Abstract
This chapter provides an introduction to the Coulomb phase of spin ice. After reviewing conventional notions of order and disorder, as well as the emergence of quasiparticles, we show how spin ice is special in that it exhibits an emergent gauge field with fractionalised excitations in the form of magnetic monopoles. This is a property of a topological magnetic phase, a Coulomb phase of the corresponding emergent gauge theory, which even harbours irrational magnetic charge and observable ‘Dirac strings’. We provide a broad overview of unusual and novel phenomena arising in spin ice, including the notion of residual entropy, the possibility of generating dimensional reduction to kagome ice via application of a magnetic field, the role of disorder, magnetoelectric phenomena, and various unusual phase transitions.
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References
P.M. Chaikin, T.C. Lubensky, J. Stat. Phys. 83, 1263 (1996). https://doi.org/10.1007/BF02179565
F. Wegner, J. Math. Phys. 12, 2259 (1971). https://doi.org/10.1063/1.1665530
P.W. Anderson, Science 177, 393 (1972). https://doi.org/10.1126/science.177.4047.393
P.W. Anderson, Mater. Res. Bull. 8, 153–160 (1973). https://doi.org/10.1016/0025-5408(73)90167-0
P.W. Anderson, Phys. Rev. 102, 1008–1013 (1956). https://doi.org/10.1103/PhysRev.102.1008
J.F. Nagle, J. Math. Phys. 7, 1484 (1966). https://doi.org/10.1063/1.1705058
S.V. Isakov, K.S. Raman, R. Moessner, S.L. Sondhi, Phy. Rev. B 70, 104418 (2004). https://doi.org/10.1103/PhysRevB.70.104418
H.W.J. Blote, R.F. Wielinga, W.J. Huiskamp, Physica 43, 549 (1969). https://doi.org/10.1016/0031-8914(69)90187-6
A.P. Ramirez, A. Hayashi, R.J. Cava, R. Siddharthan, B.S. Shastry, Nature 399, 333–335 (1999). https://doi.org/10.1038/20619
M.B. Geilikman, Zh. Eksp. Teor. Fiz. 66, 1166 (1974); or Sov. Phys. J. Exp. Theor. Phys. 39, 570 (1974). http://www.jetp.ac.ru/cgi-bin/e/index/e/39/3/p570?a=list
J. Stephenson, J. Math. Phys. 11, 420 (1970). https://doi.org/10.1063/1.1665155
L.D.C. Jaubert, M. Haque, R. Moessner, Phys. Rev. Lett. 107, 177202 (2011). https://doi.org/10.1103/PhysRevLett.107.177202
S.V. Isakov, K. Gregor, R. Moessner, S.L. Sondhi, Phys. Rev. Lett. 93, 167204 (2004). https://doi.org/10.1103/PhysRevLett.93.167204
M. Hermele, M.P.A. Fisher, L. Balents, Phys. Rev. B 69, 064404 (2004). https://doi.org/10.1103/PhysRevB.69.064404
D.J.P. Morris, D.A. Tennant, S.A. Grigera, B. Klemke, C. Castelnovo, R. Moessner, C. Czternasty, M. Meissner, K.C. Rule, J.-U. Hoffmann, K. Kiefer, S. Gerischer, D. Slobinsky, R.S. Perry, Science 326, 411 (2009). https://doi.org/10.1126/science.1178868
T. Fennell, P.P. Deen, A.R. Wildes, K. Schmalzl, D. Prabhakaran, A.T. Boothroyd, R.J. Aldus, D.F. McMorrow, S.T. Bramwell, Science 326, 415 (2009). https://doi.org/10.1126/science.1177582
