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Spent Automotive Converters as a Secondary Resource of Metals

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Practical Aspects of Chemical Engineering (PAIC 2019)

Abstract

Chapter describes a possibility of recovery of metal ions (especially platinum group metals) from spent automobile converters by hydrometallurgical method. Also, the composition of the automobile catalyst is reported. Moreover, the results of leaching of metal ions from spent catalysts with organic and inorganic acids were presented. Carboxylic acids were considered as potential leaching agents for treatment of spent automotive converters. These acids show leaching potential towards base metals, and could be used in the first step of leaching prior to platinum group metals leaching in more stringent conditions.

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References

  • Al-Sheeha, H., Marafi, M., Raghavan, V., Rana, M.S.: Recycling and recovery routes for spent hydroprocessing catalyst waste. Ind. Eng. Chem. Res. 52, 12794–12801 (2013)

    Article  CAS  Google Scholar 

  • Angelidis, T.N.: Development of a laboratory scale hydrometallurgical procedure for the recovery of Pt and Rh from spent automotive catalysts. Top. Catal. 16, 419–423 (2001)

    Article  Google Scholar 

  • Bailey, O.H.: NOx Adsorbers for diesel applications: general considerations and operational issues. Diesel Net Technical report, ASEC Manufacturing (1997)

    Google Scholar 

  • Benson, M., Bennett, C.R., Harry, J.E., Patel, M.K., Cross, M.: The recovery mechanism of platinum group metals from catalytic converters in spent automotive exhaust systems. Resour. Conserv. Recycl. 31, 1–7 (2000)

    Article  Google Scholar 

  • Ding, Y., Zheng, H., Li, J., Zhang, S., Liu, B., Ekberg, C.: An efficient leaching of palladium from spent catalysts through oxidation with Fe(III). Materials 12, 1205 (2019)

    Article  CAS  Google Scholar 

  • DCL (2017). http://www.dcl-inc.com. Accessed 1 Oct 2017)

  • Fornalczyk, A: Analiza możliwości wykorzystania magnetohydrodynamiki do intensyfikacji odzysku platyny ze zużytych katalizatorów samochodowych. Wydawnictwo Politechniki Śląskiej, Gliwice (2016). ( in Polish)

    Google Scholar 

  • Hagelüken, C.: Markets for the catalyst metals platinum, palladium and rhodium. Metall 1–2, 31–42 (2006)

    Google Scholar 

  • Johnson Matthey (2019).http://www.platinum.matthey.com/. Accessed 21 Sept 2019

  • Kucharski, M.: Recykling metali nieżelaznych. Wydawnictwa AGH, Kraków (2010). (in Polish)

    Google Scholar 

  • Malekian, H., Salehi, M., Biria, D.: Investigation of platinum recovery from a spent refinery catalyst with a hybrid of oxalic acid produced by Aspergillus niger and mineral acids. Waste Manage. 85, 264–271 (2019)

    Article  CAS  Google Scholar 

  • Marafi, M., Stanislaus, A.: Waste catalyst utilization: extraction of valuable metals from spent hydroprocessing catalysts by ultrasonic-assisted leaching with acids. Ind. Eng. Chem. Res. 50, 9495–9501 (2011)

    Article  CAS  Google Scholar 

  • Mazurek, K.: Removal of vanadium, potassium and iron from spent vanadium catalyst by leaching with citric acid at atmospheric pressure. Pol. J. Chem. Technol. 16, 59–62 (2014)

    Article  CAS  Google Scholar 

  • McVicker, G.B., Carter, J.L., Murrell, L.L., Ziemiak, J.J.: Removal of metal contaminants from catalysts using buffered oxalic acid. US patent: 4522928 (1985)

    Google Scholar 

  • Mišić, L., Kovačević, R., Gardić, V., Marković, R., Petrović, J.: Leaching process of platinum metals from spent autocatalysts. In: 17th International Research/Expert Conference on Trends in the Development of Machinery and Associated Technology, Istanbul, Turkey, pp. 169–172 (2013)

