Abstract
Metallic foams (MFs) are a moderately new class of designing materials having a unique kind of properties including high strength-to-weight ratio and appealing energy absorption characteristics contrasted with their bulk counterparts. These striking properties of MFs make them reasonable for applications in wide areas, e.g., impact energy absorption, load-bearing sandwich cores for aerospace and ground transportation industries, in automobile components to reduce weight, as heat sinks for thermal management, fortifying building and transport structures against impacts or buckling, etc. The various manufacturing processes are grouped by the state of matter in which the metal is handled – solid, liquid, gaseous, or ionized. This chapter reports the most simple and versatile process called “replication process” which offers a versatile way to produce open-cell foams, also called metal sponges. The basis of this process was developed in the 1960s, which uses a leachable preform (NaCl particles work well for aluminum), into which a molten material is infiltrated under inert gas pressure and solidified, before leaching of the preform to leave an open-celled structure. Replication process can be implicated to manufacture pure aluminum and other alloy foams of various materials and sizes. Replication can be done by covering with metal vapor, electroplating, or investment casting. Different structures can be utilized as templates for making cell materials: free or sintered main part of inorganic or natural granular issue, hollow spheres, or even customary polymer structures which are changed over to a metallic structure in an assigned preparing step.
The present chapter also reports an investigation of metallic foams which has turned out to be appealing to analysts keen on both scientific and industrial applications. The ideology of research is focused on manufacturing process of lightweight metallic foam. This chapter is focused on making production more reliable and to improve the properties of foamed metals. A second important field is the investigation of structure-property relationships. Intuitively it seems obvious that uniform metal foam with smooth cell walls yields the best mechanical properties. Third, modeling of metal foam structures is important for being able to interpret the experimental data and to help design engineers to apply the material. Besides these areas there are other more technological fields of interest such as joining, cutting, or coating of metal foams.
References
Fukasawa T, Ando M, Ohji T, Kanzaki S (2001) Synthesis of porous ceramics with complex pore structure by freeze-dry processing. J Am Ceram Soc 84(1):230–232
Atisivan R, Bose S, Bandyopadhyay A (2001) Porous mullite preforms via fused deposition. J Am Ceram Soc 84(1):221–223
Cichocki FR Jr, Trumble KP (1998) Tailored porosity gradients via colloidal infiltration of compression-molded sponges. J Am Ceram Soc 81(6):1661–1664
Zhao B, Gain AK, Ding W, Zhang L, Li X, Fu Y (2018) A review on metallic porous materials: pore formation, mechanical properties, and their applications. Int J Adv Manuf Technol 95(5-8):2641–2659
Banhart J (2013) Light-metal foams – history of innovation and technological challenges. Adv Eng Mater 15(3):82–111
Nayebi A, Surmiri A (2018) Characterization of mechanical properties of metallic foams by instrumented indentation test. Metall Res Technol 115(4):405
Feng Q, Wu X, Guo Y, She J, Xiang Y (2018) The effect of aluminum dihydrogen phosphate on the enhanced mechanical properties of aluminum foams. Mater Trans 59(6):922–926
Taherishargh M, Linul E, Broxtermann S, Fiedler T (2018) The mechanical properties of expanded perlite-aluminium syntactic foam at elevated temperatures. J Alloys Compd 737:590–596
Sosnik A (1948) US Patent 2434 775
Niebylski LM, Charema CP, Lee TE (1974a) US Patent 3743 353
Fiedler SO, Bjorksten J, Fielder WS (1961) US Patent 2979 392
Liu X, Wei Y, Jin D, Shih WH (2000) Synthesis of mesoporous aluminum alkoxide and tartaric acid. Mater Lett 42(3):143–149
Wang LZ, Shi JL, Yu J, Zhang WH, Yan DS (2000) Temperature control in the synthesis of cubic mesoporous silica materials. Mater Lett 45(5):273–278
