Abstract
Some concerns regarding the depletion of non-renewable sources of energy along with the environmental damage resulting from their use have motivated the search for alternative fuels. Ethanol is a renewable and important energy alternative for Otto-cycle engines. In such context, this study proposes the evaluation of carbon monoxide (CO) and total hydrocarbons (THC) concentrations and the performance of a spark-ignited non-road engine fueled with gasoline types A and C (GC, with 27% ethanol) and kerosene as adulterant in different proportions. Quality parameters of the fuel blends were also evaluated. The results revealed some difficulties in the identification of gasoline adulteration, relating to the current legal parameters in the conditions of mixtures and tests used in the study. Regarding the gaseous emissions, the addition of the adulterant resulted in an increase of the CO and THC concentrations to 74% and 78%, respectively, in gasoline type C with 30% adulterant, when compared to gasoline C free of adulterant. The addition of ethanol to the gasoline resulted in a reduction of the CO and THC concentrations to 64% and 56%, respectively, in relation to the pure gasoline (without ethanol), evidencing greater combustion efficiency due to the presence of the oxygenated fuel (ethanol).
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References
ABNT—ASSOCIAÇÃO BRASILEIRA DE NORMAS TÉCNICAS. NBR ISO 8178-4 (2012) Motores alternativos de combustão interna—Medição da emissão de gases de exaustão. Parte 4: Ciclos de ensaio em regime constante para diferentes aplicações de motor. Rio de Janeiro: ABNT. https://www.abntcatalogo.com.br/norma.aspx?ID=090271. Accessed 25 Apr 2019
AGÊNCIA NACIONAL DO PETRÓLEO, GÁS NATURAL E BIOCOMBUSTÍVIEIS (2011) Cartilha do Posto Revendedor de Combustíveis. 5ª ed. Available in: https://www.larcopetroleo.com.br/wp-content/uploads/2013/10/cartilha_anp.pdf
AGÊNCIA NACIONAL DO PETRÓLEO, GÁS NATURAL E BIOCOMBUSTÍVIEIS (2013) Resolução ANP No 40. Available in http://www.anp.gov.br/legislacao/qualidade
AGÊNCIA NACIONAL DO PETRÓLEO, GÁS NATURAL E BIOCOMBUSTÍVIEIS (2016) Gasolina. Available in http://www.anp.gov.br/producao-de-derivados-de-petroleo-e-processamento-de-gas-natutal/producao-centrais-de-materias-primas-petroquimicas-cpq/gasolina
Andersen VF, Anderson JE, Wallington TJ, Mueller SA, Nielsen OJ (2010) Distillation curves for alcohol-gasoline blends. Energy Fuels 24(4):2683–2691. https://doi.org/10.1021/ef9014795
Babu V, Krishna R, Mani N Review on the detection of adulteration in fuels through computational techniques (2017) Mater Today Proc 4(2):1723–1729. https://doi.org/10.1016/j.matpr.2017.02.013
Barakat Y, Awad EN, Ibrahim V (2016) Fuel consumption of gasoline ethanol blends at different engine rotational speeds. Egypt J Petrol 25(3):309–315. https://doi.org/10.1016/j.ejpe.2015.07.019
Bielaczyc P, Woodburn J, Klimkiewicz D, Pajdowski P, Szczotka A (2013) An examination of the effect of ethanol–gasoline blends’ physicochemical properties on emissions from a light-duty spark ignition engine. Fuel Process Technol 107:50–63. https://doi.org/10.1016/j.fuproc.2012.07.030
Broustail G, Seers P, Halter F, Moréac G, Mounaim-Rousselle C (2011) Experimental determination of laminar burning velocity for butanol and ethanol iso-octane blends. Fuel 90(1):1–6. https://doi.org/10.1016/j.fuel.2010.09.021
Chang DY, Lopez I, Yocklovich SG (2008) Determination of kerosene and #2 diesel in soil by purge and trap versus extraction procedure. J Soil Contamination 1(3):239–251. https://doi.org/10.1080/15320389209383414
Channiwala SA, Parikh PP (2002) A unified correlation for estimating HHV of solid, liquid and gaseous fuel. Fuel 81(8):1051–1063. https://doi.org/10.1016/S0016-2361(01)00131-4
Costagliola MA, Prati MV, Florio S, Scorletti P, Terna D, Iodice P, Buono D, Senatore A (2016) Performances and emissions of a 4-stroke motorcycle fuelled with ethanol/gasoline blends. Fuel 183(1):470–477. https://doi.org/10.1016/j.fuel.2016.06.105
Dahadha AA, Talat N, Barakat S (2013) Study of the research octane number depression of domestic kerosene-doped automotive gasoline. Advances in Applied Science Research 4(4):129–134. ISSN: 0976–8610
