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Composite Scintillators

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Plastic Scintillators

Part of the book series: Topics in Applied Physics ((TAP,volume 140))

Abstract

In this chapter, organic–inorganic composite scintillators are introduced with the main focus on nanocomposites. In the field of materials science, organic–inorganic nanocomposites have been used for wide applications. They are designed to offer the advantages of both organic and inorganic counterparts and synergetic effects of the composites. A rich variety of optical materials have been developed based on polymers and inorganic nanoparticles. In spite of the intriguing functionality of the nanocomposites, the fabrication of uniform nanocomposites is challenging in preventing the aggregation of the inorganic nanoparticles. Some strategies to overcome the main issues are introduced in Sect. 6.1.1. Also, two related optical phenomena inherent to nanocomposites are introduced in Sect. 6.1.2: one is the scattering at the interface between the inorganic and organic phases, and the other is the quantum confinement effects of semiconductor nanocrystals, which are attractive inorganic phosphors in nanocomposite scintillators. Subsequently, examples of nanocomposite scintillators prepared by different approaches and design principles are explained. Nanocomposite scintillators have been developed mainly to obtain high detection efficiency for high-energy photons such as X-rays and gamma-rays or thermal neutrons similar to the cases of loaded plastic scintillators. This discussion is complementary to recent review papers and several dedicated chapters of this book [Bertrand et al. in Chem Eur J 20(48), 15660 (2014); Hajagos et al. in Adv. Mater. 30:1706956, 2018; Koshimizu in Mater. Lett. 13:2030003, 2020] [1, 2, 3].

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Notes

  1. 1.

    Topological representation and key information of these molecules is given in the Appendix section at the end of the book.

References

  1. G.H.V. Bertrand, M. Hamel, F. Sguerra, Chem. Eur. J. 20(48), 15660 (2014)

    Google Scholar 

  2. T.J. Hajagos, C. Liu, N.J. Cherepy, Q. Pei, Adv. Mater. 30(27), 1706956 (2018)

    Article  Google Scholar 

  3. M. Koshimizu, Funct. Mater. Lett. 13(6), 2030003 (2020)

    Google Scholar 

  4. D. Pinto, L. Bernardo, A. Amaro, S. Lopes, Constr. Build. Mater. 95, 506 (2015)

    Article  Google Scholar 

  5. M. Sangermano, M. Messori, Macromol. Mater. Eng. 295(7), 603 (2010)

    Article  Google Scholar 

  6. B.P. Tripathi, V.K. Shahi, Prog. Polym. Sci. 36(7), 945 (2011)

    Article  Google Scholar 

  7. D.J. Kim, M.J. Jo, S.Y. Nam, J. Ind. Eng. Chem. 21, 36 (2015)

    Article  Google Scholar 

  8. L. Yue, J. Ma, J. Zhang, J. Zhao, S. Dong, Z. Liu, G. Cui, L. Chen, Energy Storage Mater. 5, 139 (2016)

    Article  ADS  Google Scholar 

  9. P. Sengodu, A.D. Deshmukh, RSC Adv. 5(52), 42109 (2015)

    Article  ADS  Google Scholar 

  10. Q. Wang, L. Zhu, J. Polym. Sci., Part B: Polym. Phys. 49(20), 1421 (2011)

    Google Scholar 

  11. A. Kaushik, R. Kumar, S.K. Arya, M. Nair, B.D. Malhotra, S. Bhansali, Chem. Rev. 115(11), 4571 (2015)

    Article  Google Scholar 

  12. G. Zhao, X. Huang, Z. Tang, Q. Huang, F. Niu, X. Wang, Polym. Chem. 9, 3562 (2018)

    Article  Google Scholar 

  13. C. Su, J. Hazard. Mater. 322(A), 48 (2017)

    Google Scholar 

  14. J. Tang, Y. Chen, S.R. McCuskey, L. Chen, G.C. Bazan, Z. Liang, Adv. Electron. Mater. 5(11), 1800943 (2019)

    Article  Google Scholar 

  15. T.-P. Nguyen, Surf. Coat. Technol. 206(4), 742 (2011)

    Article  Google Scholar 

  16. L. Zhao, Z. Lin, Adv. Mater. 24(32), 4353 (2012)

    Article  Google Scholar 

  17. R. Liu, Materials 7(4), 2747 (2014)

    Article  ADS  Google Scholar 

  18. S. Singh, H. Chen, S. Shahrokhi, L.P. Wang, C.-H. Lin, L. Hu, X. Guan, A. Tricoli, Z.J. Xu, T. Wu, ACS Energy Lett. 5(5), 1487 (2020)