M. Brooks-Bartlett, S.T. Banks, L.D.C. Jaubert, A. Harman-Clarke, P.C.W. Holdsworth, Phys. Rev. X 4, 011007 (2014). https://doi.org/10.1103/PhysRevX.4.011007
H. Kadowaki, N. Doi, Y. Aoki, Y. Tabata, T.J. Sato, J.W. Lynn, K. Matsuhira, Z. Hiroi, J. Phys. Soc. Jpn. 78, 103706 (2009). https://doi.org/10.1143/JPSJ.78.103706
R. Siddharthan, B.S. Shastry, A.P. Ramirez, A. Hayashi, R.J. Cava, S. Rosenkranz, Phys. Rev. Lett. 83, 1854 (1999). https://doi.org/10.1103/PhysRevLett.83.1854
B.C. den Hertog, M.J.P. Gingras, Phys. Rev. Lett. 84, 3430 (2000). https://doi.org/10.1103/PhysRevLett.84.3430
M.J.P. Gingras, B.C. den Hertog, Can. J. Phys. 79, 1339 (2001). https://doi.org/10.1139/p01-099
D.L. Bergman, C. Wu, L. Balents, Phys. Rev. B 78, 125104 (2008). https://doi.org/10.1103/PhysRevB.78.125104
S.V. Isakov, R. Moessner, S.L. Sondhi, Phys. Rev. Lett. 95, 217201 (2005). https://doi.org/10.1103/PhysRevLett.95.217201
T. Neupert, L. Santos, C. Chamon, C. Mudry, Phys. Rev. Lett. 106, 236804 (2011). https://doi.org/10.1103/PhysRevLett.106.236804
E. Tang, J.-W. Mei, X.-G. Wen, Phys. Rev. Lett. 106, 236802 (2011). https://doi.org/10.1103/PhysRevLett.106.236802
K. Sun, Z. Gu, H. Katsura, S. Das Sarma, Phys. Rev. Lett. 106, 236803 (2011). https://doi.org/10.1103/PhysRevLett.106.236803
C. Castelnovo, R. Moessner, S.L. Sondhi, Nature 451, 42 (2008). https://doi.org/10.1038/nature06433
D. Pomaranski, L.R. Yaraskavitch, S. Meng, K.A. Ross, H.M.L. Noad, H.A. Dabkowska, B.D. Gaulin, J.B. Kycia, Nat. Phys. 9, 353 (2013). https://doi.org/10.1038/NPHYS2591
R. Moessner, S.L. Sondhi, Phys. Rev. Lett. 105, 166401 (2010). https://doi.org/10.1103/PhysRevLett.105.166401
J.F. Nagle, Chem. Phys. 43, 317 (1979). https://doi.org/10.1016/0301-0104(79)85200-3
P.A.M. Dirac, Proc. R. Soc. Lond. A 133, 60–72 (1931). https://doi.org/10.1098/rspa.1931.0130
K. Matsuhira, Z. Hiroi, T. Tayama, S. Takagi, T. Sakakibara, J. Phys.: Condens. Matter 14, L559–L565 (2002). https://doi.org/10.1088/0953-8984/14/29/101
L.D.C. Jaubert, P.C.W. Holdsworth, Nat. Phys. 5, 258 (2009). https://doi.org/10.1038/NPHYS1227
C. Castelnovo, R. Moessner, S.L. Sondhi, Phys. Rev. B 84, 144435 (2011). https://doi.org/10.1103/PhysRevB.84.144435
S.T. Bramwell, J. Phys.: Condens. Matter 23, 112201 (2011). https://doi.org/10.1088/0953-8984/23/11/112201
L. Onsager, J. Chem. Phys. 2, 599–615 (1934). https://doi.org/10.1063/1.1749541
S.T. Bramwell, S.R. Giblin, S. Calder, R. Aldus, D. Prabhakaran, T. Fennell, Nature 461, 956 (2009). https://doi.org/10.1038/nature08500
V. Kaiser, S.T. Bramwell, P.C.W. Holdsworth, R. Moessner, Phys. Rev. Lett. 115, 037201 (2015). https://doi.org/10.1103/PhysRevLett.115.037201
D.I. Khomskii, Nat. Commun. 3, 904 (2012). https://doi.org/10.1038/ncomms1904
H. Katsura, N. Nagaosa, A.V. Balatsky, Phys. Rev. Lett. 95, 057205 (2005). https://doi.org/10.1103/PhysRevLett.95.057205