    Google Scholar 

  • Rzelewska, M., Regel-Rosocka, M.: Wastes generated by automotive industry–spent automotive catalysts. Phys. Sci. Rev. 3(8), 20180021 (2018)

    Google Scholar 

  • Saguaru, C., Ndlovu, S., Moropeng, D.: A review of recent studies into hydrometallurgical methods for recovering PGMs from used catalytic converters. Hydrometallurgy 182, 44–56 (2018)

    Article  Google Scholar 

  • Sarioğlan, Ş.: Recovery of palladium from spent activated carbon-supported palladium catalysts. Platin. Met. Rev. 57, 289–296 (2013)

    Article  Google Scholar 

  • Saternus, M., Fornalczyk, A.: Zużyte katalizatory samochodowe jako źródło platynowców. Rudy Metale 54(2), 59–67 (2009). (in Polish)

    Google Scholar 

  • Shen, W., Li, T., Chen, J.: Recovery of hazardous metals from spent refinery processing solid catalyst. Procedia Environ. Sci. 16, 253–256 (2012)

    Article  CAS  Google Scholar 

  • Sinisalo, P., Lundström, M.: Refining approaches in the platinum group metal processing value chain—a review. Metals 8, 203 (2018)

    Article  Google Scholar 

  • Suiter, J.: Al2O3 Oxide Morphology for Two Fe-Cr-Al Stainless Steel Foils Used in Gasoline Engine Catalytic Converters (2012). http://digitalcommons.calpoly.edu/cgi/viewcontent.cgi?article=1068&context=matesp

  • Suoranta, T., Zugazua, O., Niemelä, M., Perämäki, P.: Recovery of palladium, platinum, rhodium and ruthenium from catalyst materials using microwave-assisted leaching and cloud point extraction. Hydrometallurgy 156, 56–62 (2015)

    Article  Google Scholar 

  • Trinh, H.B., Lee, J.C., Srivastava, R.R., Kim, S., Ilyas, S.: Eco-threat minimization in HCl leaching of PGMs from spent automobile catalysts by formic acid prereduction. ACS Sustain. Chem. Eng. 58, 7302–7309 (2017)

    Article  Google Scholar 

  • Umicore Precious Metals Refining (2009). http://www.umicore.com/storage/migrate/2009sept_PMR.pdf

  • Upadhyay, A.K., Lee, J., Kim, E., Kim, M., Kim, B.S., Kumar, V.: Leaching of platinum group metals (PGMs) from spent automotive catalyst using electro-generated chlorine in HCl solution: Leaching of platinum group metals from spent automotive catalyst. J. Chem. Technol. Biotechnol. 88, 1991–1999 (2013)

    CAS  Google Scholar 

  • Wolak, P.: Motoryzacja a środowisko. Otwarty Uniwersytet Ekonomiczny (2008). (in Polish)

    Google Scholar 

  • Wołowicz, A.: Zastosowanie palladu i jego związków ze szczególnym uwzględnieniem katalizy. Przem. Chem. 92(7), 1237–1245 (2013). (in Polish)

    Google Scholar 

  • Zeng, L., Cheng, C.Y.: A literature review of the recovery of molybdenum and vanadium from spent hydrodesulphurisation catalysts: part I: metallurgical processes. Hydrometallurgy 98, 1–9 (2009)

    Article  CAS  Google Scholar 

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Acknowledgements

The work was supported by the Polish Ministry of Science and Higher Education (Grant No. 0912/SBAD/2010) and co-financed by National Agency of Academic Exchange NAWA (Grant No. PPN/BIL/2018/1/00200).

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Correspondence to Martyna Rzelewska-Piekut .

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Rzelewska-Piekut, M., Saternus, M., Fornalczyk, A., Regel-Rosocka, M. (2020). Spent Automotive Converters as a Secondary Resource of Metals. In: Ochowiak, M., Woziwodzki, S., Mitkowski, P., Doligalski, M. (eds) Practical Aspects of Chemical Engineering. PAIC 2019. Springer, Cham. https://doi.org/10.1007/978-3-030-39867-5_41

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