    Article  ADS  Google Scholar 

  19. C. Lü, B. Yang, J. Mater. Chem. 19, 2884 (2009)

    Article  Google Scholar 

  20. Y. Tomita, E. Hata, K. Momose, S. Takayama, X. Liu, K. Chikama, J. Klepp, C. Pruner, M. Fally, J. Mod. Opt. 63(S3), S1 (2016)

    Article  ADS  Google Scholar 

  21. C. Sanchez, G.J. de A.A. Soler-Illia, F. Ribot, T. Lalot, C.R. Mayer, V. Cabuil, Chem. Mater. 13(10), 3061 (2001)

    Google Scholar 

  22. C. Sanchez, B. Julián, P. Belleville, M. Popall, J. Mater. Chem. 15(35–36), 3559 (2005)

    Article  Google Scholar 

  23. P.W. de Oliveira, C. Becker-Willinger, M.H. Jilavi, Adv. Eng. Mater. 12(5), 349 (2010)

    Article  Google Scholar 

  24. M.A. Hood, M. Mari, R. Muñoz-Espí, Materials 7(5), 4057 (2014)

    Article  ADS  Google Scholar 

  25. S. Kango, S. Kalia, A. Celli, J. Njuguna, Y. Habibi, R. Kumar, Prog. Polym. Sci. 38(8), 1232 (2013)

    Google Scholar 

  26. J. Jung, M. Chang, H. Yoon, Appl. Sci. 8(8), 1376 (2018)

    Article  Google Scholar 

  27. Y. Li, T.M. Krentz, L. Wang, B.C. Benicewicz, L.S. Schadler, A.C.S. Appl, Mater. Interfaces 6(9), 6005 (2014)

    Article  Google Scholar 

  28. M.A. Boles, D. Ling, T. Hyeon, D.V. Talapin, Nat. Mater. 15, 141 (2016)

    Article  ADS  Google Scholar 

  29. M.J. Owen, in Adhesion Science and Engineering, ed. by D.A. Dillard, A.V. Pocius, M. Chaudhury (Elsevier, 2002) pp. 403–431

    Google Scholar 

  30. M.Z. Rong, M.Q. Zhang, Y.X. Zheng, H.M. Zeng, R. Walter, K. Friedrich, Polymer 42(1), 167 (2001)

    Article  Google Scholar 

  31. T. Adschiri, Chem. Lett. 36, 1188 (2007)

    Article  Google Scholar 

  32. C.B. Murray, C.R. Kagan, M.G. Bawendi, Annu. Rev. Mater. Sci. 30, 545 (2000)

    Article  ADS  Google Scholar 

  33. H.C. van de Hulst, Light Scattering by Small Particles (Dover Publications, New York, 1981).

    Google Scholar 

  34. H. Althues, J. Henle, S. Kaskel, Chem. Soc. Rev. 36(9), 1454 (2007)

    Article  Google Scholar 

  35. G.D. Scholes, G. Rumbles, Nat. Mater. 5, 683 (2006)

    Article  ADS  Google Scholar 

  36. A.M. Smith, S. Nie, Acc. Chem. Res. 43(2), 190 (2010)

    Article  Google Scholar 

  37. K. Tomanová, V. Čuba, M.G. Brik, E. Mihóková, R.M. Turtos, P. Lecoq, F. Auffray, M. Nikl, APL Mater. 7(1), 011104 (2019)

    Article  ADS  Google Scholar 

  38. M. Hamel, F. Carrel, in New Insights on Gamma Rays, ed. by A.M. Maghraby (InTech, 2017), pp. 47–66

    Google Scholar 

  39. M. Koshimizu, in Handbook of Sol-Gel Science and Technology, ed. by L. Klein, M. Aparicio, A. Jitianu (Springer, Cham, 2016), pp. 2273–2300

