Abstract
A critical evaluation of the newly developed analytical methods, as well as a comparison of them with those previously published, is unambiguously the important job of every researcher. Methods are mainly compared in terms of validation criteria and greenness of the process, yet there is a need to introduce a comprehensive protocol, which takes into account the method performance, compliance with green chemistry rules, and productivity. The recently developed RGB model provides an easy-to-use algorithm to fill this gap and evaluate the method in three colors: red (R) assigned to the analytical effectiveness of the method expressed by validation criteria, green (G) to safety and environmental friendliness, and blue (B) to practical effectiveness and productivity. Moreover, the method brilliance (MB) was introduced to facilitate the overall characterization of the method. This chapter provides the necessary theoretical background and examples explaining how to use the RGB model, based on the comparison of selected bioanalytical methods using high-performance liquid chromatography and capillary electrophoresis.
References
Bystrzanowska, M., & Tobiszewski, M. (2018). How can analysts use multicriteria decision analysis? TrAC Trends in Analytical Chemistry, 105, 98–105.
Gałuszka, A., Migaszewski, Z. M., Konieczka, P., & Namieśnik, J. (2012). Analytical eco-scale for assessing the greenness of analytical procedures. TrAC Trends in Analytical Chemistry, 37, 61–72.
Gumustas, M., Caglayan, M. G., Onur, F., & Ozkan, S. A. (2018). Simultaneous determination and validation of emtricitabine, rilpivirine and tenofovir from biological samples using LC and CE methods. Biomedical Chromatography, 32, e4158.
ICH: Bioanalytical method validation M10, draft. https://www.ich.org/fileadmin/Public_Web_Site/ICH_Products/Guidelines/Multidisciplinary/M10/M10EWG_Step2_DraftGuideline_2019_0226.pdf. Accessed 7 Sept 2019.
Jędrkiewicz, R., Orłowski, A., Namieśnik, J., & Tobiszewski, M. (2016). Green analytical chemistry introduction to chloropropanols determination at no economic and analytical performance costs? Talanta, 147, 282–288.
Jędrkiewicz, R., Tsakovski, S., Lavenu, A., et al. (2018). Simultaneous grouping and ranking with combination of SOM and TOPSIS for selection of preferable analytical procedure for furan determination in food. Talanta, 178, 928–933.
Kadziński, M., Cinelli, M., Ciomek, K., et al. (2018). Co-constructive development of a green chemistry-based model for the assessment of nanoparticles synthesis. European Journal of Operational Research, 264, 472–490.
Kowalski, P., Marszałł, M., Olędzka, I., & Czarnowski, W. (2007). Comparative evaluation of CE and HPLC for determination of cotinine in human urine. Chromatographia, 66, 357–361.
Nowak, P. M., & Kościelniak, P. (2019). What color is your method? Adaptation of the RGB additive color model to analytical method evaluation. Analytical Chemistry, 91, 10343–10352.
Ramautar, R., Somsen, G. W., & de Jong, G. J. (2016). Developments in coupled solid-phase extraction-capillary electrophoresis 2013–2015. Electrophoresis, 37, 35–44.
Tobiszewski, M. (2016). Metrics for green analytical chemistry. Analytical Methods, 8, 2993–2999.
Tobiszewski, M., Marć, M., Gałuszka, A., et al. (2015). Green chemistry metrics with special reference to green analytical chemistry. Molecules, 20, 10928–10946.
Tobiszewski, M., Pena-Pereira, F., Orłowski, A., & Namieśnik, J. (2016). A standard analytical method as the common good and pollution abatement measure. TrAC Trends in Analytical Chemistry, 80, 321–327.
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Nowak, P.M., Woźniakiewicz, M., Kościelniak, P. (2022). Capillary Electrophoresis and High Performance Liquid Chromatography in the Context of Selected Bioanalytical Applications – a comparison using the RGB Color Model. In: Buszewski, B., Baranowska, I. (eds) Handbook of Bioanalytics. Springer, Cham. https://doi.org/10.1007/978-3-030-63957-0_38-1
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DOI: https://doi.org/10.1007/978-3-030-63957-0_38-1
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