Abstract
The supersonic cluster beam deposition (SCBD) of neutral carbon clusters produced in a pulsed microplasma cluster source (PMCS) is an effective technique for producing nanostructured carbon (nsC) thin films with controlled nanostructures. The use of carbon clusters as building blocks allows the synthesis of carbonaceous materials with structural properties that are determined not only by the characteristics of the clusters but also by their organization upon deposition. NsC films produced by SCBD/PMCS grow in a ballistic deposition regime where incoming particles land on the growing interface and do not diffuse significantly. This growth regime leads to remarkable statistical scale invariance of the evolving interface at which the carbon clusters aggregate in larger and larger superunits. Due to negligible stress accumulation during the low-energy deposition process, nsC films with thicknesses of between a few tens of nanometers and a few micrometers can be routinely deposited onto and will adhere to almost any kind of surface. This deposition approach enables the production of carbon thin films characterized by low density, high surface roughness, and high porosity, making them promising materials for use in the fabrication of devices such as electrolyte-gated transistors, supercapacitors, and photocatalytic systems for sustainable energy technologies.
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References
V. Georgakilas, J.A. Perman, J. Tucek, R. Zboril: Broad family of carbon nanoallotropes: classification, chemistry, and applications of fullerenes, carbon dots, nanotubes, graphene, nanodiamonds, and combined superstructures, Chem. Rev. 115, 4744–4822 (2015)
G. Benedek, P. Milani, V.G. Ralchenko: Nanostructured carbon for advanced applications. In: Proc. NATO Advanced Study Institute on Nanostructured Carbon for Advanced Applications Erice (Springer, Berlin 2001)
G. Bongiorno, A. Podestà, L. Ravagnan, P. Piseri, P. Milani, C. Lenardi, S. Miglio, M. Bruzzi, C. Ducati: Electronic properties and applications of cluster-assembled carbon films, J. Mater. Sci. Mater. Electron. 17, 427–441 (2006)
P. Serp, B. Machado: Nanostructured Carbon Materials for Catalysis (R. Soc. Chem., London 2015)
Y. Gogotsi, V. Presser: Carbon Nanomaterials, 2nd edn. (CRC, Boca Raton 2013)
S.L. Candelaria, Y. Shao, W. Zhou, X. Li, J. Xiao, J.-G. Zhang, Y. Wang, J. Liu, J. Li, G. Cao: Nanostructured carbon for energy storage and conversion, Nano Energy 1, 195–220 (2012)
P. Milani, P. Piseri, E. Barborini, A. Podesta, C. Lenardi: Cluster beam synthesis of nanostructured thin films, J. Vac. Sci. Technol. Vac. Surf. Films. 19, 2025–2033 (2001)
L. Ravagnan, F. Siviero, C. Lenardi, P. Piseri, E. Barborini, P. Milani, C.S. Casari, A. Li Bassi, C.E. Bottani: Cluster-beam deposition and in situ characterization of carbyne-rich carbon films, Phys. Rev. Lett. 89, 285506 (2002)
M. Bogana, L. Ravagnan, C.S. Casari, A. Zivelonghi, A. Baserga, A.L. Bassi, C.E. Bottani, S. Vinati, E. Salis, P. Piseri, E. Barborini, L. Colombo, P. Milani: Leaving the fullerene road: presence and stability of sp chains in sp2 carbon clusters and cluster-assembled solids, New J. Phys. 7, 81 (2005)
D. Donadio, L. Colombo, P. Milani, G. Benedek: Growth of nanostructured carbon films by cluster assembly, Phys. Rev. Lett. 83, 776–779 (1999)
P. Piseri, A. Podestà, E. Barborini, P. Milani: Production and characterization of highly intense and collimated cluster beams by inertial focusing in supersonic expansions, Rev. Sci. Instrum. 72, 2261–2267 (2001)
K. Wegner, P. Piseri, H.V. Tafreshi, P. Milani: Cluster beam deposition: a tool for nanoscale science and technology, J. Phys. Appl. Phys. 39, R439 (2006)
E. Barborini, P. Piseri, A. Podesta’, P. Milani: Cluster beam microfabrication of patterns of three-dimensional nanostructured objects, Appl. Phys. Lett. 77, 1059–1061 (2000)
P. Piseri, H.V. Tafreshi, P. Milani: Manipulation of nanoparticles in supersonic beams for the production of nanostructured materials, Curr. Opin. Solid State Mater. Sci. 8, 195–202 (2004)
E. Barborini, P. Piseri, P. Milani: A pulsed microplasma source of high intensity supersonic carbon cluster beams, J. Phys. Appl. Phys. 32, L105 (1999)