    Google Scholar 

  40. Y. Sun, M. Koshimizu, N. Yahaba, F. Nishikido, S. Kishimoto, R. Haruki, K. Asai, Appl. Phys. Lett. 104(17), 174104 (2014)

    Article  ADS  Google Scholar 

  41. K. Kagami, M. Koshimizu, Y. Fujimoto, S. Kishimoto, R. Haruki, F. Nishikido, K. Asai, J. Mater. Sci.: Mater. Electron. 31, 896 (2020)

    Google Scholar 

  42. M. Koshimizu, H. Kitajima, T. Iwai, K. Asai, Jpn. J. Appl. Phys. 47(7R), 5717 (2008)

    Article  ADS  Google Scholar 

  43. F. Hiyama, T. Noguchi, M. Koshimizu, S. Kishimoto, R. Haruki, F. Nishikido, T. Yanagida, Y. Fujimoto, T. Aida, S. Takami, T. Adschiri, K. Asai, Jpn. J. Appl. Phys. 57(1), 012601 (2018)

    Article  ADS  Google Scholar 

  44. F. Hiyama, T. Noguchi, M. Koshimizu, S. Kishimoto, R. Haruki, F. Nishikido, Y. Fujimoto, T. Aida, S. Takami, T. Adschiri, K. Asai, Jpn. J. Appl. Phys. 57(5), 052203 (2018)

    Article  ADS  Google Scholar 

  45. A. Toda, S. Kishimoto, IEEE Trans. Nucl. Sci. 67(6), 983 (2020)

    Article  ADS  Google Scholar 

  46. Y. Araya, M. Koshimizu, R. Haruki, F. Nishikido, S. Kishimoto, K. Asai, Sens. Mater. 27, 255 (2015)

    Google Scholar 

  47. W. Cai, Q. Chen, N. Cherepy, A. Dooraghi, D. Kishpaugh, A. Chatziioannou, S. Payne, W. Xiang, Q. Pei, J. Mater. Chem. C 1(10), 1970 (2013)

    Article  Google Scholar 

  48. Y. Jin, D. Kishpaugh, C. Liu, T.J. Hajagos, Q. Chen, L. Li, Y. Chen, Q. Pei, J. Mater. Chem. C 4(16), 3654 (2016)

    Article  Google Scholar 

  49. C. Liu, T.J. Hajagos, D. Kishpaugh, Y. Jin, W. Hu, Q. Chen, Q. Pei, Adv. Funct. Mater. 25(29), 4607 (2015)

    Article  Google Scholar 

  50. U.U. Sytnik, O.V. Svidlo, P.N. Zhmurin, Funct. Mater. 20, 243 (2013)

    Article  Google Scholar 

  51. O.V. Svidlo, P.N. Zhmurin, Y.A. Gurkalenko, Funct. Mater. 21, 414 (2014)

    Article  Google Scholar 

  52. S.M. Carturan, T. Marchi, G. Maggioni, F. Gramegna, M. Degerlier, M. Cinausero, M. Dalla Palma, A. Quaranta, J. Phys. Conf. Ser. 620, 012010 (2015)

    Google Scholar 

  53. S.M. Carturan, M. Degerlier, G. Maggioni, T. Marchi, F. Gramegna, M. Cinausero, L. Stevanato, M. Vesco, A. Quaranta, Acta Phys. Pol., A 134, 405 (2018)

    Google Scholar 

  54. S.M. Carturan, M. Vesco, I. Bonesso, A. Quaranta, G. Maggioni, L. Stevanato, E. Zanazzi, T. Marchi, D. Fabris, M. Cinausero, F. Pino, F. Gramegna, Nucl. Instr. Methods A 925, 109 (2019)

    Article  ADS  Google Scholar 

  55. C. Frangville, A. Grabowski, J. Dumazert, E. Montbarbon, C. Lynde, R. Coulon, A. Venerosy, G.H.V. Bertrand, M. Hamel, Mater. Chem. Front. 3, 1574 (2019)

    Article  Google Scholar 

  56. C. Frangville, A. Grabowski, J. Dumazert, E. Montbarbon, C. Lynde, R. Coulon, A. Venerosy, G.H.V. Bertrand, M. Hamel, Nucl. Instr. Methods A 942, 162370 (2019)

