Abstract
This study investigates the chemical and morphological behavior of rejuvenated asphalt binders. A TFOT aged PG 58-28 binder was mixed with three different types of rejuvenators that include waste cooking oil/untreated used cooking oil (UT), treated used oil (TR), and Hydrolene (HL) at 3, 6, and 9% by the weight of the total binder. To understand the characteristics and the performance of these rejuvenators, three sets of characterization tests were conducted: rheological, chemical, and morphological. This paper presents a summary of the results from our chemical and morphological studies. Gas Chromatography-Mass Spectroscopy (GC-MS) was conducted to identify the chemical composition of rejuvenators, while Fourier Transformed Infrared Spectroscopy (FTIR) was conducted for obtaining chemical functional group information. Furthermore, an Atomic Force Microscopy (AFM) was employed to obtain the micro-morphological properties of rejuvenated asphalt binders. The collected data showed that rejuvenation changes the chemical composition and alters the micro-structures of binders significantly, which impacts the overall performances of binder. In fact, this experimental study showed a good correlation between chemical compositional and morphological features with the rheological performance of the binder. The research findings are expected to contribute to the performance evaluation and characterization of rejuvenated asphalt mixes.
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References
Hossain, K., Karakas, A., Hossain, Z.: Effects of aging and rejuvenation on surface free energy measurements and adhesion of asphalt mixtures. J. Mater. Civ. Eng. 31(7) (2019)
Brown, E.R.: Preventive maintenance of asphalt concrete pavements. Transp. Res. Rec. J. Transp. Res. Board 6–11 (1988)
Hossain, Z., et al.: Evaluation for warm-mix additive-modified asphalt binders using spectroscopy techniques. J. Mater. Civ. Eng. 25(2), 149–159 (2013)
Hossain, K., Hossain, Z.: A synthesis of computational and experimental approaches of evaluating chemical, physical and mechanistic properties of asphalt binders. J. Adv. Civ. Eng. (2018)
Pauli, A.T., Grimes, R.W., Beemer, A.G., Turner, T.F., Branthaver, J.F.: Morphology of asphalts, asphalt fractions and model wax-doped asphalts studied by atomic force microscopy. Int. J. Pavement Eng. 12(4), 291–309 (2011)
Yu, X., Zaumanis, M., Dos Santos, S., Poulikakos, L.D.: Rheological, microscopic, and chemical characterization of the rejuvenating effect on asphalt binders. Fuel 135(1), 162–171 (2014)
Ahmed, R.B., Hossain, K.: Waste cooking oil as an asphalt rejuvenator: a state-of-the-art review. Constr. Build. Mater. 230, 116985 (2019)
Leung, D.Y.C., Guo, Y.: Transesterification of neat and used frying oil: optimization for biodiesel production. Fuel Process. Technol. 87(10), 883–890 (2006)
Herrington, P.R., Ball, G.F.A.: Dependence oxidation mechanism of asphalt. Fuel 75(9), 1129–1131 (1996)
Azahar, W.N.A.W., Jaya, R.P., Hainin, M.R., Bujang, M., Ngadi, N.: Chemical modification of waste cooking oil to improve the physical and rheological properties of asphalt binder. Constr. Build. Mater. 126, 218–226 (2016)
Masson, J.-F., Leblond, V., Margeson, J.: Bitumen morphologies by phase-detection atomic force. J. Microsc. 221(1), 17–29 (2006)
Acknowledgments
The authors gratefully acknowledge the Leslie Harris Centre of Regional Policy and Developments and Multi-Material Stewardship Board of Government of Newfoundland and Labrador for the research funding.
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Ahmed, R.B., Hossain, K. (2022). Characterization of Rejuvenated Asphalt Binders Using FTIR and AFM Techniques. In: Di Benedetto, H., Baaj, H., Chailleux, E., Tebaldi, G., Sauzéat, C., Mangiafico, S. (eds) Proceedings of the RILEM International Symposium on Bituminous Materials. ISBM 2020. RILEM Bookseries, vol 27. Springer, Cham. https://doi.org/10.1007/978-3-030-46455-4_45
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DOI: https://doi.org/10.1007/978-3-030-46455-4_45
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