Abstract
Many binary and ternary chalcogenide semiconductor materials (viz CdS, CdSe, CdTe, CdZnTe, CuInS2, CuInSe2, Bi2CdS4, CdIn2Se4, etc.) have been used to develop photoelectrochemical (PEC) solar cells for the sustained and efficient capture of solar energy conversion. Because thin-film solar cell technologies are a capable tactic for global and planetary-photovoltaics and offer a wide variability of picks in terms of device designing and fabrication. Cadmium indium selenide (CdIn2Se4) has obtained very little consideration as a potential material for photoelectrochemical cells. The manufacturing of thin-film-based heterojunction solar cells done by using some chemical and physical techniques such as sputtering, pulsed laser deposition, and evaporation. In spray pyrolysis technique (Fig. 1), a desired equimolar aqueous solution of cadmium chloride, indium trichloride, and selenourea in appropriate volumes can be taken onto preheated substrates (amorphous or conducting substrates viz. ITO, FTO, quartz, etc.). The preparative parameters (substrate temperature, solution concentration, quantity of solution) should be optimized by a PEC method in order to get high-quality stoichiometric films. The optimization of preparative parameters of the photoactive semiconducting electrode by the photoelectrochemical method is a new, reliable, and unique technique in the field of thin-film technology. So, this chapter deals with the preparation of cadmium indium chalcogenide thin films from aqueous medium by cost-effective and simple spray pyrolysis and consequently use of these films in heterojunction solar cell applications. It also extensively describes the physiochemical properties of CdIn2Se4 thin film as a potential window layer to the photoelectrochemical solar cells.
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References
The University of Colorado Boulder, http://lsa.colorado.edu/essence/texts/solar.html. Accessed on 19 Dec 2019.
Nalwa, H. S. (2001). Handbook of thin films (1st ed., pp. 1–102). Cambridge: Academic Press, Elsevier.
Nikale, V. M., & Bhosale, C. H. (2004). Properties of spray-deposited CdIn2Se4 thin films for photovoltaic applications. Solar Energy Materials and Solar Cells, 82, 3.
Green, M. A. (1992). Solar cells: operating principles, technology, and system applications (2nd ed., pp. 1–274). Kensington/Sydney: University of New South Wales.
Chopra, K. L., Paulson, P. D., & Dutta, V. (2004). Thin‐film solar cells: an overview, Progress in Photovoltaics: Research and Applications, 12, 69.
Hassanien, A. S., & Sharma, I. (2020). Optical properties of quaternary a-Ge15-x SbxSe50Te35 thermally evaporated thin-films: refractive index dispersion and single oscillator parameters. Optik, 200, 163415.
Hassanien, A. S., & Sharma, I. (2019). Band-gap engineering, conduction and valence band positions of thermally evaporated amorphous Ge15-xSbxSe50Te35 thin films: Influences of Sb upon some optical characterizations and physical parameters. Journal of Alloys and Compounds, 798, 750.
Hassanien, A. S., & Akl, A. A. (2018). Influence of thermal and compositional variations on conduction mechanisms and localized state density of amorphous Cd50S50-xSex thin films. Journal of Non-Crystalline Solids, 487, 28.
Hassanien, A. S., & Akl, A. A. (2018). Optical characteristics of iron oxide thin films prepared by spray pyrolysis technique at different substrate temperatures. Applied Physics A, 124, 752.
Ushasree, P. M., & Bora, B. (2019). Solar energy capture materials (p. 1) (E. A. Gibson, Ed.). Cambridge: Royal Society of Chemistry.
Green, M. A., Hishikawa, Y., Dunlop, E. D., Levi, D. H., Hohl-Ebinger, J., & Ho-Baillie, A. W. Y. (2018). Solar cell efficiency tables (version 52). Progress in Photovoltaics: Research and Applications, 26, 427.
Ahn, J.-H., Cai, G., Mane, R. S., Todkar, V. V., Shaikh, A. V., Chung, H., et al. (2007). Electrochemically deposited photoactive CdIn2Se4 thin films: Structural and optical studies. Applied Surface Science, 253, 8588.
Dalchiele, E. A., Cattarin, S., & Musiani, M. M. (1998). Preparation of CdIn2Se4 thin films by electrodeposition. Journal of Applied Electrochemistry, 28, 1005.
Salem, A. M., Soliman, W. Z., & Mady, Kh A. (2008). Structural characterization and electrical properties of quaternary CdGaInSe4 thin films. Physica B, 403, 145.
Chander, S., & Dhaka, M. S. (2017). Optimization of substrates and physical properties of CdS thin films for perovskite solar cell applications. Journal of Materials Science: Materials in Electronics, 28, 6852.