Lange FF, Miller KT (1987) Open-cell, low density ceramics fabricated from reticulated polymer substrate. Adv Ceram Mater 2(4):827–831
Powell SJ, Evans JRG (1995) The structure of ceramic foams prepared from polyurethane–ceramic suspensions. Mater Manuf Process 10(4):757–771
Sherman J, Tuffias RH, Kaplan RB (1991) Refractory ceramic foams: a novel, new high-temperature structure. Am Ceram Soc Bull 70(6):1025–1029
Peng HX, Fan Z, Evans JRG, Busfield JJC (2000) Microstructure of ceramic foams. J Eur Ceram Soc 20(7):807–813
Lyckfildt O, Ferreira JMF (1998) Processing of porous ceramics by starch consolidation. J Eur Ceram Soc 18(2):131–140
Komarneni S, Pach L, Pidugu R (1995) Porous-alumina ceramics using boehmite and rice flour. Mater Res Soc Symp Proc 371:285–290
Schmidt H, Koch D, Grathwohl G, Colombo P (2001) Micro-/Macroporous ceramics from preceramic precursors. J Am Ceram Soc 84(10):2252–2255
Colombo P, Roisman TG, Scheffler M, Buhler P, Greil P (2001) Conductive ceramic foams from preceramic polymers. J Am Ceram Soc 84(10):2265–2268
Kuchek HA (1966) US Patent 3236 706
Thiele W (1971) German Patent 1933 321
Gilani H, et al. (2012) Effect of processing parameters and glycerin addition on the properties of Al foams. Met Mater Int 18(2):327–333
Sharma V, Ghose J, Kumar S (2012) Compressive and acoustic behavioural analysis of Al-MMC foam for industrial applications. J I Eng (India): Series C 93(1):33–40
Kreigh JR, Gibson JK (1962) US Patent 3055 763
Geramipour T, Oveisi H (2017) Effects of foaming parameters on microstructure and compressive properties of aluminum foams produced by powder metallurgy method. T Nonferr Metal Soc 27(7):1569–1579
Pen, sinteza in karakterizacija aluminijevih, and dolomita in titanovega hidrida kot penilnega.(2014) Synthesis and characterization of Al foams produced by powder metallurgy route using dolomite and titanium hydride as a foaming agents. Materiali in tehnologije 48(6):943–947
Chang C, Shen B, Inoue A (2006) FeNi-based bulk glassy alloys with superhigh mechanical strength and excellent soft-magnetic properties. Appl Phys Lett 89(5):051912
Wang W-H, Dong C, Shek CH (2004) Bulk metallic glasses. Mat Sci Eng R 44(2–3):45–89
Kündig AA, et al. (2002) Influence of low oxygen contents and alloy refinement on the glass forming ability of Zr52. 5Cu17. 9Ni14. 6Al10Ti5. Mater T 43(12):3206–3210
Liu CT, Chisholm MF, Miller MK (2002) Oxygen impurity and microalloying effect in a Zr-based bulk metallic glass alloy. Intermetallics 10(11–12):1105–1112
Merrett RP, Langdon GS, Theobald MD (2013) The blast and impact loading of aluminium foam. Mater Des 44:311–319
Dandliker RB, Conner RD, Johnson WL (1998) Melt infiltration casting of bulk metallic-glass matrix composites. J Mater Res 13(10):2896–2901
Choi-Yim H, et al. (1999) Synthesis and characterization of particulate reinforced Zr57Nb5Al10Cu15. 4Ni12. 6 bulk metallic glass composites. Acta Mater 47(8):2455–2462
Choi-Yim H, et al. (2002) Processing, microstructure and properties of ductile metal particulate reinforced Zr57Nb5Al10Cu15. 4Ni12. 6 bulk metallic glass composites. Acta Mater 50(10):2737–2745
Peroni M, Solomos G, Pizzinato V (2013) Impact behaviour testing of aluminium foam. Int J Impact Eng 53:74–83
Jin I, Kenny LD, Sang H (1990) US Patent 4 973 358, PCT Patent WO 91/03578 (1991); PCT Patent WO 92/03582 (1992); US Patent 5 112 696 (1992)
Thomas M, Kenny LD (1994) PCT Patent WO 94/172218
Wood JT (1998) Metal foams. In: Proceedings of the Fraunhofer USA metal foam symposium 7–8.10.1997, Stanton, Delaware. Eds.: J. Banhart and H. Eifert, MIT Verlag/Publishing, Bremen, p 31
Ruch W, Kirkevag B (1990) International Patent Application PCT/NO90/00115; WO 91/01387 (1991)
D.J. Lloyd, A.D. McLeod, P.L. Morris, I. Jin, PCT Patent WO 91/19823 (1991)
Kenny LD, Thomas M (1994) PCT Patent WO 94/09931
Sang H, Kenny LD, Jin I (1992) PCT Patent WO 92/21457
Prakash O, et al. (1997) Light weight cellular structures based on aluminium. No. LA-UR-96-4083; CONF-970248-1. Los Alamos National Lab., NM (United States)
Zheng Y, Sridhar S, Russell KC (1995) Advances in porous materials. Komareni S, et al, (eds) MRS Society Bull 371:365
