content/articlehtml/2010/ee/c0ee00139b

  • Zhou, L., Wang, W., Xu, H., Sun, S., Shang, M.: Bi2O3 hierarchical nanostructures: controllable synthesis, growth mechanism, and their application in photocatalysis. Chem. A Eur. J. 15, 1776–1782 (2009). https://doi.org/10.1002/chem.200801234

    Article  CAS  Google Scholar 

  • Zhou, Z., Zeng, T., Cheng, Z., Yuan, W.: Preparation of a catalyst for selective hydrogenation of pyrolysis gasoline. Ind. Eng. Chem. Res. 49, 11112–11118 (2010)

    Google Scholar 

  • Zhu, L.P., Liao, G.H., Bing, N.C., Wang, L.L., Yang, Y., Xie, H.Y.: Self-assembled 3D BiOCl hierarchitectures: tunable synthesis and characterization. CrystEngComm 12, 3791–3796 (2010). https://doi.org/10.1039/c0ce00038h

    Article  CAS  Google Scholar 

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Lal, H.M., Uthaman, A., Thomas, S. (2022). Fundamentals of Hierarchically Porous Materials and Its Catalytic Applications. In: Uthaman, A., Thomas, S., Li, T., Maria, H. (eds) Advanced Functional Porous Materials. Engineering Materials. Springer, Cham. https://doi.org/10.1007/978-3-030-85397-6_12

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