Purohit, A., Chander, S., Nehra, S. P., & Dhaka, M. S. (2015). Thickness-dependent physical properties of thermally evaporated nanocrystalline CdSe thin films. Acta Metallurgica Sinica (English Letters), 28, 1299.
Chander, S., & Dhaka, M. S. (2016). Thermal evolution of physical properties of vacuum evaporated polycrystalline CdTe thin films for solar cells. Journal of Materials Science: Materials in Electronics, 27, 11961.
Chander, S., & Dhaka, M. S. (2015). Preparation and physical characterization of CdTe thin films deposited by vacuum evaporation for photovoltaic applications. Advanced Materials Letters, 6, 907.
Chander, S., & Dhaka, M. S. (2017). Thermal annealing induced physical properties of electron beam vacuum evaporated CdZnTe thin films. Thin Solid Films, 625, 131.
Chander, S., & Dhaka, M. S. (2016). Effect of thickness on physical properties of electron beam vacuum evaporated CdZnTe thin films for tandem solar cells. Physica E: Low-dimensional Systems and Nanostructures, 84, 112.
El-Nahass, M. M. (1991). Optical properties of Cdln2Se4 thin films. Applied Physics A, 52, 353.
Khusayfan, N. M. (2012). Optical properties of CdIn2Se4 thin films in the region of the fundamental absorption edge. Australian Journal of Basic and Applied Sciences, 6, 329.
Hahn, H., Frank, G., Klinger, W., Storger, A. D., & Storger, G. (1955). Untersuchungen über ternäre Chalkogenide. VI. Über Ternäre Chalkogenide des Aluminiums, Galliums und Indiums mit Zink, Cadmium und Quecksilber. Zeitschrift für Anorganische und Allgemeine Chemie, 279, 241.
Nitsche, R. (1960). The growth of single crystals of binary and ternary chalcogenides by chemical transport reactions. Journal of Physics and Chemistry of Solids, 17, 163.
Rajpure, K. Y., Lokhande, C. D., & Bhosale, C. H. (1997). A comparative study of concentration effect of complexing agent on the properties of spray deposited Sb2S3 thin films and precipitated powders. Materials Chemistry and Physics, 51, 252.
Rajpure, K. Y., Mathe, V. L., & Bhosale, C. H. (1999). Photoelectrochemical investigation on spray depositedn-CdIn2S4 thin films. Bulletin of Material Science, 22, 927.
Nikale, V. M., Shinde, S. S., Bhosale, C. H., & Rajpure, K. Y. (2011). Structural, morphological and electrical properties of spray deposited CdIn2Se4 thin films. Journal of Alloys and Compounds, 509, 3116.
Nikale, V. M., Gaikwad, N. S., Rajpure, K. Y., & Bhosale, C. H. (2003). Structural and optical properties of spray-deposited CdIn2Se4 thin films. Materials Chemistry and Physics, 78, 363.
Adpakpang, K., Sarakonsri, T., Isoda, S., Shinoda, Y., & Thanachayanont, C. (2010). Synthesis of CdIn2Se4 compound used as thermoelectric materials via the solution method. Journal of Alloys and Compounds, 500, 259.
Nikale, V. M., Shinde, S. S., Babar, A. R., Bhosale, C. H., & Rajpure, K. Y. (2011). The n-CdIn2Se4/p-CdTe heterojunction solar cells. Solar Energy, 85, 1336.
Bhalerao, A. B., Wagh, B. G., Deshmukh, R. N. P. R., Shim, J.-J., & Lokhande, C. D. (2017). (Photo) electrochemical analysis of electrosynthesized fibrous cadmium indium selenide (CdIn2Se4) thin films. Journal of Photochemistry and Photobiology A: Chemistry, 336, 69.
Tenne, R., Mirovsky, Y., Greenstein, Y., & Cahen, D. (1982). Ternary chalcogenide‐based photoelectrochemical cells: II . The n-CdIn2Se4/aqueous polysulfide system. Journal of the Electrochemical Society, 129, 1506.
Marinelli, M., de Pascale, T. M., Meloni, F., Mula, G., Serra, M., & Baroni, S. (1989). Theoretical study of cubic versus tetragonal structures of defect zinc-blende semiconductors: CdIn2Se4. Physical Review B, 40, 1725.
Ruanthon, A.-A., Sarakonsri, T., & Thanachayanont, C. (2009). Preparation of CdIn2Se4n-type semiconductor sed as thermoelectric material by sol-gel method. Functional Materials Letters, 2, 199.
Salim, S. M., Kamal, M., Salem, A. M., & Bahr, T. M. (2012). Characteristic behaviour of thermaly evaporated CdIn2Se4 thin films. Journal of Applied Sciences Research, 8, 2670.
Sudha, D., Dhanapandian, S., Manoharan, C., & Arunachalam, A. (2016). Structural, morphological and electrical properties of pulsed electrodeposited CdIn2Se4 thin films. Results in Physics, 6, 599.
Nikale, V. M., Shinde, S. S., Babar, A. R., Bhosale, C. H., & Rajpure, K. Y. (2011). Photoelectrochemical performance of sprayed n-CdIn2Se4 photoanodes. Solar Energy, 85, 325.
Rawat, K., Manisha, C., & Shishodia, P. K. (2016). Investigation of CuInSe2 thin films deposited by laser ablation method. Emerging Materials Research, 5, 259.
Mahalingam, T., Thanikaikarasan, S., Chandramohan, R., Chung, K., Chu, J. P., Velumani, S., et al. (2010). Electrosynthesis and studies on cadmium-indium-selenide thin films. Materials Science and Engineering B, 174, 236.
Perna, G., Capozzi, V., Minafra, A., Pallara, M., & Ambrico, M. (2003). Effects of the indium doping on structural and optical propertiesof CdSe thin films deposited by laser ablation technique. The European Physical Journal B, 32, 339.
Hady, D. A., El-Shazly, A. A., Soliman, H. S., & El-Shazly, E. A. (1999). Electrical properties of SnSe2 thin films. Vacuum, 52, 375.
Nakanishi, H., Eudo, S., & Trie, T. (1973). Optical Absorption in CdIn2S4. Japanese Journal of Applied Physics, 12, 1646.
Fuentes-Cabrera, M., Dong, J., & Sankey, O. F. (2000). Theoretical study of the structural, electronic and vibrational properties of CdIn2Te4. Thin Solid Films, 373, 19.
Nakada, T. (2000). Nano-structural investigations on Cd-doping into Cu(In,Ga)Se2 thin films by chemical bath deposition process. Thin Solid Films, 361–362, 346.
Krishna, K. M., Sharon, M., Mishra, M. K., & Marathe, V. R. (1996). Selection of optimal mixing ratios to obtain suitable photoelectrodes from mixed semiconductors using band gap calculations. Electrochimica Acta, 41, 1999.
Kokate, A. V., Suryavanshi, U. B., & Bhosale, C. H. (2006). Structural, compositional, and optical properties of electrochemically deposited stoichiometric CdSe thin films from non-aqueous bath. Solar Energy, 80, 156.
Abdel-Aal, A. (2007). The optical parameters and photoconductivity of CdxIn1Se9-x chalcogenide thin films. Physica B, 392, 180.
Neumann, H., Kissinger, W., Lévy, F., Sobotta, H., & Riede, V. (1989). Electrical and infrared optical properties of CdIn2S4 single crystals grown by chemical transport. Crystal Research and Technology, 24, 1165.
Guerrero, E., Quintero, M., & Woolley, J. C. (1990). Temperature variation in direct and indirect band gaps of β-CdIn2Se4. Journal of Physics: Condensed Matter, 2, 6119.
Hady, D. A., El-Shazly, A. A., Soliman, H. S., & El-Shazly, E. A. (1996). The thermoelectric power, the dark electrical resistivity and the grain boundary potential barrier in CdIn2Se4 thin films. Physica A, 226, 324.
Trykozko, R., & Huffman, D. R. (2009). Reflectance and optical constants of CdIn2Se4 crystals. Journal of Applied Physics, 52, 5283.
Girija, K., Thirumalairajan, S., & Mohan, S. M. (2009). Deposition and characterization of cadmium indium selenide thin films by chemical bath technique. Optoelectronics and Advanced Materials, Rapid Communications, 3, 60.
Degdas, G., & Peksoz, A. (2019). Electrodeposition of In:CdSe precursor thin films in aqueous electrolytes including different selenous acid concentrations as Se source. Materials Science in Semiconductor Processing, 104, 104655.
Reichman, J., & Russak, M. A. (1981). Photo effects a semiconductor electrolyte interface. In A. J. Nozik (Ed.) ACS Sys (vol. 146, p. 359).
Zhuiykov, S. (2014). Nanostructured semiconductor oxides for the next generation of electronics and functional devices: Properties and applications (pp. 1–49). Cambridge: Woodhead Publishing, Elsevier.
Luque, A., & Hegedus, S. (2011). Handbook of photovoltaic science and engineering (2nd ed.). London: Wiley.
Chander, S. (2016). Dissertation, Mohanlal Sukhadia University Udaipur.
Chander, S., Purohit, A., Sharma, A., Arvind, S. P., Nehra, & Dhaka, M. S. (2015). Impact of temperature on the performance of series and parallel connected mono-crystalline silicon solar cell. Energy Reports, 1, 175.