    Article  Google Scholar 

  57. N.L. Karavaeva, N.Z. Galunov, E.V. Martynenko, A.V. Kosinova, Funct. Mater. 17, 549 (2010)

    Google Scholar 

  58. N.Z. Galunov, B.V. Grinyov, N.L. Karavaeva, Y.V. Gerasymov, O.T. Sidletskiy, O.A. Tarasenko, IEEE Trans. Nucl. Sci. 58(1), 339 (2011)

    Article  ADS  Google Scholar 

  59. A.Y. Boyarintsev, N.Z. Galunov, I.V. Gerasymov, N.L. Karavaeva, A.V. Krech, L.G. Levchuk, V.F. Popov, O.T. Sidletskiy, P.V. Sorokin, O.A. Tarasenko, Nucl. Instr. Methods A 841, 124 (2017)

    Article  ADS  Google Scholar 

  60. S.K. Gupta, J.P. Zuniga, M. Abdou, P.S. Ghosh, Y. Mao, Inorg. Chem. Front. 7(2), 505 (2020)

    Article  Google Scholar 

  61. P.M. Martins, P. Martins, V. Correia, J.G. Rocha, S. Lanceros-Mendez, J. Electron. Mater. 44, 129 (2015)

    Article  ADS  Google Scholar 

  62. J. Oliveira, P.M. Martins, P. Martins, V. Correia, J.G. Rocha, S. Lanceros-Mendez, Appl. Phys. A 121, 581 (2015)

    Article  ADS  Google Scholar 

  63. J. Oliveira, P.M. Martins, P. Martins, V. Correia, J.G. Rocha, S. Lanceros-Mendez, Composites. Part B. 91, 610 (2016)

    Article  Google Scholar 

  64. H. Ziluei, R. Azimirad, M.M. Larijani, F. Ziaie, Nucl. Instr. Methods A 852, 85 (2017)

    Article  ADS  Google Scholar 

  65. S.M.V. Novais, T.J. Monteiro, V.C. Teixeira, M.A. Gomes, M.E.G. Valerio, Z.S. Macedo, L.B. Barbosa, J. Lumin. 199, 225 (2018)

    Article  Google Scholar 

  66. S. Sen, M. Tyagi, K. Sharma, P.S. Sarkar, S. Sarkar, C.B. Basak, S. Pitale, M. Ghosh, S.C. Gadkari, A.C.S. Appl, Mater. Interfaces 9(42), 37310 (2017)

    Article  Google Scholar 

  67. M.S.E. Hamroun, K. Bachari, L. Guerbous, A. Berrayah, L. Mechernene, Optik 187, 111 (2019)

    Article  ADS  Google Scholar 

  68. R.K. Feller, G.M. Purdy, D. Ortiz-Acosta, S. Stange, A. Li, E.A. McKigney, E.I. Esch, R.E. Muenchausen, R. Gilbertson, M. Bacrania, B.L. Bennett, K.C. Ott, L. Brown, C.S. Macomber, B.L. Scott, R.E. Del Sesto, J. Mater. Chem. 21(15), 5716 (2011)

    Article  Google Scholar 

  69. H. Burešová, L. Procházková, R.M. Turtos, V. Jarý, E. Mihóková, A. Beitlerová, R. Pjatkan, S. Gundacker, E. Auffray, P. Lecoq, M. Nikl, V. Čuba, Opt. Exp. 24(14), 15289 (2016)

    Article  ADS  Google Scholar 

  70. S. Alamdari, M.J. Tafreshi, M.S. Ghamsari, Appl. Phys. A 125, 450 (2019)

    Article  ADS  Google Scholar 

  71. T.M. Demkiv, O.O. Halyatkin, V.V. Vistovskyy, V.B. Hevyk, P.M. Yakibchuk, A.V. Gektin, A.S. Voloshinovskii, Nucl. Instr. Methods A. 847, 47 (2017)

    Article  ADS  Google Scholar 

  72. S. Sahi, W. Chen, K. Jiang, J. Lumin. 159, 105 (2015)

    Article  Google Scholar 

  73. T.M. Demkiv, V.V. Vistovskyy, O.O. Halyatkin, T. Malyi, P.M. Yakibchuk, A.V. Gektin, A.S. Voloshinovskii, Nucl. Instr. Methods A. 908, 309 (2018)