Akiyama S et al (1986) European Patent Application EP 0 210803 A1, US Patent4 713 277 (1987)
Otsuka M, Kojima A, Itoh M, Ishii E (1991) Science and engineering of light metals. In: Proceedings of the conference on RASELM ’91, Tokyo, Oct. 1991, Ed.: Japan Institute of Light Metals, p 999
Duarte I, Banhart J (2000) A study of aluminium foam formation–kinetics and microstructure. Acta Mater 48(9):2349–2362
Thiele W (1972) German Patent, 1 933 321 (1971); Metals and Materials, Aug. 1972, p 349
Hartmann M, Singer RF (1997) Metallschäume. In: Proceedings of the symposium on metal foams, 6.-7.3.1997, Bremen, Germany. Ed.: J. Banhart, MIT-Verlag/Publishing Bremen, p 39, (in German); this symposium R5.5
Banhart J (2005) Aluminium foams for lighter vehicles. Int J Vehicle Des 37(2–3):114–125
Degischer H-P, Kriszt B (2002) Handbook of cellular metals. Wiley-VCH, Weinheim
Banhart J, Schmoll C, Neumann U (1998) In: Faria L (ed) Materials in oceanic environment. Sociedade Portuguesa de Materiais, Lisbon, p 55
Dannemann KA, et al. (2004) Dynamic compression of aluminum foam processed by a freeform fabrication technique. AIP Conference Proceedings. Vol. 706. No. 1. American Institute of Physics
Ashby MF, Evans AG, Fleck NA, Gibson LJ, Hutchinson JW, Wadley HNG (2000) Metal foams – a design guide. Butterworth-Heinemann, London
Simancik F, Rajner W, Laag R (2002) In: Ghosh A, Sanders TH, Claar TD (eds) Processing and properties of lightweight cellular metals and structures. TMS, Seattle, p 25
Allen BC, Mote MW, Sabroff AM (1963) Method for making foamed metal, USA Patent 3,087,807
Baumeister J, Banhart J, Weber M (1994) Verfahren zur Herstellung eines metallischen Verbundwerkstoffs. [Process for manufacturing metallic composite materials] German Patent. 44 26 627 C2
Banhart J, Seeliger H-W (2008) Aluminium foam sandwich panels: manufacture, metallurgy and applications. Adv Eng Mater 10(9):793–802
Helwig H-M, Garcia-Moreno F, Banhart J (2011a) A study of Mg and Cu additions on the foaming behaviour of Al–Si alloys. J Mater Sci 46(15):5227–5236
Helwig HM, Banhart J, Seeliger HW (2011b) Metallschäume aus einer Aluminium legierung, ihre Verwendung und Verfahren zur Herstellung [Metal foams made of an aluminium alloy, use and manufacturing route], European Patent EP 2 143 809
Simančík F, Lúčan L, Jerz J (2001) Reinforced aluminium foams. Cell Metals and Metal Foaming Technology (MetFoam2001) 365
Andrews EW, Sanders W, Gibson LJ (1999) Compressive and tensile behaviour of aluminum foams. Mater Sci Eng A 270(2):113–124
Simone AE, Gibson LJ (1998a) Aluminum foams produced by liquid-state processes. Ada Materialia 46(9):3109–3123
Sugimura Y, Meyer J, He MY, Bart-Smith H, Grenestedt J, Evans AG (1997a) On the mechanical performance of closed cell Al alloy foams. Acta Mater 45(12):5245–5259
Gibson LJ, Ashby MF (1982) On the mechanical performance of closed cell Al alloy foams. Proc R Soc A 382:43–59
Gibson LJ, Ashby MF (1997) Cellular solids: structure and properties, 2nd edn. Cambridge University Press, Cambridge
Ko WL (1965) Deformation of foamed elastomers. J Cell Plast 1:45–50
Dilley DC (1974) Foametal–its properties and applications. Mach Prod Eng 125: 24–25
Thornton PH, Magee CL (1975a) The deformation of aluminum foams. Metall Trans A 6(6):1253–1263
Berry Jr CB, Fanning RJ (1972) US Patent 3705 030
Berry Jr CB (1972) US Patent 3669654
Berry Jr CB, Valdo AR (1973) US Patent 3725 037
Niebylski LM, Jarema CP, Immethun PA (1974b) US Patent 3794 481
Bjorksten J, Rock EJ (1972) US Patent 3794481
Niebylski LM, Jarema CP, Lee TE (1976) US Patent 3940 262
Jiang B, Wang Z, Zhao N (2007) Effect of pore size and relative density on the mechanical properties of open cell aluminum foams. Scripta Mater 56(2):169–172
Fabrizio Q, et al. (2011) Replication casting of open-cell AlSi7Mg0. 3 foams. Mater Lett 65(17–18):2558–2561
Ashby MF, Hutchinson JW, Evans AG (1998) Cellular metals, a design guide. Cambridge University Press, Cambridge
Conclusions VI, Sugimura Y, Meyer J, He MY, Bart-Smith H, Grenestedt J, Evans AG (1997b) Acta Mater 45:5245
McCullough KYG, Fleck NA, Ashby FM (1999) Toughness of aluminium alloy foams. Acta Mater 47(8):2331–2343
Veyhl C, et al. (2011) Thermal analysis of aluminium foam based on micro-computed tomography. Materialwiss Werkst 42(5):350–355
