Skip to main content
SpringerLink
Log in

Formation of Manganese-Containing PEO Coatings on Aluminum Alloys

  • Conference paper
  • First Online:
Nanomaterials and Nanocomposites, Nanostructure Surfaces, and Their Applications

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 246))

  • 488 Accesses

Abstract

This chapter introduces the investigation of Al alloys plasma electrolytic oxidizing (PEO) and analysis of process characteristics. The research directs to set regularity of electrochemical obtaining (forming or formation) of nanostructured coatings mono- and mixed oxides which are incorporated with transition metals namely manganese. It is shown that the alloys surface and bulk composition heterogeneity complicates the alloys processing to produce a uniform layer of oxides. Electrolytes containing K4P2O7 and KOH as the basic component were used to homogenize the outer surface layer of aluminum alloys and to form uniform conversion covers, predominantly oxides. PEO in these electrolytes in the range of current densities 5…20 A/dm2 allows obtaining mixed oxide coatings which contained both matrix and doping metal oxides. It was found that the rising of both the permanganate concentration in the electrolyte and current density of treatment allows to enrich the surface layer of the coatings with oxides. The X-ray analysis confirms the incorporation of MnOx into the matrix of aluminum oxide. The modes for PEO of aluminum alloys have been proposed for producing conversion coatings containing Mn up to 36 wt%. Mixed oxide covers exhibit a developed surface and increased catalytic properties and corrosion stability. The complex of functional properties determines the possibility of their usage as promising materials for emission control technologies and also in systems of ICE waste gas purification.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Heck RM, Farrauto RJ, Gulati ST (2009) Catalytic air pollution control: commercial technology. Wiley, p 544

    Google Scholar 

  2. Stiles AB (1987) Catalyst supports and supported catalysts: theoretical and applied concepts. Butterworth, Stoneham, MA

    Google Scholar 

  3. Yerokhin AL, Nie X, Leyland A, Matthews A, Dowey SJ (1999) Plasma electrolysis for surface engineering. Surface Coat Technol 122(2–3):73–93

    Article  Google Scholar 

  4. https://doi.org/10.1016/s0257-8972(99)00441-7

  5. Gupta P, Tenhundfeld G, Daigle EO, Ryabkov D (2007) Electrolytic plasma technology: science and engineering—an overview. Surf Coat Technol 201(21):8746–8760

    Article  Google Scholar 

  6. Rudnev VS, Lukiyanchuk IV, Vasilyeva MS, Medkov MA, Adigamova MV, Sergienko VI (2016) Aluminum- and titanium-supported plasma electrolytic multicomponent coatings with magnetic, catalytic, biocide or biocompatible properties. Surf Coat Technol 307(Part C):1219–1235

    Google Scholar 

  7. Rakoch AG, Khokhlov VV, Bautin VA, Lebedeva NA, Magurova YuV, Bardin IV (2006) Model concepts on the mechanism of microarc oxidation of metal materials and the control over this process. Prot Met 42(2):158–169

    Article  Google Scholar 

  8. Sakhnenko ND, Ved MV, Vestfrid YuV, Stepanova II (1996) Predicting the catalytic activity of metal oxide systems in treatment of exhaust gases to remove nitrogen oxides. Russ J Appl Chem 69(9):1346–1350

    Google Scholar 

  9. Sakhnenko N, Ved M, Karakurkchi A, Galak A. (2016) A study of synthesis and properties of manganese-containing oxide coatings on alloy VT1–0. East Eur J Enterpr Technol 3/5(81):37–43

    Google Scholar 

  10. Sakhnenko M, Karakurkchi A, Galak A, Menshov S, Matykin O (2017) Examining the formation and properties of TiO2 oxide coatings with metals of iron triad. East Eur J Enterpr Technol 2(11/86):4–10

    Google Scholar 

  11. Karakurkchi A, Sakhnenko M, Ved M, Galak A, Petrukhin S (2017) Application of oxide-metallic catalysts on valve metals for ecological catalysis. East Eur J Enterp Technol 5/10(89):12–18

    Google Scholar 

  12. Lukiyanchuk IV, Rudnev VS, Tyrina LM (2016) Plasma electrolytic oxide layers as promising systems for catalysis. Surf Coat Technol 307(Part C): 1183–1193

    Google Scholar 

  13. Md Jani AM, Losic D, Voelcker NH (2013) Nanoporous anodic aluminium oxide: Advances in surface engineering and emerging applications. Prog Mater Sci 58(5):636–704

    Article  Google Scholar 

  14. Sakhnenko ND, Ved’ MV, Androshchuk DS, Korniy SA. (2016) Formation of coatings of mixed aluminum and manganese oxides on the AL25 alloy. Surf Eng Appl Electrochem 52(2):145–151

    Google Scholar 

  15. Karakurkchi AV, Sakhnenko ND, Ved MV, Luhovskyi IS, Drobakha HA, Mayba MV (2019) Features of plasma electrolytic formation of manganese- and cobalt-containing composites on aluminum alloys. Adv Mater Sci Eng 19(Article ID 6381291)

    Google Scholar 

  16. Labardi M, Allegrini M, Salerno M, Fredriani C, Ascoli C (1994) Dynamical friction coefficient map using a scanning force and friction force microscope. Appl Phys 59

    Google Scholar 

  17. Arbizzani C, Borghini M, Mastragostino M, Meneghello L, Zanelli A (1994) Impedance spectroscopy in electrode/electrolyte interface investigations. Solid State Ionics 72(2):115–121