I.A. Sergienko, E. Dagotto, Phys. Rev. B 73, 094434 (2006). https://doi.org/10.1103/PhysRevB.73.094434
M. Mostovoy, Phys. Rev. Lett. 96, 067601 (2006). https://doi.org/10.1103/PhysRevLett.96.067601
A. Sarkar, S. Mukhopadhyay, Phys. Rev. B 90, 165129 (2014). https://doi.org/10.1103/PhysRevB.90.165129
I.V. Aleksandrov, B.V. Lidsky, L.G. Mamsurova, M.G. Neigauz, K.S. Pigal’skii, K.K. Pukhov, N.G. Trusevich, L.G. Shcherbakova, J. Exp. Theor. Phys. 62, 1287 (1985). https://www.jetp.ac.ru/cgi-bin/e/index/e/62/6/p1287?a=list
L.G. Mamsurova, K.S. Pigal’skii, K.K. Pukhov, J. Exp. Theor. Phys. Lett. 43, 755 (1986). https://www.jetpletters.ac.ru/ps/1413/article_21511.shtml
J.P.C. Ruff, Z. Islam, J.P. Clancy, K.A. Ross, H. Nojiri, Y.H. Matsuda, H.A. Dabkowska, A.D. Dabkowski, B.D. Gaulin, Phys. Rev. Lett. 105, 077203 (2010). https://doi.org/10.1103/PhysRevLett.105.077203
T. Fennell, M. Kenzelmann, B. Roessli, H. Mutka, J. Ollivier, M. Ruminy, U. Stuhr, O. Zaharko, L. Bovo, A. Cervellino, M.K. Haas, R.J. Cava, Phys. Rev. Lett. 112, 017203 (2014). https://doi.org/10.1103/PhysRevLett.112.017203
P. Bonville, A. Gukasov, I. Mirebeau, S. Petit, Phys. Rev. B 89, 085115 (2014). https://doi.org/10.1103/PhysRevB
M.J.P. Gingras, B.C. den Hertog, M. Faucher, J.S. Gardner, S.R. Dunsiger, L.J. Chang, B.D. Gaulin, N.P. Raju, J.E. Greedan, Phys. Rev. B 62, 6496 (2000). https://doi.org/10.1103/PhysRevB.89.085115
H. Cao, A. Gukasov, I. Mirebeau, P. Bonville, C. Decorse, G. Dhalenne, Phys. Rev. Lett. 103, 056402 (2009). https://doi.org/10.1103/PhysRevLett.103.056402
T. Fennell, M. Kenzelmann, B. Roessli, M.K. Haas, R.J. Cava, Phys. Rev. Lett. 109, 017201 (2012). https://doi.org/10.1103/PhysRevLett.109.017201
S. Petit, P. Bonville, J. Robert, C. Decorse, I. Mirebeau, Phys. Rev. B 86, 174403 (2012). https://doi.org/10.1103/PhysRevB.86.174403
L.D.C. Jaubert, R. Moessner, Phys. Rev. B 91, 214422 (2015). https://doi.org/10.1103/PhysRevB.91.214422
J.P.C. Ruff, B.D. Gaulin, K.C. Rule, J.S. Gardner, Phys. Rev. B 82, 100401 (2010). https://doi.org/10.1103/PhysRevB.82.100401
A.P. Sazonov, A. Gukasov, I. Mirebeau, P. Bonville, Phys. Rev. B 85, 214420 (2012). https://doi.org/10.1103/PhysRevB.85.214420
I.A. Ryzhkin, J. Exp. Theor. Phys. 101, 481–486 (2005). https://doi.org/10.1134/1.2103216
L.D.C. Jaubert, J.T. Chalker, P.C.W. Holdsworth, R. Moessner, Phys. Rev. Lett. 100, 067207 (2008). https://doi.org/10.1103/PhysRevLett.100.067207
L.D.C. Jaubert, J.T. Chalker, P.C.W. Holdsworth, R. Moessner, Phys. Rev. Lett. 105, 087201 (2010). https://doi.org/10.1103/PhysRevLett.105.087201
Y.-Z. Chou, Y.-J. Kao, Phys. Rev. B 82, 132403 (2010). https://doi.org/10.1103/PhysRevB.82.132403
S. Powell, J.T. Chalker, Phys. Rev. B 78, 024422 (2008). https://doi.org/10.1103/PhysRevB.78.024422
C.S.O. Yokoi, J.F. Nagle, S.R. Salinas, J. Stat. Phys. 44, 729 (1986). https://doi.org/10.1007/BF01011905
S. Powell, Phys. Rev. B 87, 064414 (2013). https://doi.org/10.1103/PhysRevB.87.064414
R. Moessner, Phys. Rev. B 57, R5587 (1998). https://doi.org/10.1103/PhysRevB.57.R5587
R. Moessner, S.L. Sondhi, Phys. Rev. B 68, 064411 (2003). https://doi.org/10.1103/PhysRevB.68.064411
M. Udagawa, M. Ogata, Z. Hiroi, J. Phys. Soc. Jpn. 71, 2365–2368 (2002). https://doi.org/10.1143/JPSJ.71.2365
A. Harman-Clarke, Ph.D. thesis, University College London and Ecole Normale Supérieure de Lyon (2011)
T. Sakakibara, T. Tayama, Z. Hiroi, K. Matsuhira, S. Takagi, Phys. Rev. Lett. 90, 207205 (2003). https://doi.org/10.1103/PhysRevLett.90.207205
G. Sala, M.J. Gutmann, D. Prabhakaran, D. Pomaranski, C. Mitchelitis, J.B. Kycia, D.G. Porter, C. Castelnovo, J.P. Goff, Nat. Mater. 13, 488–493 (2014). https://doi.org/10.1038/NMAT3924
X. Obradors, A. Labarta, A. Isalgué, J. Tejada, Solid State Comm. 65, 189 (1988). https://doi.org/10.1016/0038-1098(88)90885-X
A.P. Ramirez, Annu. Rev. Mater. Sci. 24, 453 (1994). https://doi.org/10.1146/annurev.ms.24.080194.002321
L. Limot, P. Mendels, G. Collin, C. Mondelli, B. Ouladdiaf, H. Mutka, N. Blanchard, M. Mekata, Phys. Rev. B 65, 144447 (2002). https://doi.org/10.1103/PhysRevB.65.144447
O. Cépas, B. Canals, Phys. Rev. B 86, 024434 (2012). https://doi.org/10.1103/PhysRevB.86.024434
G.C. Lau, R.S. Freitas, B.G. Ueland, B.D. Muegge, E.L. Duncan, P. Schiffer, R.J. Cava, Nat. Phys. 2, 249 (2006). https://doi.org/10.1038/nphys270
H.D. Zhou, C.R. Wiebe, Y.J. Jo, L. Balicas, Y. Qiu, J.R.D. Copley, G. Ehlers, P. Fouquet, J.S. Gardner, J. Phys.: Condens. Matter 19, 342201 (2007). https://doi.org/10.1088/0953-8984/19/34/342201
X. Ke, R.S. Freitas, B.G. Ueland, G.C. Lau, M.L. Dahlberg, R.J. Cava, R. Moessner, P. Schiffer, Phys. Rev. Lett. 99, 137203 (2007). https://doi.org/10.1103/PhysRevLett.99.137203
J. Snyder, J.S. Slusky, R.J. Cava, P. Schiffer, Phys. Rev. B 66, 064432 (2002). https://doi.org/10.1103/PhysRevB.66.064432
M. Kajnaková, M. Orendác, A. Orendácová, A. Vlcek, T. Fennell, S.T. Bramwell, J. Magn. Magn. Mater. 272–276, e989–991 (2004). https://doi.org/10.1016/j.jmmm.2003.12.702
G. Ehlers, J.S. Gardner, C.H. Booth, M. Daniel, K.C. Kam, A.K. Cheetham, D. Antonio, H.E. Brooks, A.L. Cornelius, S.T. Bramwell, J. Lago, W. Häussler, N. Rosov, Phys. Rev. B 73, 174429 (2006). https://doi.org/10.1103/PhysRevB.73.174429
T. Lin, X. Ke, M. Thesberg, P. Schiffer, R.G. Melko, M.J.P. Gingras, Phys. Rev. B 90, 214433 (2014). https://doi.org/10.1103/PhysRevB.90.214433
S. Scharffe, O. Breunig, V. Cho, P. Laschitzky, M. Valldor, J.F. Welter, T. Lorenz, Phys. Rev. B 92, 180405(R) (2015). https://doi.org/10.1103/PhysRevB.92.180405
A. Sen, R. Moessner, Phys. Rev. Lett. 114, 247207 (2015). https://doi.org/10.1103/PhysRevLett.114.247207
O. Petrova, R. Moessner, S.L. Sondhi, Phys. Rev. B 92, 100401(R) (2015). https://doi.org/10.1103/PhysRevB.92.100401