A. Podestà, F. Borghi, M. Indrieri, S. Bovio, C. Piazzoni, P. Milani: Nanomanufacturing of titania interfaces with controlled structural and functional properties by supersonic cluster beam deposition, J. Appl. Phys. 118, 234309 (2015)
F. Borghi, E. Sogne, C. Lenardi, A. Podestà, M. Merlini, C. Ducati, P. Milani: Cluster-assembled cubic zirconia films with tunable and stable nanoscale morphology against thermal annealing, J. Appl. Phys. 120, 055302 (2016)
P. Milani, A. Podesta, P. Piseri, E. Barborini, C. Lenardi, C. Castelnovo: Cluster assembling of nanostructured carbon films, Diam. Relat. Mater. 10, 240–247 (2001)
P. Milani, E. Barborini, P. Piseri, C.E. Bottani, A.C. Ferrari, A. Li Bassi: Nanostructured carbon films from supersonic cluster beam deposition: structure and morphology, Eur. Phys. J. D 9, 63–68 (1999)
R. Buzio, E. Gnecco, C. Boragno, U. Valbusa, P. Piseri, E. Barborini, P. Milani: Self-affine properties of cluster-assembled carbon thin films, Surf. Sci. 444, L1–L6 (2000)
A.-L. Barabási, H.E. Stanley: Fractal Concepts in Surface Growth (Cambridge Univ. Press, Cambridge 1995)
F. Family, T. Vicsek (Eds.): Dynamics of Fractal Surfaces (World Scientific, Singapore 1991)
M.O. Robbins, M. Cieplak, H. Ji, B. Koiller, N. Martys: Growth in systems with quenched disorder. In: Growth Patterns in Physical Sciences and Biology, ed. by J.M. Garcia-Ruiz, E. Louis, P. Meakin, L.M. Sander (Springer, Boston 1993) pp. 65–75
F. Family, T. Vicsek: Scaling of the active zone in the Eden process on percolation networks and the ballistic deposition model, J. Phys. Math. Gen. 18, L75–L81 (1985)
G. Bongiorno, M. Blomqvist, P. Piseri, P. Milani, C. Lenardi, C. Ducati, T. Caruso, P. Rudolf, S. Wachtmeister, S. Csillag, E. Coronel: Nanostructured CNx (0 < x < 0.2) films grown by supersonic cluster beam deposition, Carbon 43, 1460–1469 (2005)
E. Barborini, C. Lenardi, P. Piseri, P. Milani, R.G. Agostino, T. Caruso, E. Colavita, S.L. Rosa, M. Bertolo, C. Ducati: Morphology and electronic structure of nanostructured carbon films embedding transition metal nanoparticles, Eur. Phys. J. 24, 273–276 (2003)
M. Amati, C. Lenardi, R.G. Agostino, T. Caruso, C. Ducati, S. La Rosa, G. Bongiorno, V. Cassina, P. Podestà, L. Ravagnan, P. Piseri, P. Milani: Electrical conductivity of cluster-assembled carbon/titania nanocomposite films irradiated by highly focused vacuum ultraviolet photon beams, J. Appl. Phys. 101, 064314 (2007)
R.G. Agostino, T. Caruso, G. Chiarello, A. Cupolillo, D. Pacilè, R. Filosa, V. Formoso, E. Colavita, L. Papagno, C. Ducati, E. Barborini, C. Lenardi, G. Bongiorno, P. Piseri, P. Milani: Thermal annealing and hydrogen exposure effects on cluster-assembled nanostructured carbon films embedded with transition metal nanoparticles, Phys. Rev. B 68, 035413 (2003)
L.G. Bettini, G. Divitini, C. Ducati, P. Milani, P. Piseri: Nickel nanoparticles effect on the electrochemical energy storage properties of carbon nanocomposite films, Nanotechnology 25, 435401 (2014)
E. Barborini, P. Piseri, P. Milani, G. Benedek, C. Ducati, J. Robertson: Negatively curved spongy carbon, Appl. Phys. Lett. 81, 3359–3361 (2002)
G. Bongiorno, C. Lenardi, C. Ducati, R.G. Agostino, T. Caruso, M. Amati, M. Blomqvist, E. Barborini, P. Piseri, S. La Rosa, E. Colavita, P. Milani: Nanocrystalline metal/carbon composites produced by supersonic cluster beam deposition, J. Nanosci. Nanotechnol. 5, 1072–1080 (2005)
T. Caruso, R.G. Agostino, G. Bongiorno, E. Barborini, P. Piseri, P. Milani, C. Lenardi, S. La Rosa, M. Bertolo: Writing submicrometric metallic patterns by ultraviolet synchrotron irradiation of nanostructured carbon and TiOx–carbon films, Appl. Phys. Lett. 84, 3412–3414 (2004)
A.S. Aricò, P. Bruce, B. Scrosati, J.-M. Tarascon, W. van Schalkwijk: Nanostructured materials for advanced energy conversion and storage devices, Nat. Mater. 4, 366–377 (2005)
E. Serrano, G. Rus, J. García-Martínez: Nanotechnology for sustainable energy, Renew. Sustain. Energy Rev. 13, 2373–2384 (2009)
Z.L. Wang: Self-powered nanosensors and nanosystems, Adv. Mater. 24, 280–285 (2012)
S.P.S. Badwal, S.S. Giddey, C. Munnings, A.I. Bhatt, A.F. Hollenkamp: Emerging electrochemical energy conversion and storage technologies, Front. Chem. (2014), https://doi.org/10.3389/fchem.2014.00079