    Article  Google Scholar 

  18. Ved’ MV, Sakhnenko ND, Karakurkchi AV, Myrna TYu (2017) Functional mixed cobalt and aluminum oxide coatings for environmental safety. Funct Mater 24(2):303–310

    Google Scholar 

  19. Glazoff MV, Zolotorevsky VS, Belov NA (2007) Casting aluminum alloys. Elsiever, Oxford, p 544

    Google Scholar 

  20. Davis JR (1993) ASM specialty handbook: aluminum and aluminum alloys. ASM International, Cleveland, OH

    Google Scholar 

  21. Dong H. (2010) Surface engineering of light alloys: aluminium, magnesium and titanium alloys. Elsevier, p 680

    Google Scholar 

  22. Egorkin VS, Vyaliy IE, Sinebryukhov SL, Gnedenkov SV (2017) Composition, morphology and tribological properties of PEO-coatings formed on an aluminum alloy D16 at different duty cycles of the polarizing signal. Non-ferrous Met 42(1):12–16

    Article  Google Scholar 

  23. Sakhnenko ND, Ved MV, Karakurkchi AV (2017) Nanoscale oxide PEO coatings forming from diphosphate electrolytes. In: Fesenko O, Yatsenko L (eds) Nanophysics, nanomaterials, interface studies, and applications. In: NANO 2016, Proceedings in physics, vol 195. Springer, pp 159–184

    Google Scholar 

  24. Boguta DL, Rudnev VS, Yarovaya TP, Kaidalova TA, Gordienko PS (2002) On composition of anodic-spark coatings formed on aluminum alloys in electrolytes with polyphosphate complexes of metals. Russ J Appl Chem 75(10):1605–1608

    Article  Google Scholar 

  25. Ayday A, Durman M (2015) Growth characteristics of plasma electrolytic oxidation coatings on aluminum alloys. Acta Physic Polon A 127(4):886–887

    Article  ADS  Google Scholar 

  26. Ponomarev IS, Krivonosova EA, Gorchakov AI (2015) Investigation of discharge dynamics in microarc oxidation of D16 aluminium alloy. Weld Intern 30(3):244–246

    Article  Google Scholar 

  27. Rudnev VS, Vasilyeva MS, Kondrikov NB, Tyrina LM (2005) Plasma-electrolytic formation, composition and catalytic activity of manganese oxide containing structures on titanium. Appl Surf Sci 252(5):1211–1220

    Article  ADS  Google Scholar 

  28. Sakhnenko ND, Ved MV, Karakurkchi AV (2019) Nanostructured mixed oxide coatings on silumin incorporated by cobalt. Nanophys Nanomater Interface Studies Appl 221:269–291

    Google Scholar 

  29. Dudareva NYu, Abramova MM (2016) The structure of plasma-electrolytic coating formed on Al–Si alloys by the micro-arc oxidation method. Prot Met Phys Chem Surf 52(1):128–132

    Article  Google Scholar 

  30. Vasilyeva MS, Rudnev VS (2014) Composition, surface structure and catalytic properties of manganese- and cobalt-containing oxide layers on titanium. Adv Mater Res 875–877:351–355

    Article  Google Scholar 

  31. Yar-Mukhamedova GSh, Ved MV, Karakurkchi AV, Sakhnenko ND (2017) Mixed alumina and cobalt containing plasma electrolytic oxide coatings. IOP Conf Ser Mater Sci Eng 213

    Google Scholar 

  32. Bykanova VV, Sakhnenko ND, Ved MV (2015) Synthesis and photocatalytic activity of coatings based on the TixZnyOz system. Surf Eng Appl Elechtrochem 51(3):276–282

    Article  Google Scholar 

  33. Ved M, Glushkova M, Sakhnenko N (2013) Catalytic properties of binary and ternary alloys based on silver. Func Mater 20(1):87–91

    Google Scholar 

  34. Parsadanov IV, Sakhnenko ND, Ved’ MV, Rykova I V, Khyzhniak VA, Karakurkchi AV, Gorokhivskiy AS (2017) Increasing the efficiency of intra-cylinder catalysis in diesel engines. Vopr Khim Khim Tekhnol 6:75–81

    Google Scholar 

Download references

Acknowledgements

This research was conducted within the confines of the project (Registration Number 0119U002568) with the support of the Ministry of Education and Science of Ukraine.

Author information

Authors and Affiliations

  1. National Technical University, Kharkiv Polytechnic Institute, 2, Kyrpychova str., 61002, Kharkiv, Ukraine

    Hanna Karakurkchi, Maryna Ved’ & N. D. Sakhnenko

Authors
  1. Hanna Karakurkchi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Maryna Ved’
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. D. Sakhnenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hanna Karakurkchi .

Editor information

Editors and Affiliations

  1. National Academy of Sciences of Ukraine, Institute of Physics, Kyiv, Ukraine

    Olena Fesenko

  2. National Academy of Sciences of Ukraine, Institute of Physics, Kyiv, Ukraine

    Leonid Yatsenko

Rights and permissions

Reprints and permissions

Copyright information

© 2021 Springer Nature Switzerland AG

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Karakurkchi, H., Ved’, M., Sakhnenko, N. (2021). Formation of Manganese-Containing PEO Coatings on Aluminum Alloys. In: Fesenko, O., Yatsenko, L. (eds) Nanomaterials and Nanocomposites, Nanostructure Surfaces, and Their Applications . Springer Proceedings in Physics, vol 246. Springer, Cham. https://doi.org/10.1007/978-3-030-51905-6_26

Download citation

Publish with us

Policies and ethics

Search

Navigation