K. Kimura, S. Nakatsuji, J.-J. Wen, C. Broholm, M.B. Stone, E. Nishibori, H. Sawa, Nat. Commun. 4, 1934 (2013). https://doi.org/10.1038/ncomms2914
L. Pan, N.J. Laurita, K.A. Ross, B.D. Gaulin, N.P. Armitage, Nat. Phys. 12, 361 (2015). https://doi.org/10.1038/nphys3608
V.F. Petrenko, R.W. Whitworth, Physics of Ice (Oxford University Press, Oxford, 1999). ISBN 9780198518945
L. Pauling, J. Am. Chem. Soc. 57, 2680 (1935). https://doi.org/10.1021/ja01315a102
R. Youngblood, J.D. Axe, B.M. McCoy, Phys. Rev. B 21, 5212 (1980). https://doi.org/10.1103/PhysRevB.21.5212
D.A. Garanin, Benjamin Canals. Phys. Rev. B 59, 443 (1999). https://doi.org/10.1103/PhysRevB.59.443
S.V. Isakov, R. Moessner, S.L. Sondhi, D.A. Tennant, Phys. Rev. B 91, 245152 (2015). https://doi.org/10.1103/PhysRevB.91.245152
J.C. Li, V.M. Nield, D.K. Ross, R.W. Whitworth, C.C. Wilson, D.A. Keen, Philos. Mag. B 69, 1173 (1994). https://doi.org/10.1080/01418639408240187
R. Moessner, J.T. Chalker, Phys. Rev. B 58, 12049 (1998). https://doi.org/10.1103/PhysRevB.58.12049
A. Sen, R. Moessner, S.L. Sondhi, Phys. Rev. Lett. 110, 107202 (2013). https://doi.org/10.1103/PhysRevLett.110.107202
O. Benton, L.D.C. Jaubert, H. Yan, N. Shannon, Nat. Commun. 7, 11572 (2016). https://doi.org/10.1038/ncomms11572
R. Moessner, S.L. Sondhi, Phys. Rev. B 68, 184512 (2003). https://doi.org/10.1103/PhysRevB.68.184512
C. Nisoli, R. Moessner, P. Schiffer, Rev. Mod. Phys. 85, 1473 (2013). https://doi.org/10.1103/RevModPhys.85.1473
X. Wan, A. Turner, A. Vishwanath, S.Y. Savrasov, Phys. Rev. B 83, 205101 (2011). https://doi.org/10.1103/PhysRevB.83.205101
U.K. Rößler, A.N. Bogdanov, C. Pfleiderer, Nature 442, 797–801 (2006). https://doi.org/10.1038/nature05056
P. Milde, D. Köhler, J. Seidel, L.M. Eng, A. Bauer, A. Chacon, J. Kindervater, S. Mühlbauer, C. Pfleiderer, S. Buhrandt, C. Schütte, A. Rosch, Science 340, 1076 (2013). https://doi.org/10.1126/science.1234657
Acknowledgements
I am very grateful to my numerous collaborators in the work discussed here. It is almost impossible to single out any individuals here, but it was with Claudio Castelnovo, Sergei Isakov and Shivaji Sondhi that much of the conceptual framework presented here was developed. I am also grateful to the editors of this volume, Ludovic Jaubert and Masafumi Udagawa, for much encouragement, support and patience. I also thank the former, along with Peter Holdsworth, for help with the figures, and Maximilian Schulz for comments on the manuscript.
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Moessner, R. (2021). Spin Ice As a Coulomb Liquid: From Emergent Gauge Fields to Magnetic Monopoles. In: Udagawa, M., Jaubert, L. (eds) Spin Ice. Springer Series in Solid-State Sciences, vol 197. Springer, Cham. https://doi.org/10.1007/978-3-030-70860-3_3
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