B.E. Conway: Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications (Springer, Berlin 2013)
R. Kötz, M. Carlen: Principles and applications of electrochemical capacitors, Electrochim. Acta 45, 2483–2498 (2000)
M. Beidaghi, Y. Gogotsi: Capacitive energy storage in micro-scale devices: recent advances in design and fabrication of micro-supercapacitors, Energy Environ. Sci. 7, 867–884 (2014)
L.G. Bettini, M. Galluzzi, A. Podestà, P. Milani, P. Piseri: Planar thin film supercapacitor based on cluster-assembled nanostructured carbon and ionic liquid electrolyte, Carbon 59, 212–220 (2013)
L.G. Bettini, P. Piseri, F. De Giorgio, C. Arbizzani, P. Milani, F. Soavi: Flexible, ionic liquid-based micro-supercapacitor produced by supersonic cluster beam deposition, Electrochim. Acta 170, 57–62 (2015)
L.G. Bettini, G. Bardizza, A. Podestà, P. Milani, P. Piseri: Electrochemical impedance spectroscopy on nanostructured carbon electrodes grown by supersonic cluster beam deposition, J. Nanopart. Res. 15, 1429 (2013)
L. Diederich, E. Barborini, P. Piseri, A. Podestà, P. Milani, A. Schneuwly, R. Gallay: Supercapacitors based on nanostructured carbon electrodes grown by cluster-beam deposition, Appl. Phys. Lett. 75, 2662–2664 (1999)
L.G. Bettini, A. Bellacicca, P. Piseri, P. Milani: Supersonic cluster beam printing of carbon microsupercapacitors on paper, Flex. Print. Electron. 2, 025002 (2017)
F. Soavi, L.G. Bettini, P. Piseri, P. Milani, C. Santoro, P. Atanassov, C. Arbizzani: Miniaturized supercapacitors: key materials and structures towards autonomous and sustainable devices and systems, J. Power Sources 326, 717–725 (2016)
S.H. Kim, K. Hong, W. Xie, K.H. Lee, S. Zhang, T.P. Lodge, C.D. Frisbie: Electrolyte-gated transistors for organic and printed electronics, Adv. Mater. 25, 1822–1846 (2013)
J. Sayago, F. Soavi, Y. Sivalingam, F. Cicoira, C. Santato: Low voltage electrolyte-gated organic transistors making use of high surface area activated carbon gate electrodes, J. Mater. Chem. C 2, 5690–5694 (2014)
H. Tang, P. Kumar, S. Zhang, Z. Yi, G.D. Crescenzo, C. Santato, F. Soavi, F. Cicoira: Conducting polymer transistors making use of activated carbon gate electrodes, ACS Appl. Mater. Interfaces 7, 969–973 (2015)
J. Sayago, U. Shafique, F. Soavi, F. Cicoira, C. Santato: TransCap: a monolithically integrated supercapacitor and electrolyte-gated transistor, J. Mater. Chem. C 2, 10273–10276 (2014)
Z. Yi, L.G. Bettini, G. Tomasello, P. Kumar, P. Piseri, I. Valitova, P. Milani, F. Soavi, F. Cicoira: Flexible conducting polymer transistors with supercapacitor function, J. Polym. Sci. B 55, 96–103 (2017)
M.R. Hoffmann, S.T. Martin, W. Choi, D.W. Bahnemann: Environmental applications of semiconductor photocatalysis, Chem. Rev. 95, 69–96 (1995)
M. Miyauchi, A. Nakajima, T. Watanabe, K. Hashimoto: Photocatalysis and photoinduced hydrophilicity of various metal oxide thin films, Chem. Mater. 14, 2812–2816 (2002)
M.N. Chong, B. Jin, C.W.K. Chow, C. Saint: Recent developments in photocatalytic water treatment technology: a review, Water Res. 44, 2997–3027 (2010)
P. Hartmann, D.-K. Lee, B.M. Smarsly, J. Janek: Mesoporous TiO2: comparison of classical sol–gel and nanoparticle based photoelectrodes for the water splitting reaction, ACS Nano 4, 3147–3154 (2010)
A.Y. Shan, T.I.M. Ghazi, S.A. Rashid: Immobilisation of titanium dioxide onto supporting materials in heterogeneous photocatalysis: a review, Appl. Catal. Gen. 389, 1–8 (2010)
L.G. Bettini, D.F. Foglia, P. Milani, P. Piseri: Nanostructured carbon substrate improves the photoelectrochemical water splitting activity of cluster-assembled TiO2 thin films, Int. J. Hydrog. Energy 40, 6013–6020 (2015)
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Bettini, L.G., Galluzzi, M., Podestà, A., Piseri, P., Milani, P. (2020). Cluster-Assembled Carbon Thin Films. In: Rocca, M., Rahman, T.S., Vattuone, L. (eds) Springer Handbook of Surface Science. Springer Handbooks. Springer, Cham. https://doi.org/10.1007/978-3-030-46906-1_38
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DOI: https://doi.org/10.1007/978-3-030-46906-1_38
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