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Response Surface Methodology for the Optimization of 4-Nitrophenol Degradation by a Heterogeneous Fenton-Like Reaction on Moroccan Pillared Clays

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Advanced Intelligent Systems for Sustainable Development (AI2SD’2019) (AI2SD 2019)

Part of the book series: Advances in Intelligent Systems and Computing ((AISC,volume 1104))

Abstract

Heterogeneous Fenton-like reactions on pillared clays were investigated for the degradation of 4-Nitrophenol (4-NP). A Box–Behnken Design coupled with response surface methodology (RSM) was applied to evaluate and optimize the important variables. In this process, copper-pillared clays were prepared by intercalation of a Moroccan Bentonite and tested in the catalytic wet peroxide oxidation of 4-NP. The prepared catalysts were characterized by X-Ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and Inductively coupled plasma atomic emission spectroscopy (ICP-AES). A significant quadratic model (P-value < 0.0008, R2 = 0.9526) was derived using analysis of variance (ANOVA), which was adequate to perform the process variables optimization. More than 90% of 4-NP was experimentally degraded after 4 h of reaction time under the optimum conditions. The model predicted maximum removal of 98.66% of 4-NP under the optimum conditions of operational parameters (9.48 mM peroxide concentration, 0.325 g L−1 catalyst dose and 51 ℃).

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Acknowledgment

The authors gratefully acknowledge the financial support of CNRST-Maroc (Projets dans les domaines Prioritaires de la Recherche scientifique et du développement technologique PPR2). F. Baragh would like to thank Mrs. A. Loqman for the technical support regarding the use of JMP software.

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Authors and Affiliations

  1. Laboratory of Coordination and Analytical Chemistry (LCCA), Faculty of Sciences, Chouaib Doukkali University, Route Ben Maachou, 24000, El Jadida, Morocco

    Fidâ Baragh & Mahfoud Agunaou

  2. Laboratory of Catalysis, Materials and Environment (LCME), Higher School of Technology, Sidi Mohamed Ben Abdellah University, USMBA, EST, 30000, Fez, Morocco

    Fidâ Baragh, Brahim El Bali & Abdelhak Kherbeche

  3. Materials and Interfacial Systems Laboratory (MSI), Faculty of Sciences, Abdel Malek Essaadi University, Avenue de Sebta, B.P. 2121, 93002, M’hannech II, Tetouan, Morocco

    Khalid Draoui

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  1. Fidâ Baragh
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  2. Khalid Draoui
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  3. Brahim El Bali
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  4. Abdelhak Kherbeche
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  5. Mahfoud Agunaou
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Correspondence to Fidâ Baragh .

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Editors and Affiliations

  1. Faculty of Sciences and Techniques of Tangier, Abdelmalek Essaâdi University, Tangier, Morocco

    Mostafa Ezziyyani

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Baragh, F., Draoui, K., El Bali, B., Kherbeche, A., Agunaou, M. (2020). Response Surface Methodology for the Optimization of 4-Nitrophenol Degradation by a Heterogeneous Fenton-Like Reaction on Moroccan Pillared Clays. In: Ezziyyani, M. (eds) Advanced Intelligent Systems for Sustainable Development (AI2SD’2019). AI2SD 2019. Advances in Intelligent Systems and Computing, vol 1104. Springer, Cham. https://doi.org/10.1007/978-3-030-36671-1_50

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