Abstract
Based on the introduction of semiconductor technologies, the application of thin-film and micromachining techniques to fabricate integrated vacuum field emission devices in the submicron size range became feasible in the 1960s. These were pioneered at SRI by C. Spindt and colleagues, who first introduced gated field emitter arrays. There are several previous extended reviews on this topic published until 2001 [1]. The present chapter presents a short wrap up of fabrication techniques and structures, and a performance update on Spindt arrays and on field emitter arrays (FEAs) in general. This chapter will only deal with regular array structures and their specific advantages and problems; random structures will not be discussed. A critical evaluation of progress and of application of FEAs in devices is given.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Similar content being viewed by others
References
W. Zhu (ed.), Vacuum Microelectronics (Wiley 2001). including chapter 1: “Historical Overview” by Takao Utsumi
C. Spindt, I. Brodie, C. Holland, P. Schwoebel, Spindt Field Emitter Arrays, in Chapter 4 of Vacuum Microelectronics (Wiley 2001), pp. 105–186
K. Jensen, Theory of field emission, in Chapter 3 of Vacuum Microelectronics (Wiley 2001), pp. 33–104
I. Brodie, C.A. Spindt, Vacuum microelectronics, in Advances in Electronics and Electron Physics, vol. 83, ed. by P.W. Hawkes (Academic Press, New York 1992), pp. 1–106
N. Cade, R. Lee, Vacuum microelectronics. GEC J. Res. 7(3), 129–138 (1990)
Dorota Temple, Recent progress in field emitter array development for high performance applications. Mater. Sci. Eng. R24, 185–239 (1999)
N. Egorov, E.P. Sheshin, Electron field emission, principles and applications (In Russian), Intellekt 2011; Updated English version Field Emission Electronics published by Springer in 2017
C.A. Spindt, K.R. Shoulders, Research in micron-size Field-emission tubes, in IEEE Conference Record, Eighth Conference on Tube Techniques (1966), p. 143
C.A. Spindt, A thin-film field-emission cathode. J. Appl. Phys. 39, 350 (1968)
R. Meyer, A. Ghis, P. Rambaud, F. Muller, Microchip florescent display, in Proc. Japan Display (1985), p. 513
C.E. Holland, C.A. Spindt, I. Brodie, J. Mooney, E.R. Westerberg, Matrix addressed cathodoluminescent display, in Int. Display Conf. (London, UK, 1987)
G. Gaertner, P. Janiel, J.E. Crombeen, J. Hasker, Top-layer scandate cathodes by plasma- activated CVD, in Vacuum Microelectronics 1989, ed. by R.E. Turner, Institute of Physics Conf. Series No. 99 (Bristol, New York), pp. 25–28
Ivor Brodie, Julius J. Muray, The Physics Of Micro/Nano-Fabrication (Springer, Boston, MA, 1992)
I. Brodie, E.R. Westerberg, D.R. Cone, J.J. Muray, N. Williams, L. Gasiorek, A multiple- electron- beam exposure system for high-throughput, direct-write submicrometer lithography. IEEE Transact. Electron Dev. 28(11), 1422–1428 (1981)
C.A. Spindt, I. Brodie, L. Humphrey, E.R. Westerberg, Physical properties of thin-film field emission cathodes with molybdenum cones. J. Appl. Phys. 47, 5248 (1976)
X. Chen, S. Zaidi, D. Devine, S. Brueck, J. Vac. Sci. Technol. B. 14, 3339 (1996)
C.H. Oh, J.D. Lee, et al., Fabrication of metal field emitter arrays for low voltage and high current operation, J. Vac. Sci. Technol. B. 16, 807 (1998)
C. Bozler, C. Harris, S. Rabe, D. Rathman, M. Hollis, H. Smith, Arrays of gated field-emitter cones having 0.32 μm tip-to-tip spacing. J. Vac. Sci. Technol. B. 12, 629 (1994)
P.R. Schwoebel, C.A. Spindt, C.E. Holland, High current, high current density field emitter array cathodes. J. Vac. Sci. Technol. B. 23/2, 691f.(2005)
J.H. Jung et al., Electron emission performance of Mo tip FEAs with nitrogen-doped hydrogen-free DLC coating, in Proceedings of 12th IVMC (Darmstadt 1999), pp. 110–111
J. Shaw, J. Itoh, Silicon Field Emitter Arrays, in Chapter 5 of Vacuum Microelectronics (Wiley, 2001), pp. 187–246
J.M. Macaulay, I. Brodie, C.A. Spindt, C.E. Holland, Appl. Phys. Lett. 61, 997 (1992)
C.A. Spindt, C.E. Holland, A. Rosengreen, I. Brodie, Field-emitter arrays for vacuum microelectronics. IEEE Trans. Electron Devices 38, 2355 (1991)
C.A. Spindt, C.E. Holland, P.R. Schwoebel, I. Brodie, Field emitter array development for microwave applications II. J. Vac. Sci. Technol. B. 16, 758–761 (1998)
C.A. Spindt, C.E. Holland, P.R. Schwoebel, I. Brodie, Field-emitter-array development for microwave applications. J. Vac. Sci. Technol. B. 14, 1986 (1996)
I. Brodie, C.A. Spindt, The application of thin-film field-emission cathodes to electronic tubes. Appl. Surf. Sci. 2, 149–163 (1979)
C.A. Spindt, C. Holland, R. Stowell, Field emission array development for high-current-density applications. Appl. Surf. Sci. 16, 268–276 (1983)
R. Forman, Evaluation of emission capabilities of Spindt-type field emitting cathodes. Appl. Surf. Sci. 16, 277–291 (1983)
C. Herring, Structures and Properties of Solid Surfaces (University of Chicago Press, Chicago,1953). p. 5
M. Benjamin, R.O. Jenkins, Proc. R. Soc. Lond. A. 176, 262 (1940)
R. Gomer, Field Emission and Field Ionization (Harvard University Press, Cambridge/MA, 1961). p. 54
B. Gnade, in Proc. Spring Meeting of the Materials Research Society, Tutorial Program, Symposium G (San Francisco, CA, 1997)
P.R. Schwoebel, C.A. Spindt, I. Brodie, Electron emission enhancement by over-coating molybdenum field-emitter arrays with titanium, zirconium, and hafnium. J. Vac. Sci. Technol. B. 13, 338 (1995)
C.A. Spindt, C.E. Holland, A. Rosengreen, I. Brodie, Field emitter-array development for high- frequency operation. J. Vac. Sci. Technol. B. 11, 468 (1993)
G.N.A. van Veen, Space-charge effects in Spindt-type field emission cathodes. J. Vac. Sci. Technol. B. 12, 655 (1994)
C.A. Spindt, C.E. Holland, P.R. Schwoebel, Thermal field forming of Spindt cathode arrays. J. Vac. Sci. Technol. B. 33, 03C108–1 (2015)
G. Gaertner, H.W.P. Koops, Vacuum Electron Sources and their Materials and Technologies, in chapter 10 of Vacuum Electronics, Components and Devices, ed. J. Eichmeier, M. Thumm (Springer, 2008)
P.R. Schwoebel, C.A. Spindt, C.E. Holland, Spindt cathode tip processing to enhance emission stability and high-current performance. J. Vac. Sci. Technol. B. 21, 433 (2003)
A. Mustonen, V. Guzenko, C. Spreu, T. Feurer, S. Tsujino, High-density metallic nano-emitter arrays and their field emission characteristics. Nanotechnology 25, 085203 (2014)
C. Spindt, C. Holland, I. Brodie et al., Field emitter arrays applied to vacuum fluorescent display. IEEE Trans. ED 36, 225–228 (1989)
H. Busta, Field emission flat panel displays, in chapter 7 of Vacuum Microelectronics (Wiley, 2001), pp. 289–347
P. Schwoebel et al., Field emission arrays for medical X-ray imaging. Appl. Phys. Lett. 88, 113902 (2006)
R.A. Murphy, M.A. Codis, Cold cathode microwave devices, in chapter 8 of Vacuum Microelectronics (Wiley, 2001), pp. 349–391
G. Gaertner, Historical development and future trends of vacuum electronics. J. Vac. Sci. Technol. B. 30/6, 060801(2012)
D.R. Whaley, B.M. Gannon, C.R. Smith, C.M. Armstrong, C.A. Spindt, Application of field emitter arrays to microwave power amplifiers. IEEE Trans. Plasma Sci. 28, 727–747 (2000)
J.X. Qiu, B. Levush et al., Vacuum tube amplifiers. IEEE Microw. Mag. 38–51 (2009)
J.A. Hart, A History of Field Emission Displays (Indiana University, 1999). http://www.indiana.edu/~hightech/fpd/papers/FEDs.PDF
J. Lieberman, Field-Emission Displays Get a Second Wind?”, IEEE Spectrum, 1.10.2003
P.R. Schwoebel, J.M. Boone, J. Shao, Studies of a prototype linear stationary X-ray source for tomosynthesis imaging. Phys Med Biol. 59, 2393–2413 (2014)
G.Z. Yue, O. Zhu et al., Generation of continuous and pulsed diagnostic imaging x-ray radiation using a carbon-nanotube-based field-emission cathode. Appl. Phys. Lett. 81, 355–357 (2002)
S Cheng et al., A compact X-ray generator using a nanostructured field emission cathode and a micro-structured transmission anode. J. Phys. Conf. Ser. 476, 012016 (2013)
T. Hirano, S. Kanemaru, J. Itoh, Emission current saturation of the p-type silicon gated field emitter array. J. Vac. Sci. Technol. B. 14, 3357 (1996)
T. Matsukawa, S. Kanemaru, K. Tokunaga, J. Itoh, Individual tip evaluation in Si field emitter arrays by electrostatic lens projector. J. Vac. Sci. Technol. B. 18, 952 (2000)
J. Itoh, Development and applications of field emitter arrays in Japan. Appl. Surf. Sci. 111, 194–203 (1997)
S. Kanemaru, T. Hirano, H. Tanoue, J. Itoh, Control of emission characteristics of silicon field emitter arrays by an ion implantation technique. J. Vac. Sci. Technol. B. 14, 1885 (1996)
D. Temple, W.D. Palmer, L.N. Yadon, J.E. Mancusi, D. Vellenga, G.E. McGuire, Silicon field emitter cathodes: fabrication, performance, and applications. J. Vac. Sci. Technol. A. 16, 1980 (1998)
T. Matsukawa, S. Kanemaru, K. Tokunaga, J. Itoh, Effects of conduction type on field-electron emission from single Si emitter tips with extraction gate. J. Vac. Sci. Technol. B. 18, 1111 (2000)
D. Palmer, H.F. Gray, J. Mancusi, D. Temple, C. Ball, J. Shaw, G.E. McGuire, Silicon field emitter arrays with low capacitance and improved transconductance for microwave amplifier applications. J. Vac. Sci. Technol. B. 13, 576–579 (1995)
S. Kanemaru, T. Hirano, H. Tanoue, J. Itoh, Control of emission current from silicon field emitter arrays using a built-in MOSFET. Appl. Surf. Sci. 111, 218–223 (1997)
M. Nagao, D. Nicolaescu, T. Matsukawa, S. Kanemaru, J. Itoh, T. Sato, Y. Sato, N. Wada, Metal–oxide–semiconductor field-effect transistor-structured Si field emitter array with a built-in ring gate lens. J. Vac. Sci. Technol. B. 21, 495 (2003)
H. Gama, S. Kanemaru, J. Itoh, A field emitter array monolithically integrated with a thin film transistor on glass for display applications. Appl. Surf. Sci. 146, 187–192 (1999)
K. Ehara, S. Kanemaru, T. Matsukawa, J. Itoh, Improvement of electron emission characteristics of Si field emitter arrays by surface modification. Appl. Surf. Sci. 146, 172–175 (1999)
J. Itoh, K. Uemura, S. Kanemaru, Three-dimensional vacuum magnetic sensor with a Si emitter tip. J. Vac. Sci. Technol. B 16, 1233 (1998)
M. Nagao, C. Yasumuro, M. Taniguchi, S. Itoh, S. Kanemaru, J. Itoh, Field emitter array with a memory function for ultrahigh luminance field emission display. J. Vac. Sci. Technol. B25, 464 (2007)
B. Wei, R. Vajtai, P.M. Ajayan, Reliability and current carrying capacity of carbon nanotubes. Appl. Phys. Lett. 79, 1172 (2001)
N. de Jonge, J.-M. Bonard, Carbon nanotube electron sources and applications. Phil. Trans. R. Soc. Lond. A 362, 2239–2266 (2004)
Z. Chen, G. Cao, Z. Lin, D. den Engelsen et al., Synthesis and emission properties of carbon nanotubes grown by sandwich catalyst stacks. J. Vac. Sci. Technol. B 24, 1017 (2006)
Z. Chen, P.K. Bachmann et al., Fabrication and characterization of carbon nanotube arrays using sandwich catalyst stacks. Carbon 44, 225–230 (2006)
Z. Chen, P.K. Bachmann et al., Growth of uniform carbon nanotube arrays with sandwich technology. J. Soc. Inf. Display 16, 645 (2008)
Z. Chen, P.K. Bachmann, et al., Field emission from CNT bundles for application in biomedical equipment, in Proc. 8th Int. Vac. Electron Sources Conf. and Nanocarbon (IEEE Press, Nanjing, 2010), pp. 111–112
S.H. Heo, H.J. Kim et al., A vacuum-sealed miniature X-ray tube based on carbon nanotube field emitters. Nanoscale Res. Lett. 7, 258 (2012)
G. Yue, O. Zhou, Generation of continuous and pulsed diagnostic imaging x-ray radiation using a carbon-nanotube based field-emission cathode. Appl. Phys. Lett. 81, 355 (2002)
J. Ryu, J. Kang, K. Park, Carbon nanotube electron emitter for X-ray imaging. Materials 5, 2353–2359 (2012)