Elfasakhany A (2015) Investigations on the effects of ethanol-methanol-gasoline blends in a spark-ignition engine: Performance and emissions analysis. Eng Sci Technol Int J 18(4):713–719. https://doi.org/10.1016/j.jestch.2015.05.003
Estatcamp. Software Action (2014) Consultoria em Estatística e Qualidade. São Carlos. Available in https://www.estatcamp.com.br/empresa/action-stat#in
Fonseca MM, Yoshida MI, Fortes ICP, Pasa VMD (2007) Thermogravimetric study of kerosene-doped gasoline. J Therm Anal Calorim 87(2):499–503. https://doi.org/10.1007/s10973-005-7457-2
García CA, Manzini F, Islas JM (2017) Sustainability assessment of ethanol production from two crops in Mexico. Renew Sustain Energy Rev 72:1199–1207. https://doi.org/10.1016/j.rser.2016.10.035
Gawande AP, Kaware JP (2013) Fuel adulteration consequences in India: a review. Sci Rev Chem Commun 3(3):161–171. Available in https://www.tsijournals.com/articles/fuel-adulteration-consequences-in-india--a-review.pdf
Gibbs L, Anderson B, Barnes K, Engeler G, Freel J, Horn J, Ingham M, Kohler D, Lesnini D, Macarthur R, Mortier M, Peyla D, Taniguchi B, Tiedemann A, Welstand S, Bernhardt D, Collini K, Farr A, Jones J, Lind J, Tom C (2009) Motor gasolines technical review. Chevron Corporation. Available in https://www.academia.edu/4857002/Motor_Gasolines_Technical_Review_Chevron_Products_Company_Motor_Gasolines_Technical_Review_Recycled_Recyclable_paper
Gravalos I, Moshou D, Gialamas Th, Xyradakis P, Kateris D, Tsiropoulos Z (2013) Emissions characteristics of spark ignition engine operating on lower-higher molecular mass alcohol blended gasoline fuels. Renew Energy 50:27–32. https://doi.org/10.1016/j.renene.2012.06.033
Gwilliam K, Kojima M, Johnson T (2004) Reducing air pollution from urban transport. Washington D.C. Available in https://documents.worldbank.org/curated/en/989711468328204490/pdf/304250PAPER0Reducing0air0pollution.pdf
Heywood JB (1988) Internal combustion engine fundamentals. McGraw Hill, 1st edn, 930p. ISBN 0-07-028637-X
Hsieh WD, Chen RH, Wu TL, Lin TH (2002) Engine performance and pollutant emission of an SI engine using ethanol–gasoline blended fuels. Atmos Environ 36(3):403–410. https://doi.org/10.1016/S1352-2310(01)00508-8
Kalligeros S, Zannikos F, Stournas S, Lois E (2003) Fuel adulteration issues in Greece. Energy 28(1):15–26. https://doi.org/10.1016/S0360-5442(02)00091-9
Koç M, Sekmen Y, Topgül T, Yücesu HS (2009) The effects of ethanol-unleaded gasoline blends on engine performance and exhaust emissions in a spark-ignition engine. Renew Energy 34(10):2101–2106. https://doi.org/10.1016/j.renene.2009.01.018
Lin WY, Chang YY, Hsieh YR (2010) Effect of ethanol-gasoline blends on small engine generator energy efficiency and exhaust emission. J Air Waste Manag Assoc 60(2):142–148. https://doi.org/10.3155/1047-3289.60.2.142
Masum BM, Masjuki HH, Kalam MA, Palash SM, Habibullah M (2015) Effect of alcohol-gasoline blends optimization on fuel properties, performance and emissions of a SI engine. J Clean Product 86(1):230–237. https://doi.org/10.1016/j.jclepro.2014.08.032
Napro (2018) Manual de operação, analisador de gases modelo 10.02/10J. Available in http://www.napro.com.br/analisadores.html
Nwufo OC, Nwaiwu CF, Ononogbo C, Igbokwe JO, Nwafor OMI, Anyanwu EE (2017) Performance, emission and combustion characteristics of a single cylinder spark ignition engine using ethanol–petrol-blended fuels. Int J Ambient Energy 39(8):792–801. https://doi.org/10.1080/01430750.2017.1354318
Obodeh O, Akhere NC (2010) Experimental study on the effects of kerosene-doped gasoline on gasoline-powered engine performance characteristics. J Petrol Gas Eng 1(2):37–40. Available in https://pdfs.semanticscholar.org/e177/bd80cee1e9c0323464305d2dc9f490d13736.pdf
Olanyk LZ (2013) Avaliação das emissões gasosas de um motor monocilindro ciclo Otto utilizando diferentes misturas de gasolina com etanol e adulterante. Universidade Estadual do Centro-Oeste, Guarapuava. Available in https://www.unicentro.br/posgraduacao/mestrado/bioenergia/dissertacoes/Disserta_o_Luciano_Zart_Olanyk_52448bfa35e4a.pdf
Olanyk LZ, Schirmer WN, Gueri MVD, Guedes CLB, Borsato D, Rodrigues PRP, Quessada TP, Oliveira DS (2014) Avaliação das emissões gasosas, parâmetros de qualidade e desempenho de consumo de um motor de combustão interna operando com misturas gasolina/adulterante em diferentes proporções. CIATEC 6(2):15–30. https://doi.org/10.5335/ciatec.v6i2.3814