    Article  ADS  Google Scholar 

  74. T.M. Demkiv, O.O. Halyatkin, V.V. Vistovskyy, A.V. Gektin, A.S. Voloshinovskii, Nucl. Instr. Methods A 810, 1 (2016)

    Article  ADS  Google Scholar 

  75. T.M. Demkiv, O.O. Halyatkin, V.V. Vistovskyy, A.V. Gektin, A.S. Voloshinovskii, J. Appl. Phys. 120(14), 144301 (2016)

    Article  ADS  Google Scholar 

  76. W.G. Lawrence, S. Thacker, S. Palamakumbura, K.J. Riley, V.V. Nagarkar, IEEE Trans. Nucl. Sci. 59(1), 215 (2012)

    Article  ADS  Google Scholar 

  77. A.K. Tam, O. Boyraz, J. Unangst, P. Nazareta, M. Schreuder, M. Nilsson, Rad. Meas. 111, 27 (2018)

    Article  Google Scholar 

  78. Z. Kang, Y. Zhang, H. Menkara, B.K. Wagner, C.J. Summers, W. Lawrence, V. Nagarkar, Appl. Phys. Lett. 98, 181914 (2011)

    Article  ADS  Google Scholar 

  79. C.L. Wang, L. Gou, J.M. Zaleski, D.L. Friesel, Nucl. Instr. Methods A 622(1), 186 (2010)

    Article  ADS  Google Scholar 

  80. J.M. Park, H.J. Kim, Y.S. Hwang, D.H. Kim, H.W. Park, J. Lumin. 146, 157 (2014)

    Article  Google Scholar 

  81. C. Liu, Z. Li, T.J. Hajagos, D. Kishpaugh, D.Y. Chen, Q. Pei, ACS Nano 11(6), 6422 (2017)

    Article  Google Scholar 

  82. I.H. Campbell, B.K. Crone, Adv. Mater. 18, 77 (2006)

    Article  Google Scholar 

  83. S.E. Létant, T.-F. Wang, Nano Lett. 6, 2877 (2006)

    Article  ADS  Google Scholar 

  84. M. Gandini, I. Villa, M. Beretta, C. Gotti, M. Imran, F. Carulli, E. Fantuzzi, M. Sassi, M. Zaffalon, C. Brofferio, L. Manna, L. Beverina, A. Vedda, M. Fasoli, L. Gironi, S. Brovelli, Nat. Nanotechnol. 15, 462 (2020)

    Article  ADS  Google Scholar 

  85. K.J. Wilson, R. Alabd, M. Abolhasan, M. Safavi-Naeini, D.R. Franklin, Sci. Rep. 10, 1409 (2020)

    Article  ADS  Google Scholar 

  86. V.N. Bliznyuk, A.F. Seliman, S.M. Husson, Y.M. Lvov, T.A. DeVol, Macromol. Mater. Eng. 303, 1700651 (2018)

    Article  Google Scholar 

  87. T. Chiba, J. Kido, J. Mater. Chem. C 6(44), 11868 (2018)

    Article  Google Scholar 

  88. B. Liu, Q. Wu, Z. Zhu, C. Cheng, M. Gu, J. Xu, H. Chen, J. Liu, L. Chen, Z. Zhang, X. Ouyang, Appl. Phys. Lett. 111(8), 081904 (2017)

    Article  ADS  Google Scholar 

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Acknowledgements

This research was supported by a Grant-in-Aid for Development of Systems and Technology for Advanced Measurement and Analysis from the Japan Science and Technology Agency, Grant-in-Aid for Young Scientists (A) (No. 25709088, 2013–2015), a Grant-in-Aid for Scientific Research (A) (No. 18H03890, 2018–2021), and grants from The Kazuchika Okura Memorial Foundation and Nippon Sheet Glass Foundation for Materials Science and Engineering. A part of this research is based on the Cooperative Research Project of the Research Center for Biomedical Engineering, Ministry of Education, Culture, Sports, Science, and Technology.

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Koshimizu, M. (2021). Composite Scintillators. In: Hamel, M. (eds) Plastic Scintillators. Topics in Applied Physics, vol 140. Springer, Cham. https://doi.org/10.1007/978-3-030-73488-6_6

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