N. de Jonge, N. van Druten, Field emission from individual multiwalled carbon nanotubes prepared in an electron microscope. Ultramicroscopy 95, 85–91 (2003)
W.I. Milne, K. Teo, G. Amaratunga et al., Carbon nanotubes as field emission sources. J. Mater. Chem. 14, 933–943 (2004)
G. Amaratunga, Watching the nanotubes. IEEE Spectr. 40, 28–32 (2003)
L. Nilsson, O. Groening, J.-M. Bonard et al., Appl. Phys. Lett. 76, 2071–2073 (2000) and L.-O. Nilsson, Microscopic characterization of electron field emission from carbon nanotubes and carbon thin-film electron emitters”, PhD thesis, University Freiburg (CH), p. 79 (2001)
K. Teo, S. Lee, W. Milne et al., Plasma enhanced chemical vapour deposition carbon nanotubes/ nanofibres—how uniform do they grow? Nanotechnology 14, 204–211 (2003)
Z. Chen, P.K. Bachmann et al., High emission current density microwave-plasma-grown carbon nanotube arrays by post-depositional radio-frequency oxygen plasma treatment. Appl. Phys. Lett. 87, 243104 (2005)
W. Knapp, D. Schleussner, Field-emission charcteristics of carbon buckypaper. JVST B 21, 557–561 (2003)
W. Knapp, D. Schleussner, Special features of electron sources with CNT field emitter and micro-grid. Appl. Surf. Sci. 251, 164–169 (2005)
R. Parmee, C. Collins, W. Milne, M. Cole, X-ray generation using carbon nanotubes. Nano Converg. 2(1), 1–27 (2015)
M. Cole, R. Parmee, W. Milne, Nanomaterial-based x-ray sources. Nanotechnology 27, 082501 (2016)
P. Sarrazin, D. Blake, M. Meyyappan et al., Carbon-nanotube field emission X-ray tube for space exploration XRD/XRF instrument. Adv. X-Ray Anal. 47, 232 (2004)
M. Cole, M. Mann, K. Teo, W. Milne, Engineered carbon nanotube field emission devices, in Chapter 5 of Emerging Nanotechnologies for Manufacturing, 2nd edn. (Pergamon/Elsevier Science, 2014), pp. 126–185
G.N. Fursey, Field emission in vacuum micro-electronics. Appl. Surf. Sci. 215, 113 (2003)
G. van Gorkom, A. Hoeberechts, Back-biased junction cold cathodes: history and state of the art, in Vacuum Microelectronics 1989, IOP Conference Series 99 (Institute of Physics, Bristol, 1989), pp. 41–52
V.V. Zhirnov, C. Lizzul-Rinne, G.J. Wojak, R.C. Sanwald, J.J. Hren, “Standardization” of field emission measurements. J. Vac. Sci. Technol. B 19, 87 (2001)
F. Charbonnier, “Developing and using the field emitter as a high intensity electron source. Appl. Surf. Sci. 94/95, 26–43 (1996)
D. Wenger, W. Knapp, B. Hensel, S. F. Tedde, Transition of electron field emission to normal glow discharge. IEEE Transact. Electron Devices, 61(11), 3864–3870 (2014)
P.R. Schwoebel, C.A. Spindt, Glow discharge processing to enhance field-emitter array performance. J. Vac. Sci. Technol. B. 12, 2414 (1994)
P.R. Schwoebel, C.A. Spindt, C.E. Holland, Emission uniformity enhancement between micro-fabricated tips in cold cathode arrays. J. Vac. Sci. Technol. B. 19, 582 (2001)
P.R. Schwoebel, C.A. Spindt, C.E. Holland, J.A. Panitz, Field emission current cleaning and annealing of micro-fabricated cold cathodes. J. Vac. Sci. Technol. B. 19, 980 (2001)
C. Holland, C. Spindt, A. Rosengren, I. Brodie, Field emitter array development for high-frequency operation. Conference Record of TRI/NASA Cathode Workshop (Cleveland/Ohio 1994), pp. 87–90
Acknowledgement
The authors want to thank Ivor Brodie for his advice w.r.t. relevant literature.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2020 Springer Nature Switzerland AG
About this chapter
Cite this chapter
Gaertner, G., Knapp, W. (2020). Spindt Cathodes and Other Field Emitter Arrays. In: Gaertner, G., Knapp, W., Forbes, R.G. (eds) Modern Developments in Vacuum Electron Sources. Topics in Applied Physics, vol 135. Springer, Cham. https://doi.org/10.1007/978-3-030-47291-7_12
Download citation
DOI: https://doi.org/10.1007/978-3-030-47291-7_12
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-47290-0
Online ISBN: 978-3-030-47291-7
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)