Oliveira FS, Teixeira LSG, Araujo MCU, Korn M (2004) Screening analysis to detect adulterations in Brazilian gasoline samples using distillation curves. Fuel 83(7–8):917–923. https://doi.org/10.1016/j.fuel.2003.09.018
Ribeiro CB, Martins KG, Gueri MVD, Pavanello GP, Schirmer WN (2018) Effect of anhydrous ethanol/gasoline blends on performance and exhaust emissions of spark-ignited non-road engines. Environ Sci Pollut Res 25(24):24192–24200. https://doi.org/10.1007/s11356-018-2476-2
Schifter I, Diaz L, Gómez JP, Gonzalez U (2013) Combustion characterization in a single cylinder engine with mid-level hydrated ethanol–gasoline blended fuels. Fuel 103:292–298. https://doi.org/10.1016/j.fuel.2012.06.002
Schifter I, González U, Díaz L, Rodríguez R, Mejía-Centeno I, González-Macías C (2018) From actual ethanol contents in gasoline to mid-blends and E-85 in conventional technology vehicles. Emission control issues consequences. Fuel 219(1):239–247. https://doi.org/10.1016/j.fuel.2018.01.118
Schirmer WN, Olanyk LZ, Guedes CLB, Quessada TP, Ribeiro CB, Capanema MA (2017) Effects of air/fuel ratio on gas emissions in a small spark-ignited non-road engine operating with different gasoline/ethanol blends. Environ Sci Pollut Res 24(25):20354–20359. https://doi.org/10.1007/s11356-017-9651-8
Shoba, TT, Crua C, Heikal MR, Gold MR (2011) Optical characterisation of diesel, RME and kerosene sprays by microscopic imaging. In: European conference on liquid atomization and spray systems (ILASS), 24th. Estoril. Available in https://research.brighton.ac.uk/en/publications/optical-characterisation-of-diesel-rme-and-kerosene-sprays-by-mic
Silva R, Menezes EW, Cataluña R (2008) Rendimento térmico e emissões de contaminantes atmosféricos de gasolinas formuladas com etanol. MTBE E TAEE Química Nova 31(5):980–984. https://doi.org/10.1590/S0100-40422008000500007
Sinha SN, Shivgotra VK (2012) Environmental monitoring of adulterated gasoline with kerosene and their assessment at exhaust level. J Environ Biol 33:729–734. Available in https://www.jeb.co.in/journal_issues/201207_jul12/paper_09.pdf
Takeshita EV (2006) Adulteração de gasolina por adição de solventes: Análise dos parâmetros físico-químicos. Universidade Federal de Santa Catarina, Florianópolis. Available in https://repositorio.ufsc.br/bitstream/handle/123456789/89520/226279.pdf?sequence=1
Tharby R (2002) Catching gasoline and diesel adulteration. The World Bank. Urban air pollution: South Asia urban air quality management briefing note 7:4. Available in http://documents1.worldbank.org/curated/en/223591468164352248/pdf/multi0page.pdf
Toyama (2018) Geradores gasolina (31-1110—TG 2800CX). Available in https://www.toyama.com.br/?menu=produtos&produto=TG2800CX&cod=239
Turner D, Xu H, Cracknell RF, Natarajan V, Chen X (2011) Combustion performance of bio-ethanol at various blend ratios in a gasoline direct injection engine. Fuel 90(5):1999–2006. https://doi.org/10.1016/j.fuel.2010.12.025
Walter A (2009) Bio-ethanol development(s) in Brazil. In: Soetaert W, Vandamme EJ (eds) Biofuels. Wiley, pp 55–75. https://doi.org/10.1002/9780470754108.ch4
Wu CW, Chen RH, Pu JY, Lin TH (2004) The influence of air–fuel ratio on engine performance and pollutant emission of an SI engine using ethanol-gasoline-blended fuels. Atmos Environ 38(40):7093–7100. https://doi.org/10.1016/j.atmosenv.2004.01.058
Yao YC, Tsai JH, Wang IT (2013) Emissions of gaseous pollutant from motorcycle powered by ethanol–gasoline blend. Appl Energy 102:93–100. https://doi.org/10.1016/j.apenergy.2012.07.041
Acknowledgements
The authors are thankful to Conselho Nacional de Desenvolvimento Científico e Tecnológico (National Council for Scientific and Technological Development) (CNPq, regarding the Universal Call MCTI/CNPq no. 14/2014) for the financial support.
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Gauer, M.A., Ribeiro, C.B., Buratto, W.G., Schirmer, W.N. (2020). Evaluating Gaseous Emissions and Performance of a Spark-Ignited Non-road Engine Fueled with Gasoline, Ethanol and Adulterant Blends. In: Leal Filho, W., de Andrade Guerra, J.B.S. (eds) Water, Energy and Food Nexus in the Context of Strategies for Climate Change Mitigation. Climate Change Management. Springer, Cham. https://doi.org/10.1007/978-3-030-57235-8_2
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