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Ultrathin Garnet-Type Electrolytes

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Solid Electrolytes for Advanced Applications

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Abstract

Recent years, all solid-state battery (ASSB) has attracted much attention mainly due to the safety concerns. As the key factor of ASSB, the solid electrolyte determines the performance of the battery. Among the numerous electrolytes, the garnet type Li7La3Zr2O12 (LLZO) possesses the advantages of ionic conductivity and excellent chemical stability. Compared to the LLZO bulk ceramic electrolyte, LLZO thin films have advantages in better contact with electrodes, less lithium diffusion time in electrolytes and smaller resistance in ASSB. In this chapter, we will introduce LLZO films prepared by different thin-film preparation methods, including pulsed laser deposition (PLD), radio frequency (RF), sol–gel method, chemical vapor deposition (CVD), focused ion beam (FIB) milling, atomic layer deposition (ALD), and wet coating. Their methods, performance, and applications will be detailed expounded in each section.

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References

  1. Murugan R, Thangadurai V, Weppner W (2007) Angew Chem Int Ed Engl 46:7778–7781

    Article  CAS  Google Scholar 

  2. Ramakumar S, Deviannapoorani C, Dhivya L, Shankar LS, Murugan R (2017) Prog Mater Sci 88:325–411

    Article  CAS  Google Scholar 

  3. Thangadurai V, Narayanan S, Pinzaru D (2014) Chem Soc Rev 43:4714–4727

    Article  CAS  Google Scholar 

  4. Du F, Zhao N, Li Y, Chen C, Liu Z, Guo X (2015) J Power Sources 300:24–28

    Article  CAS  Google Scholar 

  5. Ohta S, Kobayashi T, Seki J, Asaoka T (2012) J Power Sources 202:332–335

    Article  CAS  Google Scholar 

  6. Wu JF, Pang WK, Peterson VK, Wei L, Guo X (2017) ACS Appl Mater Interfaces 9:12461–12468

    Article  CAS  Google Scholar 

  7. Loho C, Djenadic R, Bruns M, Clemens O, Hahn H (2017) J Electrochem Soc 164:9

    Google Scholar 

  8. Su Y, Falgenhauer J, Polity A, Leichtweiß T, Kronenberger A, Obel J, Zhou S, Schlettwein D, Janek J, Meyer BK (2015) Solid State Ionics 282:63–69

    Article  CAS  Google Scholar 

  9. Nowak S, Berkemeier F, Schmitz G (2015) J Power Sources 275:144–150

    Article  CAS  Google Scholar 

  10. Tan J, Tiwari A (2012) Mater Res Soc Symp Proc 1471

    Google Scholar 

  11. Tiwari A, Tan J (2012) ECS Solid State Lett 1:4

    Google Scholar 

  12. Rawlence M, Garbayo I, Buecheler S, Rupp JL (2016) Nanoscale 8:14746–14753

    Article  CAS  Google Scholar 

  13. Reinacher J, Berendts S, Janek J (2014) Solid State Ion 258:1–7

    Article  CAS  Google Scholar 

  14. Kim S, Hirayama M, Taminato S, Kanno R (2013) Dalton Trans 42:13112–13117

    Article  CAS  Google Scholar 

  15. Hoon Park J, Hong W-S, Park JS, Cheng L, Cabana J, Chen G, Doeff MM, Li Y, Richardson TJ, Son J-W (2013) ECS Trans 53:4

    Google Scholar 

  16. Park JS, Cheng L, Zorba V, Mehta A, Cabana J, Chen G, Doeff MM, Richardson TJ, Park JH, Son J-W, Hong W-S (2015) Thin Solid Films 576:55–60

    Article  CAS  Google Scholar 

  17. Saccoccio M, Yu J, Lu Z, Kwok SCT, Wang J, Yeung KK, Yuen MMF, Ciucci F (2017) J Power Sources 365:43–52

    Article  CAS  Google Scholar 

  18. Park JH, Hong W-S, Park JS, Cheng L, Cabana J, Chen G, Doeff MM, Li Y, Richardson TJ, Son J-W (2013) Aluminum migration during deposition of Li7La3Zr2O12 thin films on aluminum oxide substrates. ECS Trans 53:1–4

    Article  Google Scholar 

  19. Kalita DJ, Lee SH, Lee KS, Ko DH, Yoon YS (2012) Solid State Ion 229:14–19

    Article  CAS  Google Scholar 

  20. Lobe S, Dellen C, Finsterbusch M, Gehrke HG, Sebold D, Tsai CL, Uhlenbruck S, Guillon O (2016) J Power Sources 307:684–689

    Article  CAS  Google Scholar 

  21. Chen R-J, Huang M, Huang W-Z, Shen Y, Lin Y-H, Nan C-W (2014) J Mater Chem A 2:13277

    Article  CAS  Google Scholar 

  22. Tadanaga K, Egawa H, Hayashi A, Tatsumisago M, Mosa J, Aparicio M, Duran A (2015) J Power Sources 273:844–847

    Article  CAS  Google Scholar 

  23. Zarabian M, Bartolini M, Pereira-Almao P, Thangadurai V (2017) J Electrochem Soc 164:7

    Google Scholar 

  24. Zarabian M, Bartolini M, Pereira-Almao P, Thangadurai V (2017) J Electrochem Soc 164:A1133–A1139

    Article  CAS  Google Scholar 

  25. Katsui H, Goto T (2015) Thin Solid Films 584:130–134

    Article  CAS  Google Scholar 

  26. Loho C, Djenadic R, Bruns M, Clemens O, Hahn H (2017) J Electrochem Soc 164:A6131–A6139

    Article  CAS  Google Scholar 

  27. Gong Y, Zhang J, Jiang L, Shi J-A, Zhang Q, Yang Z, Zou D, Wang J, Yu X, Xiao R, Hu Y-S, Gu L, Li H, Chen L (2017) J Am Chem Soc 139:4274–4277

    Article  CAS  Google Scholar 

  28. Kazyak E, Chen K-H, Wood KN, Davis AL, Thompson T, Bielinski AR, Sanchez AJ, Wang X, Wang C, Sakamoto J, Dasgupta NP (2017) Chem Mater 29:3785–3792

    Article  CAS  Google Scholar 

  29. Yan X, Li Z, Wen Z, Han W (2017) J Phys Chem C 121:1431–1435

    Article  CAS  Google Scholar 

  30. Yan X, Li Z, Ying H, Nie F, Xue L, Wen Z, Han W (2018) Ionics 24:1445–1551

    Google Scholar 

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Authors and Affiliations

  1. Department of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027, China

    Xufeng Yan & Weiqiang Han

Authors
  1. Xufeng Yan
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  2. Weiqiang Han
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Correspondence to Weiqiang Han .

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Editors and Affiliations

  1. Department of Physics, Pondicherry University, Puducherry, India

    Ramaswamy Murugan

  2. LS Sensorik und Festkörperionik, Universität zu Kiel, Kiel, Germany

    Werner Weppner

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Yan, X., Han, W. (2019). Ultrathin Garnet-Type Electrolytes. In: Murugan, R., Weppner, W. (eds) Solid Electrolytes for Advanced Applications. Springer, Cham. https://doi.org/10.1007/978-3-030-31581-8_7

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