Preston, J. S. (1950). Constitution and mechanism of the selenium rectifier photocell. Proceedings of the Royal Society, 202, 449.
Kroemer, H. (1957). Quasi-Electric and Quasi-Magnetic Fields in Non-Uniform Semiconductors. RCA Review, 18, 332.
Kroemer, H. (1957). Theory of a Wide-Gap Emitter for Transistors. Proceedings of the IRE, 45, 1535.
Tauc, J. (1957). Generation of an emf in semiconductors with nonequilibrium current carrier concentrations. Reviews of Modern Physics, 29, 308.
Armstrong, H. L. (1958). On junctions between semiconductors having different energy gaps. Proceedings of the IRE, 46, 1307 (1958).
Chang, P. C., Fan, Z., Chien, C. J., Stichtenoth, D., Ronning, C., & Lu, J. G. (2006). High-performance ZnO nanowire field effect transistors. Applied Physics Letters, 89, 133113.
Thundat, T. (2008). Flexible approach pays off. Nature Nanotechnology, 3, 133.
Wu, J. J., & Wong, D. K.-P. (2007). Fabrication and Impedance Analysis of n‐ZnO Nanorod/p‐Si Heterojunctions to Investigate Carrier Concentrations in Zn/O Source‐ Ratio‐Tuned ZnO Nanorod Arrays. Advanced Materials, 19, 2015.
Oku, T., Takeda, A., Nagata, A., Noma, T., Suzuki, A., & Kikuchi, K. (2010). Fabrication and characterization of fullerene-based bulk heterojunction solar cells with porphyrin, cuInS2, diamond and exciton-diffusion blocking layer. Journal of Energies, 3, 671.
Fan, B., Maniglio, Y., Simeunovic, M., Kuster, S., Geiger, T., Hany, R., et al. (2009). Squaraine planar-heterojunction solar cells. International Journal of Photoenergy, 2009, 1.
Chander, S., Purohit, A., Nehra, A., Nehra, S. P., & Dhaka, M. S. (2015). A study on spectral response and external quantum efficiency of monocrystalline silicon solar cell. International Journal of Renewable Energy Research, 5, 41.
Chander, S., Purohit, A., Sharma, A., Nehra, S. P., Dhaka, M. S. (2015). A study on the photovoltaic parameters of mono-crystalline Silicon solar cell with cell temperature. Energy Reports, 1, 104.
Chander, S., & Dhaka, M. S. (2016). Optimization of structural, optical and electrical properties of CdZnTe thin films with the application of thermal treatment. Materials Letters, 182, 98.
Chander, S., & Dhaka, M. S. (2016). Impact of thermal annealing on physical properties of vacuum evaporated polycrystalline CdTe thin films for solar cell applications. Physica E: Low-dimensional Systems and Nanostructures, 80, 62.
Chander, S., & Dhaka, M. S. (2017). Time evolution to CdCl2 treatment on Cd-based solar cell devices fabricated by vapor evaporation. Solar Energy, 150, 577.
Chander, S., Purohit, A., Patel, S. L., & Dhaka, M. S. (2017). Effect of substrates on structural, optical, electrical and morphological properties of evaporated polycrystalline CdZnTe thin films. Physica E: Low-dimensional Systems and Nanostructures, 89, 29.
Chander, S., & Dhaka, M. S. (2017). Enhanced structural, electrical and optical properties of evaporated CdZnTe thin films deposited on different substrates. Materials Letters, 186, 45.
Chander, S., & Dhaka, M. S. (2018). Enhancement in microstructural and optoelectrical properties of thermally evaporated CdTe films for solar cells. Results in Physics, 8, 1131.
Matsuura, J., Khatri, I., Lin, T.-Y., Sugiyama, M., & Nakada, T. (2019). Impact of heat‐light soaking and heat‐bias soaking on NaF‐treated CIGS thin film solar cells. Progress in Photovoltaics: Research and Applications, 27, 623.
Chander, S., & Dhaka, M. S. (2019). Exploration of CdMnTe thin film solar cells. Solar Energy, 183, 544.
Yan, C., Huang, J., Sun, K., Johnston, S., Zhang, Y., Sun, H., et al. (2018). Cu2ZnSnS4 solar cells with over 10% power conversion efficiency enabled by heterojunction heat treatment. Nature Energy, 3, 764.
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Chander, S. (2020). Advancement in CdIn2Se4/CdTe Based Photoelectrochemical Solar Cells. In: Ikhmayies, S. (eds) Advances in Energy Materials. Advances in Material Research and Technology. Springer, Cham. https://doi.org/10.1007/978-3-030-50108-2_2
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