Duarte I, Vesenjak M, LovreKrstulović-Opara (2014) Dynamic and quasi-static bending behaviour of thin-walled aluminium tubes filled with aluminium foam. Compos Struct 109:48–56
Dickenson C (1997) Filters and filtration handbook, 3rd edn. Elsevier Science Publishers, Oxford
Lehtovaara A, Mojtahedi W (1993) Ceramic filters behavior in gasification. Bioresour Technol 46:113–118
Eggerstedt PM, Zievers JF, Zievers EC (1993) Choose the right ceramic for filtering hot gases. Chem Eng Prog 89:62–62
Acosta FA, Castillejos AH, Almanza JM, Flores A (1995) An analysis of liquid flow through ceramic porous media used for molten metal filtration. Metall Mater Process Trans B 26B:159–171
Sheppard LM (1993) Porous ceramics: processing and applications. Ceramic transactions – porous materials. Am Ceram Soc Bull 31:3–23
Seeliger H-W (2002) Manufacture of aluminum foam sandwich (AFS) components. Adv Eng Mater 4(10):753–758
Beals JT, Thompson MS (1997) Density gradient effects on aluminium foam compression behaviour. J Mater Sci 32(13):3595–3600
Neugebauer R, Hipke T (2006) Machine tools with metal foams. Adv Eng Mater 8(9):858–863
Neugebauer R, Hipke T (2006) Machine tools with metal foams. Adv Eng Mater 8:858–863. [CrossRef]
Pohltec metalfoam. Available online: http://metalfoam.de/. Accessed on 27 July 2015
IWU. Available online: http://www.iwu.fraunhofer.de/. Accessed on 27 July 2015
Lenel FV (1980) Powder metallurgy principles and applications. Metal Powder Industries Federation, London
Dattoma V, et al. (2009) Prediction of residual fatigue life of aluminium foam through natural frequencies and damping shift. Fatigue Fract Eng M 32(7):601–616
Haruta M, et al. (1989) Gold catalysts prepared by coprecipitation for low-temperature oxidation of hydrogen and of carbon monoxide. J Catal 115(2):301–309
Park C, Nutt SR (2001) Effects of process parameters on steel foam synthesis. Mater Sci Eng: A 297(1–2):62–68
Arwade SR, et al. (2011) Steel foam material processing, properties and potential structural applications. Structural Materials and Mechanics, Proceedings of the 2011 NSF Engineering Research and Innovation Conference, Atlanta, GA, USA. Vol. 47. 2011
Kretz R, Hombergsmeier E, Eipper K (1999) Metal foams and porous metal structures. In: Banhart J, Ashby MF, Fleck NA (eds) International conference, Bremen, Germany, 14–16 June. MIT Press–Verlag, Bremen, p 23
Thiele W (1972) Aluminium used as an impact energy absorbing material. Met Mater 6:349–352
Rakow JF, Waas AM (2004) Size effects in metal foam cores for sandwich structures. AIAA J 42(7):1331–1337
Weimer GA (1976) Foamed Metals Start to Realize Potential. Iron Age 218(8):33–34
Evans AG, Hutchinson JW, Ashby MF (1998) Multifunctionality of cellular metal systems. Prog Mater Sci 43(3):171–221
Simone AE, Gibson LJ (1998) Effects of solid distribution on the stiffness and strength of metallic foams. Acta Mater 46(6):2139–2150
Schwartz DS, et al. (1998) Materials Research Society, Symposium Proceedings, Volume 521. Porous and Cellular Materials for Structural Applications. Materials Research Society Warreendale PA
Simone AE, Gibson LJ (1998b) Effects of solid distribution on the stiffness and strength of metallic foams. Acta Mater 46(6):2139–2150
Sanders W, Gibson LJ (1998) Porous and cellular materials for structural applications. In: Schwartz DS, Shih DS, Evans AG, Wadley HNG (eds) MRS Symp Proc, vol 521, p 53. MRS Spring, San Francisco.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2021 Springer Nature Switzerland AG
About this entry
Cite this entry
Harshit, K., Gupta, P. (2021). Advanced Research Developments and Commercialization of Light Weight Metallic Foams. In: Kharissova, O.V., Torres-Martínez, L.M., Kharisov, B.I. (eds) Handbook of Nanomaterials and Nanocomposites for Energy and Environmental Applications. Springer, Cham. https://doi.org/10.1007/978-3-030-36268-3_7
Download citation
DOI: https://doi.org/10.1007/978-3-030-36268-3_7
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-36267-6
Online ISBN: 978-3-030-36268-3
eBook Packages: Chemistry and Materials ScienceReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics